화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 196-208, December, 2018
DOI10.1016/j.jiec.2018.07.046  Export Citation
New insights about coke deposition in methanol-to-DME reaction over MOR-, MFI- and FER-type zeolites
Massimo Migliori†, Enrico Catizzone, Alfredo Aloise, Giuseppe Bonura1, Luis Gómez-Hortigüela2, Leone Frusteri3, Catia Cannilla, Francesco Frusteri, and Girolamo Giordano
  • Department of Environmental and Chemical Engineering, University of Calabria, Via P. Bucci, Cubo 42a, I-87036 Rende, CS, Italy
  • 1Istituto di Tecnologie Avanzate per l’Energia “Nicola Giordano”, CNR-ITAE, Via S. Lucia Sopra Contesse 5, I-98126 Messina, Italy
  • 2Instituto de Catálisis y Petroleoquímica, ICP-CSIC, C/Marie Curie 2, Madrid, Spain
  • 3University of Messina, Dip. Ingegneria Elettronica, Chimica ed Ingegneria Industriale INSTM/CASPE, Laboratory of Catalysis for Sustainable Production and Energy, Contrada di Dio, I-98166 Messina, Italy
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The effect of channel-system of zeolite on methanol-to-DME reaction was studied. Results revealed that channels size and topology affect catalyst lifetime, type and location of coke precursors. FER and MFI showed the best resistance towards coke deposition, whilst fast deactivation was observed on MOR. Although the higher concentration and strength of acid sites, FER structure formed a lower coke amount, preferably located within the pores, while coke cluster deposited on the external surface of MOR. Analysis of acid sites distribution and strength was performed during deactivation?regeneration process. Coke location assessment was also supported by molecular simulations.
Keywords:Methanol-to-DME reaction;Catalyst deactivation;Coke deposition;Coke composition;Carbon deposit location
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