One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation

Xiangyun Xiao; Tae-Uook Kang; Hyobin Nam; Suk Ho Bhang; Seung Yong Lee; Jae-Pyung Ahn; Taekyung Yu

Korean Journal of Chemical Engineering, Vol.35, No.12, 2379-2383, December, 2018

DOI10.1007/s11814-018-0164-z Export Citation

One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation

Xiangyun Xiao¹, Tae-Uook Kang^{2, 3}, Hyobin Nam^{4, 5}, Suk Ho Bhang⁶, Seung Yong Lee^{4, 5, †}, Jae-Pyung Ahn^{3, †}, and Taekyung Yu^{1, †}

¹Department of Chemical Engineering, Kyung Hee University, Yongin 17104, Korea
²Department of Material Science & engineering, Korea University, Seoul 02841, Korea
³Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Korea
⁴Materials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Korea
⁵Department of Nanomaterials Science and Engineering, Korea University of Science and Technology, Daejeon 34113, Korea
⁶School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea

E-mail:, ,

We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

Keywords:PdAu Nanoparticles;Core/Shell;Bimetallic;One-pot Synthesis;Hydrogen Peroxide Generation

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