화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.69, 106-115, January, 2019
Fabrication of dual-coated graphene oxide nanosheets by polypyrrole and poly(ionic liquid) and their enhanced electrorheological responses
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A two-dimensional composite material, poly(ionic liquid)-modified graphene oxide/polypyrrole (GO/ PPy/PIL) multilayered nanosheets, was fabricated and applied as a new electrorheological (ER) material. The morphological differences between the single- and dual-coated nanosheets were confirmed using scanning electron microscopy and transmission electron microscopy. Rheological properties measured using a rotational rheometer indicated that the GO/PPy/PIL composite nanosheets exhibited relatively high ER effect under a certain electric field strength than the GO/PPy nanosheets because of the universal PIL second coating. The dual-coated nanosheets also showed a higher applicable electric field strength due to the semiconductive properties of the thick PIL layer.
  1. Welton T, Chem. Rev., 99(8), 2071 (1999)
  2. Yang M, Stappert K, Mudring AV, J. Mater. Chem. C, 2, 458 (2014)
  3. Bideau JL, Viau L, Vioux A, Chem. Soc. Rev., 40, 907 (2011)
  4. Rogers RD, Seddon KR, Science, 302, 792 (2003)
  5. Usui H, Domi Y, Fujiwara K, Shimizu M, Yamamoto T, Nohira T, Hagiwara R, Sakaguchi H, ACS Energy Lett., 2, 1139 (2017)
  6. Elia GA, Hassoun J, Kwak WJ, Sun YK, Scrosati B, Mueller F, Bresser D, Passerini S, Oberhumer P, Tsiouvaras N, Nano Lett., 14, 6572 (2014)
  7. Li CY, Patra J, Yang CH, Tseng CM, Majumder SB, Dong QF, Chang JK, ACS Sustain. Chem. Eng., 5, 8269 (2017)
  8. Yuan J, Mecerreyes D, Antonietti M, Prog. Polym. Sci, 23, 1009 (2013)
  9. Yoshizawa M, Ogihara W, Ohno H, Polym. Adv. Technol., 13, 589 (2002)
  10. Dong YZ, Wang B, Xiang LQ, Liu Y, Zhao XP, Yin JB, J. Phys. Chem. B, 121(25), 6226 (2017)
  11. Yuan JY, Soll S, Drechsler M, Muller AHE, Antonietti M, J. Am. Chem. Soc., 133(44), 17556 (2011)
  12. Dong YZ, Liu Y, Wang B, Xiang LQ, Zhao XP, Yin JB, Polymer, 132, 273 (2017)
  13. Kerscher B, Appel AK, Thomann R, Mulhaupt R, Macromolecules, 46(11), 4395 (2013)
  14. Green O, Grubjesic S, Lee S, Firestone MA, Polym. Rev., 49, 339 (2009)
  15. Ma Z, Yu JH, Dai S, Adv. Mater., 22(2), 261 (2010)
  16. Yuan J, Giordano C, Antonietti M, Chem. Mater., 22, 5003 (2010)
  17. Zhao X, Li S, Cheng H, Schmidt J, Thomas A, ACS Appl. Mater. Inter., 10, 3912 (2018)
  18. Kim TY, Lee HW, Stoller M, Dreyer DR, Bielawski CW, Ruoff RS, Suh KS, ACS Nano, 5, 436 (2011)
  19. Yang Y, Yuan J, ACS Symp. Ser., 1173, 17 (2014)
  20. Marcilla R, Mecerreyes D, Winroth G, Brovelli S, Maria DMRY, Cacialli F, Appl. Phys. Lett., 96, 15 (2010)
  21. Zheng Z, Xu Q, Guo J, Qin J, Mao H, Wang B, Yan F, ACS Appl. Mater. Inter., 8, 12684 (2016)
  22. Dong Y, Yin J, Zhao X, J. Mater. Chem. A, 2, 9812 (2014)
  23. Dong YZ, Yin JB, Yuan JH, Zhao XP, Polymer, 97, 408 (2016)
  24. Liu Y, Yuan J, Dong Y, Zhao X, Yin J, Soft Matter, 13, 1027 (2017)
  25. Tang JB, Radosz M, Shen YQ, Macromolecules, 41(2), 493 (2008)
  26. Liu YD, Choi HJ, Soft Matter, 8, 11961 (2012)
  27. Sheng P, Wen W, Annu. Rev. Fluid Mech., 44, 143 (2012)
  28. Zhang WL, Piao SH, Choi HJ, J. Colloid Interface Sci., 402, 100 (2013)
  29. Wereley NM, Lindler J, Rosenfeld N, Choi YT, Smart Mater. Struct., 13, 743 (2004)
  30. Oh JS, Han YM, Le SR, Choi SB, Smart Mater. Struct., 22, 045004 (2013)
  31. Tan KP, Johnson AR, Stanway R, Bullough WA, Mech. Mach. Theory, 42, 1547 (2007)
  32. Alice T, Ali S, Barbara M, Soft Robot., 3, 34 (2016)
  33. Hao T, Adv. Mater., 13, 761 (2001)
  34. Kim MJ, Chae HS, Choi HJ, J. Ind. Eng. Chem., 21, 145 (2015)
  35. Hao BN, Guo YX, Liu YD, Wang LM, Choi HJ, J. Mater. Chem. C, 4, 7875 (2016)
  36. Ji X, Zhang W, Jia W, Wang X, Tian Y, Deng L, Liu J, J. Ind. Eng. Chem., 56, 203 (2017)
  37. Zhao XP, Yin JB, J. Ind. Eng. Chem., 12(2), 184 (2006)
  38. Yin J, Wang X, Zhao X, Nanotechnology, 26, 065704 (2015)
  39. Cheng YC, Guo JJ, Liu XH, Sun AH, Xu GJ, Cui P, J. Mater. Chem., 21, 5051 (2011)
  40. Plachy T, Mrlik M, Kozakova Z, Suly P, Sedlacik M, Pavlinek V, Kuritka I, ACS Appl. Mater. Inter., 7, 3725 (2015)
  41. Plachy T, Sedlacik M, Pavlinek V, Stejskal J, J. Mater. Chem. C, 3, 9973 (2015)
  42. Jun CS, Kwon SH, Choi HJ, Seo Y, ACS Appl. Mater. Inter., 9, 44811 (2017)
  43. Yin J, Zhao X, Nanoscale Res. Lett., 6, 256 (2011)
  44. Sedlacik M, Pavlinek V, Mrlik M, Moravkova Z, Hajna M, Trchova M, Stejskal J, Mater. Lett., 101, 90 (2013)
  45. Zhang WL, Jiang D, Wang X, Hao BN, Liu YD, Liu J, J. Phys. Chem. C, 121, 4989 (2017)
  46. Mrlik M, Cvek M, Osicka J, Moucka R, Sdlacik M, Pavlinek V, Mater. Lett., 211, 138 (2018)
  47. Mrlik M, Ilcikova M, Plachy T, Moucka R, Pavlinek V, Mosnacek J, J. Ind. Eng. Chem., 57, 104 (2018)
  48. Wang XW, Qian X, Jiang XC, Lu Z, Hou LX, RSC Adv., 6, 26096 (2016)
  49. Zhang WL, Choi HJ, Soft Matter, 10, 6601 (2014)
  50. Ruiz ON, Fernando KAS, Wang B, Brown NA, Luo PG, McNamara ND, Vangsness M, Sun YP, Bunker CE, ACS Nano, 5, 8100 (2011)
  51. Stejskal J, Bober P, Trchova M, Horsky J, Walterova Z, Filippov SK, Plachy T, Mrlik M, New J. Chem., 42, 10167 (2018)
  52. Yin J, Chang R, Shui Y, Zhao X, Soft Matter, 9, 7468 (2013)
  53. Seo YP, Choi HJ, Lee JR, Seo Y, Colloids Surf. A: Physicochem. Eng. Asp., 457, 363 (2014)
  54. Tung TT, Kim TY, Shim JP, Yang WS, Kim H, Suh KS, Org. Electron., 12, 2215 (2011)
  55. Wang P, Zheng Y, Li B, Synth. Met., 166, 33 (2013)
  56. Marcilla R, Blazquez JA, Rodriguez J, Pomposo JA, Mecerreyes D, J. Polym. Sci. A: Polym. Chem., 42(1), 208 (2004)
  57. Mao H, Liang J, Zhang H, Pei Q, Liu D, Wu S, Zhang Y, Song XM, Biosens. Bioelectron., 70, 289 (2015)
  58. Yin J, Wang X, Chang R, Zhao X, Soft Matter, 8, 294 (2011)
  59. Feng XM, Yan ZZ, Li RM, Liu XF, Hou WH, Polym. Bull., 70(8), 2291 (2013)
  60. Feng S, Deng Y, Spectrochim. Acta A, 62, 239 (2005)
  61. Mrlik M, Ilcikova M, Plachy T, Pavlinek V, Spitalsky Z, Mosnacek J, Chem. Eng. J., 283, 717 (2016)
  62. Zhang WL, Liu YD, Choi HJ, Kim SG, ACS Appl. Mater. Inter., 4, 2267 (2012)
  63. Sim B, Zhang WL, Choi HJ, Mater. Chem. Phys., 153, 443 (2015)
  64. Chin BD, Winter HH, Rheol. Acta, 41(3), 265 (2002)
  65. Sim B, Dong HB, Choi HJ, Choi K, Islam MS, Kao N, Cellulose, 23, 185 (2016)
  66. Sim B, Choi HJ, RSC Adv., 5, 11905 (2015)
  67. Pan XD, Mckinley GH, Appl. Phys. Lett., 71(199), 333 (2016)
  68. Yang MC, Scriven LE, Macosko CW, J. Rheol., 30, 1015 (1986)
  69. Wang BX, Tian XL, He K, Ma LL, Yu SS, Hao CC, Chen KZ, Lei QQ, Polymer, 83, 129 (2016)
  70. Zhang WL, Choi HJ, Leong YK, Mater. Chem. Phys., 145(1-2), 151 (2014)
  71. Ilcikova M, Mrlik M, Babayan V, Kasak P, RSC Adv., 5, 57820 (2015)
  72. Yin J, Shui Y, Chang R, Zhao X, Carbon, 50, 5247 (2012)
  73. Lee S, Noh J, Hong S, Yun KK, Jang J, Chem. Mater., 28, 2624 (2016)
  74. Yin J, Shui Y, Dong Y, Zhao X, Nanotechnology, 25, 045702 (2014)
  75. Lee S, Yoon CM, Hong JY, Jang J, J. Mater. Chem. C, 2, 6010 (2014)
  76. Piao SH, Gao CY, Choi HJ, Polymer, 127, 174 (2017)
  77. Wang M, Li X, Guo Y, Wu T, Liu YD, Ngai KL, Wang LM, J. Chem. Phys., 145, 214501 (2016)
  78. Zhao J, Liu Y, Zheng C, Lei Q, Dong YZ, Zhao XP, Yin JB, Polymer, 146, 109 (2018)
  79. Iacob C, Sangoro JR, Serghei A, Naumov S, Korth Y, Karger J, Friedrich C, Kremer F, J. Chem. Phys., 129, 1615 (2008)