화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.72, 273-280, April, 2019
DOI10.1016/j.jiec.2018.12.028  Export Citation
Monitoring oxygen-vacancy ratio in NiFe-based electrocatalysts during oxygen evolution reaction in alkaline electrolyte
Hyunki Kim, Junhyeong Kim, and Sang Hyun Ahn†
  • School of Chemical Engineering and Material Science, Chung-Ang University, 84 Heukseokno, Dongjak-gu, Seoul, 06974, Republic of Korea
E-mail:
High oxygen-vacancy ratio has been recognized as an important criterion for oxygen evolving electrocatalysts to achieve high catalytic performance. Herein, we report changes in the oxygen-vacancy ratio during long-term stability tests. NiFe-based electrocatalysts containing various anions were prepared by a simple electrodeposition. After the fabrication procedure was optimized, the S-doped NiFe oxide electrocatalyst exhibited higher intrinsic activity than others in an alkaline electrolyte because it had the highest oxygen-vacancy ratio. During oxygen evolution at a constant positive potential, the intrinsic activity of the S-doped NiFe oxide electrocatalyst showed a significant correlation with the oxygen-vacancy ratio and surface morphology as a function of time.
Keywords:Electrodeposition;NiFe-based electrocatalysts;Oxygen evolution reaction;Oxygen-vacancy ratio;Long-term stability
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