폴리옥시에틸렌계 반응성 계면활성제의 합성 및 물성

조정은; 이상철; 박종권; 김경실; 신혜린; 김유리; 신승훈; 정노희; Jung-Eun Cho; Sang-Chul Lee; Jong-Kwon Park; Kyung-Sil Kim; Hye-Lin Shin; Yu-Ri Kim; Seung-Hoon Shin; Noh-Hee Jeong

Applied Chemistry for Engineering, Vol.30, No.2, 241-246, April, 2019

DOI10.14478/ace.2019.1007 Export Citation

폴리옥시에틸렌계 반응성 계면활성제의 합성 및 물성

Synthesis and Properties of Polyoxyethylene Reactive Surfactant

조정은, 이상철¹, 박종권¹, 김경실¹, 신혜린, 김유리¹, 신승훈¹, 정노희^†

충북대학교 공과대학 공업화학과
¹대양포리졸

Jung-Eun Cho, Sang-Chul Lee¹, Jong-Kwon Park¹, Kyung-Sil Kim¹, Hye-Lin Shin, Yu-Ri Kim¹, Seung-Hoon Shin¹, and Noh-Hee Jeong^†

Department of Engineering Chemistry, Chungbuk National University, Cheongju 28644, Korea
¹Daeyang polysol Co.,LTD, Sandanro 87, Heungdeok-gu, Cheongju, Korea

E-mail:

초록

본 실험에서 반응성 계면활성제는 비이온성 계면활성제인 polyoxyethylene(23) lauryl ether(Brij 35)와 polyoxyethylene(20) stearyl ether(Brij S20)를 acrylic acid 또는 3-butenoic acid를 사용하여 합성하였다. 계면활성제는 FT-IR과 1H-NMR로 확인하였으며, 물성은 임계미셀농도, 유화력, 기포력을 측정하였다. 합성한 반응성 계면활성제의 표면장력과 임계미셀 농도는 35 dyne/cm~41 dyne/cm에서 1.0 × 10-4 mol/L~9.7 × 10-5 mol/L의 값을 가진다. 또한, 계면활성제의 유화력은 대두유, 벤젠, 모노머에서 측정하였으며, 기포의 초기 높이 및 5 min 후의 높이를 측정하여 비교하였다.

In this paper, reactive surfactants were synthesized by using acrylic acid or 3-butenoic acid as nonionic surfactants, polyoxyethylene(23) lauryl ether (Brij 35) and polyoxyethylene(20) stearyl ether (Brij S20). The synthesis of surfactants was confirmed by FT-IR and 1H-NMR. The surface tension, emulsifying property, and foam power and stability were also measured. The surface tension value was 35~41 dyne/cm at an critical micelle concentration (cmc) which was measured as 1.0 × 10-4~9.7 × 10-5 mol/L using a surface tension method. The emulsifying power of synthesized surfactant was measured with benzene, soybean oil and monomer. Also, the initial height of the bubbles and the height after 5 minutes were measured and the values were compared with each other.

Keywords:Reactive surfactants;Polyoxyethylene nonionic surfactants;3-butanoic acid;Critical micelle concentration;Foam stability

[References]

Rosen MJ, Kunjappu JT, Surfactants and Interfacial Phenomena, 4th ed., 219-233, Wiley-Interscience, USA (2002).
Kirkpatrick FH, Sandberg H, Biochim. Biophys. Acta Biomembr., 298(2), 209 (1973)
Edwards DA, Luthy RG, Liu Z, Environ. Sci. Technol., 25, 127 (1991)
Ko HK, Park BD, Lim JC, J. Korean Ind. Eng. Chem., 11(6), 679 (2000)
Kunieda H, Shinoda K, J. Dispersion Sci. Technol., 3(3), 233 (2010)
Lim JC, J. Korean Ind. Eng. Chem., 16(6), 778 (2005)
Nilsson PG, Wennerstroem H, Lindman B, J. Phys. Chem., 87(8), 1377 (1983)
Laha S, Luthy RG, Environ. Sci. Technol., 25(11), 1920 (1991)
Saito H, Shinoda K, J. Colloid Interface Sci., 24(1), 10 (1967)
Chigwada G, Wang D, Jiang DD, Wilkie CA, Polym. Degrad. Stabil., 91, 755 (2006)
Nilsson PG, Lindman B, J. Phys. Chem., 87(23), 4756 (1983)
Akram M, Yousuf S, Sarwar T, Din KU, Colloids Surf. A: Physicochem. Eng. Asp., 441, 281 (2014)
Bourrel M, Salager JL, Schechter RS, Wade WH, J. Colloid Interface Sci., 75(2), 451 (1980)
Jonsson A, Jonsson B, J. Membr. Sci., 56, 49 (1991)
Guyot A, Tauer K, Polym. Synth., 111, 43 (2005)
Schoonbrood HA, Asua JM, Macromolecules, 30(20), 6034 (1997)
Amalvy JI, Unzue MJ, Schoonbrood HAS, Asua JM, J. Polym. Sci., 40, 2994 (2002)
Kunieda H, Shinoda K, J. Colloid Interface Sci., 107(1), 107 (1985)
Oh SG, Shah DO, J. Am. Oil Chemist. Soc., 7(7), 1316 (1991)
Opawale FO, Burgess DJ, J. Colloid Interface Sci., 197(1), 142 (1998)
Pasquali RC, Sacco N, Bregni C, Lat. Am. J. Pharm., 28(7), 313 (2009)

[1] Rosen MJ, Kunjappu JT, Surfactants and Interfacial Phenomena, 4th ed., 219-233, Wiley-Interscience, USA (2002).

[2] Kirkpatrick FH, Sandberg H, Biochim. Biophys. Acta Biomembr., 298(2), 209 (1973)

[3] Edwards DA, Luthy RG, Liu Z, Environ. Sci. Technol., 25, 127 (1991)

[4] Ko HK, Park BD, Lim JC, J. Korean Ind. Eng. Chem., 11(6), 679 (2000)

[5] Kunieda H, Shinoda K, J. Dispersion Sci. Technol., 3(3), 233 (2010)

[6] Lim JC, J. Korean Ind. Eng. Chem., 16(6), 778 (2005)

[7] Nilsson PG, Wennerstroem H, Lindman B, J. Phys. Chem., 87(8), 1377 (1983)

[8] Laha S, Luthy RG, Environ. Sci. Technol., 25(11), 1920 (1991)

[9] Saito H, Shinoda K, J. Colloid Interface Sci., 24(1), 10 (1967)

[10] Chigwada G, Wang D, Jiang DD, Wilkie CA, Polym. Degrad. Stabil., 91, 755 (2006)

[11] Nilsson PG, Lindman B, J. Phys. Chem., 87(23), 4756 (1983)

[12] Akram M, Yousuf S, Sarwar T, Din KU, Colloids Surf. A: Physicochem. Eng. Asp., 441, 281 (2014)

[13] Bourrel M, Salager JL, Schechter RS, Wade WH, J. Colloid Interface Sci., 75(2), 451 (1980)

[14] Jonsson A, Jonsson B, J. Membr. Sci., 56, 49 (1991)

[15] Guyot A, Tauer K, Polym. Synth., 111, 43 (2005)

[16] Schoonbrood HA, Asua JM, Macromolecules, 30(20), 6034 (1997)

[17] Amalvy JI, Unzue MJ, Schoonbrood HAS, Asua JM, J. Polym. Sci., 40, 2994 (2002)

[18] Kunieda H, Shinoda K, J. Colloid Interface Sci., 107(1), 107 (1985)

[19] Oh SG, Shah DO, J. Am. Oil Chemist. Soc., 7(7), 1316 (1991)

[20] Opawale FO, Burgess DJ, J. Colloid Interface Sci., 197(1), 142 (1998)

[21] Pasquali RC, Sacco N, Bregni C, Lat. Am. J. Pharm., 28(7), 313 (2009)