화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.76, 288-295, August, 2019
DOI10.1016/j.jiec.2019.03.053  Export Citation
MgO nanosheets with N-doped carbon coating for the efficient visible-light photocatalysis
Xiaogang Zheng1, Ke Wang1, Zhiping Huang1, Yong Liu1, Jing Wen2, 3, †, and Hao Peng4, †
  • 1College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang, Sichuan 641100, China
  • 2Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, Qinghai 810008, China
  • 3Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Xining, Qinghai 810008, China
  • 4College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408100, China
E-mail:,
MgO nanosheets with N-doped carbon coating (MgO@N-C) were fabricated for the enhanced photocatalytic degradation of dyes (methylene blue, methyl violet, and Rhodamine B) and antibiotics (ciprofloxacin and tetracycline hydrochloride) in visible light region. The effects of N-doping content, reactant concentration, pH value, and inorganic ions on the photocatalytic performance in degradation of methylene blue were investigated in this work. Narrow band gap energy and heterojunction interface endowed the extended light-harvesting capacity to visible light region and the efficient charge transfer, leading to the excellent photocatalytic activity and durability of MgO@N-C-3 with N-doping content of 1.52%.
Keywords:MgO nanosheets;N-doped carbon;Coating;Visible-light photocayalysis
  1. Subash B, Krishnakumar B, Swaminathan M, Shanthi M, Ind. Eng. Chem. Res., 53(33), 12953 (2014)
  2. Huang H, Li X, Wang J, Dong F, Chu PK, Zhang T, Zhang Y, ACS Catal., 5, 4094 (2015)
  3. Simsek EB, Kilic B, Asgin M, Akan A, J. Ind. Eng. Chem., 59, 115 (2018)
  4. Zheng XG, Huang M, You YH, Fu XJ, Liu Y, Wen J, Chem. Eng. J., 334, 1399 (2018)
  5. Zheng X, Fu W, Peng H, Wen J, J. Environ. Chem. Eng., 6, 9 (2018)
  6. Xiong W, Zeng G, Yang Z, Zhou Y, Zhang C, Cheng M, Liu Y, Hu L, Wan J, Zhou C, Xu R, Li X, Sci. Total Environ., 627, 235 (2018)
  7. Liu K, Chen L, Huang L, Lai Y, Carbohydr. Polym., 151, 1115 (2016)
  8. Kraus M, Trommler U, Holzer F, Kopinke FD, Roland U, Chem. Eng. J., 351, 356 (2018)
  9. Huang ZH, Li YZ, Chen WJ, Shi JH, Zhang N, Wang XJ, Li Z, Gao LZ, Zhang YX, Mater. Chem. Phys., 202, 266 (2017)
  10. Zheng X, Fu W, Kang F, Peng H, Wen J, J. Ind. Eng. Chem., 68, 14 (2018)
  11. Liu Y, Song Y, You Y, Fu X, Wen J, Zheng X, J. Saudi Chem. Soc., 22, 439 (2018)
  12. Simsek EB, Kilic B, Asgin M, Akan A, J. Ind. Eng. Chem., 59, 115 (2018)
  13. Zhou C, Lai C, Xu P, Zeng G, Huang D, Zhang C, Cheng M, Hu L, Wan J, Liu Y, Xiong W, Deng R, Wen M, ACS Sustain. Chem. Eng., 6, 4174 (2018)
  14. Zhou CY, Lai C, Zhang C, Zeng GM, Huang DL, Cheng M, Hu L, Xiong WP, Chen M, Wang JJ, Yang Y, Jiang LB, Appl. Catal. B: Environ., 238, 6 (2018)
  15. Vu AT, Park Y, Jeon PR, Lee CH, Chem. Eng. J., 258, 254 (2014)
  16. Xiong CM, Wang W, Tan FT, Luo F, Chen JG, Qiao XL, J. Hazard. Mater., 299, 664 (2015)
  17. Liu Y, Huang M, You Y, Zhu D, Fu X, Yuan J, Zheng X, Wen J, Desalin. Water Treat., 98, 326 (2017)
  18. Haldorai Y, Shim JJ, Appl. Surf. Sci., 292, 447 (2014)
  19. Vu AT, Ho K, Jin S, Lee CH, Chem. Eng. J., 291, 161 (2016)
  20. Vu AT, Ho K, Lee CH, Chem. Eng. J., 283, 1234 (2016)
  21. Jorfi S, Barzegar G, Ahmadi M, Soltani RDC, Haghighifard NAJ, Takdastan A, Saeedi R, Abtahi M, J. Environ. Manage., 177, 111 (2016)
  22. Mantilaka MMMGPG, De Silva RT, Ratnayake SP, Amaratunga G, de Silva KMN, Mater. Res. Bull., 99, 204 (2018)
  23. Wang Q, Li T, Xie P, Ma J, J. Environ. Chem. Eng., 5, 264 (2017)
  24. Li QY, Zong LL, Li C, Yang JJ, Appl. Surf. Sci., 314, 458 (2014)
  25. Chen JS, Xiong JH, Song YJ, Yu Y, Wu L, Appl. Surf. Sci., 440, 1269 (2018)
  26. Selvaratnam B, Koodali RT, Catal. Today, 300, 39 (2018)
  27. Bayal N, Jeevanandam P, Ceram. Int., 40, 15463 (2014)
  28. Xiang X, Xie LS, Li ZW, Li F, Chem. Eng. J., 221, 222 (2013)
  29. Al-Naser QAH, Zhou J, Wang H, Liu G, Wang L, Opt. Mater., 46, 22 (2015)
  30. Stojadinovic S, Tadic N, Radic N, Grbic B, Vasilic R, Surf. Coat. Technol., 310, 98 (2017)
  31. Jorfi S, Pourfadakari S, Kakavandi B, Chem. Eng. J., 343, 95 (2018)
  32. Renuka L, Anantharju KS, Sharma SC, Nagaswarupa HP, Prashantha SC, Nagabhushana H, Vidya YS, J. Alloy. Compd., 672, 609 (2016)
  33. Bayal N, Jeevanandam P, Mater. Res. Bull., 48(10), 3790 (2013)
  34. Najafi A, Ceram. Int., 43, 5813 (2017)
  35. Sathyamoorthy R, Mageshwari K, Mali SS, Priyadharshini S, Patil PS, Ceram. Int., 39, 323 (2013)
  36. FaurBrasquet C, Kadirvelu K, Le Cloirec P, Carbon, 40, 2387 (2002)
  37. Qi Q, Liu S, Li X, Kong C, Guo Z, Chen L, J. Solid State Chem., 255, 108 (2017)
  38. Zhao Y, Ma J, Liu J, Bao Y, Colloids Surf. A: Physicochem. Eng. Asp., 518, 57 (2017)
  39. Martins NCT, Angelo J, Girao AV, Trindade T, Andrade L, Mendes A, Appl. Catal. B: Environ., 193, 67 (2016)
  40. Mohamed MA, Salleh WNW, Jaafar J, Rosmi MS, Hir ZAM, Abd Mutalib M, Ismail AF, Tanemura M, Appl. Surf. Sci., 393, 46 (2017)
  41. Qian JW, Peng ZJ, Peng M, Li H, Wang M, Li HI, Fu XL, J. Catal., 353, 325 (2017)
  42. Wang W, Song JN, Kang YM, Dan CA, Zhao R, Lei ZQ, Energy, 133, 115 (2017)
  43. Ma R, Wang X, Huang J, Song J, Zhang J, Wang X, Vacuum, 141, 157 (2017)
  44. Wang XJ, Song JK, Huang JY, Zhang J, Wang X, Ma RR, Wang JY, Zhao JF, Appl. Surf. Sci., 390, 190 (2016)
  45. Jin QQ, Wang HB, Hu C, Chen ZS, Wang XK, Sep. Purif. Technol., 191, 108 (2018)
  46. Davila-Jimenez MM, Elizalde-Gonzalez MP, Guerrero-Morales MA, Mattusch J, Process Saf. Environ., 120, 195 (2018)
  47. Zhou C, Lai C, Xu P, Zeng G, Huang D, Li Z, Zhang C, Cheng M, Hu L, Wan J, Chen F, Xiong W, Deng R, ACS Sustain. Chem. Eng., 6, 6941 (2018)
  48. Sampaio MJ, Bacsa RR, Benyounes A, Axet R, Serp P, Silva CG, Silva AMT, Faria JL, J. Catal., 331, 172 (2015)
  49. Mohamed MA, Jaafar J, Zain MFM, Minggu LJ, Kassim MB, Rosmi MS, Alias NH, Nor NAM, Salleh WNW, Othman MHD, Appl. Surf. Sci., 436, 302 (2018)
  50. Chang Q, Li K, Hu S, Dong Y, Yang J, Mater. Lett., 175, 44 (2016)
  51. Ou JH, Gong CH, Wang M, Xiang J, Liu JX, Electrochim. Acta, 286, 212 (2018)
  52. Sampaio MJ, Benyounes A, Serp P, Faria JL, Silva CG, Appl. Catal. A: Gen., 551, 71 (2018)
  53. Xing Z, Ju Z, Zhao Y, Wan J, Zhu Y, Qiang Y, Qian Y, Sci. Rep., 6, 26146 (2016)
  54. Wang H, Maiyalagan T, Wang X, ACS Catal., 2, 781 (2012)
  55. Han M, Zhu S, Lu S, Song Y, Feng T, Tao S, Liu J, Yang B, Nano Today, 19, 201 (2018)
  56. Li J, Jiang Y, Li Y, Yang D, Xu Y, Yan M, Appl. Phys. Lett., 102, 072406 (2013)
  57. Li J, Jiang Y, Bai G, Ma T, Yang D, Du Y, Yan M, Appl. Phys. A-Mater. Sci. Process., 115, 997 (2014)
  58. Morozov IG, Sathasivam S, Belousova OV, Parkin IP, Kuznetcov MV, J. Alloy. Compd., 765, 343 (2018)
  59. Zheng X, Li X, Peng H, Wen J, J. Phys. Chem. Solids, 123, 206 (2018)
  60. Zheng X, Huang S, Yang D, Zhai H, You Y, Fu X, Yuan J, Zhou X, Wen J, Liu Y, J. Alloy. Compd., 705, 131 (2017)
  61. Jin Q, Zhang S, Wen T, Wang J, Gu P, Zhao G, Wang X, Chen Z, Hayat T, Wang X, Environ. Pollut., 243, 218 (2018)
  62. Jiang YQ, Chowdhury S, Balasubramanian R, Chem. Eng. J., 327, 751 (2017)
  63. Zhou CY, Lai C, Huang DL, Zeng GM, Zhang C, Cheng M, Hu L, Wan J, Xiong WP, Wen M, Wen XF, Qin L, Appl. Catal. B: Environ., 220, 202 (2018)
  64. Ravichandran K, Kalpana K, Uma R, Sindhuja E, Seelan KS, Mater. Res. Bull., 99, 268 (2018)
  65. Zeng J, Li Z, Peng H, Zheng X, Colloids Surf. A: Physicochem. Eng. Asp., 560, 244 (2019)
  66. Zheng XG, Huang M, You YH, Peng H, Wen J, Mater. Res. Bull., 101, 20 (2018)
  67. Huang H, Tu S, Zeng C, Zhang T, Reshak AH, Zhang Y, Angew. Chem.-Int. Edit., 56, 11860 (2017)
  68. Huang H, Xiao K, Zhang Y, ACS Sustain. Chem. Eng., 5, 5253 (2017)
  69. Huang HW, Xiao K, He Y, Zhang TR, Dong F, Du X, Zhang YH, Appl. Catal. B: Environ., 199, 75 (2016)
  70. Huang H, He Y, Li X, Li M, Zeng C, Dong F, Du X, Zhang T, Zhang Y, J. Mater. Chem. A, 3, 24547 (2015)