화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.11, 1136-1143, November, 2019
DOI10.1007/s13233-019-7148-7  Export Citation
Improving Mechanical Properties and Thermal Conductivity of Styrene-Butadiene Rubber via Enhancing Interfacial Interaction Between Rubber and Graphene Oxide/Carbon Nanotubes Hybrid
Zhenghua Qian, Jianan Song, Zijin Liu, and Zonglin Peng†
  • School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China
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To fully utilize the fascinating comprehensive properties of graphene oxide (GO) and carbon nanotubes (CNTs), GO was used to promote the dispersion of carboxylated multi-walled carbon nanotubes (CC) in rubber matrix. Additionally, carboxylated acrylonitrile butadiene rubber (xNBR) was used to enhance the interfacial interaction between the styrene-butadiene rubber (SBR) and the GO/CC hybrid fillers for the formation of hydrogen bonds between the oxygenated functional groups of GO/CC hybrid fillers and the carboxyl groups of xNBR. Moreover, the interfacial interaction was investigated by Fourier transform infrared spectroscopy and further proved by differential scanning calorimetry. As a result, the mechanical property and thermal conductivity of SBR composites were improved significantly compared with the neat SBR vulcanizate, which were much higher than those of the SBR composites without xNBR. In contrast to adding GO/CNTs directly to the rubber matrix, enhancing the interfacial interaction between GO/CC hybrid fillers and rubber matrix as demonstrated herein is a valuable strategy to prepare rubber composites with remarkable comprehensive properties.
Keywords:styrene-butadiene rubber;graphene oxide;carboxylated multi-walled carbon nanotubes;interfacial interaction
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