Effects of magnesium loading on ammonia capacity and thermal stability of activated carbons

Ji Hye Park; Haroon Ur Rasheed; Kwang Hee Cho; Hyung Chul Yoon; Kwang Bok Yi

Korean Journal of Chemical Engineering, Vol.37, No.6, 1029-1035, June, 2020

DOI10.1007/s11814-020-0508-3 Export Citation

Effects of magnesium loading on ammonia capacity and thermal stability of activated carbons

Ji Hye Park, Haroon Ur Rasheed¹, Kwang Hee Cho¹, Hyung Chul Yoon², and Kwang Bok Yi^{3, †}

Korea Institute of Industrial Technology, 89, Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan-si Chungcheongnam-do 31056, South Korea
¹Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, South Korea
²Korea Institute of Energy Research, 140, Yuseong-daero, 1312 beon-gil, Yuseong-gu, Daejeon 34101, South Korea
³Department of Chemical Engineering Education, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, South Korea

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Mg-loaded activated carbons were prepared by adding various amounts of Mg (1 to 20 wt%) via ultrasonic- assisted impregnation to investigate the effects on the adsorption and desorption characteristics of ammonia. Mgloaded activated carbons were characterized by TGA, BET, SEM, EDS mapping, and NH3-TPD analysis. Mg was homogeneously dispersed on the activated carbon and NH3-TPD analysis confirmed improved desorption and thermal stability for the 10 wt% Mg sample, named AC-Mg(10). AC-Mg(10) retained the highest desorption for five cycles and showed average desorption amount of 0.788mmol NH3/g. During the breakthrough analysis, the AC-Mg(10) showed an initial ammonia adsorption capacity of 0.81mmol NH3/g and average adsorption capacity of 0.69mmol NH3/g over 30 adsorption and desorption cycles.

Keywords:Activated Carbon;Magnesium;Ammonia;Adsorption;Breakthrough Test

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[Referenced By]

[1] Shipman MA, Symes MD, Catal. Today, 286, 57 (2017)

[2] Smil V, Nature, 400, 415 (1999)

[3] Jewell S, Kimball SM, US Geological Survey, 9, 196 (2015)

[4] Kim K, Lee SJ, Kim DY, Yoo CY, Choi JW, Kim JN, Woo Y, Yoon HC, Han JI, ChemSusChem, 11, 120 (2018)

[5] Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, Angew. Chem.-Int. Edit., 56, 2699 (2017)

[6] Jeong EY, Yoo CY, Jung CH, Park JH, Park YC, Kim JN, Oh SG, Woo Y, Yoon HC, ACS Sustain. Chem. Eng., 5, 9662 (2017)

[7] Kordali V, Kyriacou G, Lambrou C, Chem. Commun., 17, 1673 (2000)

[8] Renner JN, Greenlee LF, Ayres KE, Herring AM, Electrochem. Soc. Interface, 24, 51 (2015)

[9] Bandosz TJ, Petit C, J. Colloid Interface Sci., 338(2), 329 (2009)

[10] Ghauri M, Tahir M, Abbas T, Khurram MS, Shehzad K, Sci. Int., 24, 411 (2012)

[11] Goncalves M, Sanchez-Garcia L, Jardim EDO, Silvestre-Albero J, Rodriguez-Reinoso F, Environ. Sci. Technol., 45, 10605 (2011)

[12] Guo J, Xu WS, Chen YL, Lua AC, J. Colloid Interface Sci., 281(2), 285 (2005)

[13] Huang CC, Li HS, Chen CH, J. Hazard. Mater., 159(2-3), 523 (2008)

[14] Kim SD, Magnone E, Park JH, Ryu JY, J. Porous Mat., 25, 297 (2018)

[15] Rieth AJ, Dinca M, J. Am. Chem. Soc., 140(9), 3461 (2018)

[16] Seredych M, Petit C, Tamashausky AV, Bandosz TJ, Carbon, 47, 445 (2009)

[17] Chen Y, Zhang F, Wang Y, Yang C, Yang J, Li J, Microporous Mesoporous Mater., 258, 170 (2018)

[18] Khabzina Y, Farrusseng D, Microporous Mesoporous Mater., 265, 143 (2018)

[19] Qajar A, Peer M, Andalibi MR, Rajagopalan R, Foley HC, Microporous Mesoporous Mater., 218, 15 (2015)

[20] Molina L, Hammer B, Phys. Rev. B, 69, 155424 (2004)

[21] de Farias AMD, Barandas APMG, Perez RF, Fraga MA, J. Power Sources, 165(2), 854 (2007)

[22] Park JH, Baek JH, Hwang RH, Yi KB, Clean Technol., 23(4), 429 (2017)

[23] Baek JI, Ryu J, Lee JB, Eom TH, Kim KS, Yang SR, Ryu CK, Energy Procedia, 4, 349 (2011)

[24] Zhao M, Minett AI, Harris AT, Energy Environ. Sci., 6, 25 (2013)

[25] Choudhary VR, Uphade BS, Mamman AS, Catal. Lett., 32(3-4), 387 (1995)

[26] Iriondo A, Barrio V, Cambra J, Arias P, Guemez M, Navarro R, Sanchez-Sanchez M, Fierro J, Top. Catal., 49, 46 (2008)

[27] Parmaliana A, Arena F, Frusteri F, Coluccia S, Marchese L, Martra G, Chuvilin A, J. Catal., 141, 34 (1993)

[28] Silva WM, Ribeiro H, Seara LM, Calado HD, Ferlauto AS, Paniago RM, Leite CF, Silva GG, J. Braz. Chem. Soc., 23, 1078 (2012)

[29] Tian X, Hong G, Liu Y, Jiang B, Yang Y, RSC Adv., 4, 36316 (2014)

[30] Al Amer AM, Laoui T, Abbas A, Al-Aqeeli N, Patel F, Khraisheh M, Atieh MA, Hilal N, Mater. Des., 89, 549 (2016)

[31] Baek JH, Jeong JM, Park JH, Yi KB, Rhee YW, Trans. Korean Hydrog. New Energy Soc., 26, 423 (2015)

[32] Jeong JM, Park JH, Baek JH, Hwang RH, Jeon SG, Yi KB, Korean J. Chem. Eng., 34(1), 81 (2017)

[33] Wu Z, Jin R, Liu Y, Wang H, Catal. Commun., 9, 2217 (2008)