화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.89, 194-203, September, 2020
DOI10.1016/j.jiec.2020.05.013  Export Citation
Functionalization of 3D printed ABS filters with MOF for toxic gas removal
Ismael Pellejero†, Fernando Almazán1, Marta Lafuente1, Miguel A. Urbiztondo2, Martin Drobek3, †, Mikhael Bechelany3, †, Anne Julbe3, and Luis M. Gandía
  • Institute for Advanced Materials and Mathematics (InaMat2), Public University of Navarre (UPNA), Edificio Jerónimo de Ayanz, Campus de Arrosadia, 31006 Pamplona-Iruña, Spain
  • 1Nanoscience Institute of Aragon, University of Zaragoza, Department of Chemical & Environmental Engineering, Edificio I+D+i, Campus Río Ebro, C/Mariano Esquillor s/n, 50018 Zaragoza, Spain
  • 2Centro Universitario de la Defensa, Academia General Militar, Ctra. Huesca s/n, 50090 Zaragoza, Spain
  • 3Institut Européen des Membranes, IEM, UMR-5635, ENSCM, CNRS, Univ Montpellier, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France
E-mail:, ,
Acrylonitrile butadiene styrene (ABS) is one of the most extensively used polymer in 3D printing manufacturing due to its competitive thermal and mechanical properties. Recently, a special attention has been devoted to novel ABS composites featuring extra functionalities e.g. in the area of VOC removal. Herein, we report on a facile protocol for the functionalization of 3D printed ABS filters with a MOF (Metal-Organic Framework) material (ZIF-8) targeting the conception of attractive gas filters. The proposed synthesis strategy consists in low temperature ALD (Atomic Layer Deposition) of ZnO on the ABS grid followed by the hydrothermal conversion of ZnO to ZIF-8, both steps being conducted at 60 °C. In such way, the method enables an effective growth of ZIF-8 without altering the stability of the polymeric ABS support. The as-fabricated ABS/ZIF-8 filters offer a promising adsorption behaviour for dimethyl methylphosphonate (~20.4 mg of DMMP per gram of ZIF-8), thus proving their potential for toxic gas capture applications.
Keywords:ZIF-8;3D printing;ABS filter;Atomic Layer Deposition;VOCs abatement;Gas treatment
  1. Laplume AO, Petersen B, Pearce JM, J. Int. Bus. Stud., 47, 595 (2016)
  2. Balletti C, Ballarin M, Guerra F, J. Cult. Herit., 26, 172 (2010)
  3. Shofner ML, Lozano K, Rodriguez-Macias FJ, Barrera EV, J. Appl. Polym. Sci., 89(11), 3081 (2003)
  4. Jiang L, Lam YC, Tam KC, Chua TH, Sim GW, Ang LS, Polymer, 46(1), 243 (2005)
  5. Ma HY, Tong LF, Xu ZB, Fang ZP, Nanotechnology, 18, 375602 (2007)
  6. Schmitz DP, Silva TI, Ramoa S, Barra GMO, Pegoretti A, Soares BG, J. Appl. Polym. Sci., 135, 46546 (2018)
  7. Dul S, Fambri L, Pegoretti A, Nanomaterials, 8, 49 (2018)
  8. Bible M, Sefa M, Fedchak JA, Scherschligt J, Natarajan B, Ahmed Z, Hartings MR, Addit. Manuf., 5, 63 (2018)
  9. Kestila A, Nordling K, Miikkulainen V, Kaipio M, Tikka T, Salmi M, Auer A, Leskela M, Ritala M, Addit. Manuf., 22, 31 (2018)
  10. Anson M, Marchese J, Garis E, Ochoa N, Pagliero C, J. Membr. Sci., 243(1-2), 19 (2004)
  11. Kreider MC, Sefa M, Fedchak JA, Scherschligt J, Bible M, Natarajan B, Klimov NN, Miller AE, Ahmed Z, Hartings MR, Polym. Adv. Technol., 29, 867 (2018)
  12. Shekhah O, Liu J, Fischer RA, Woll C, Chem. Soc. Rev., 40, 1081 (2011)
  13. Zhang YY, Feng X, Yuan S, Zhou JW, Wang B, Inorg. Chem. Front., 3, 896 (2016)
  14. Cai YH, Chen DY, Li NJ, Xu QF, Li H, He JH, Lu JM, J. Membr. Sci., 543, 10 (2017)
  15. Basu S, Cano-Odena A, Vankelecom IFJ, Sep. Purif. Technol., 81(1), 31 (2011)
  16. Sorribas S, Zornoza B, Tellez C, Coronas J, J. Membr. Sci., 452, 184 (2014)
  17. Shi ZN, Xu C, Chen F, Wang YX, Li L, Meng QT, Zhang R, RSC Adv., 7, 49947 (2017)
  18. Wang ZY, Wang JJ, Li MY, Sun KH, Liu CJ, Sci. Rep., 4, 5939 (2014)
  19. Evans KA, Kennedy ZC, Arey BE, Christ JF, Schaef HT, Nune SK, Erikson RL, ACS Appl. Mater. Interfaces, 10, 15112 (2018)
  20. Li R, Yuan S, Zhang W, Zheng H, Zhu W, Li B, Zhou M, Law AWK, Zhou K, ACS Appl. Mater. Interfaces, 11, 40564 (2019)
  21. Halevi O, Tan JMR, Lee PS, Magdassi S, Adv. Sustain. Syst. 2, Unsp 1700150 (2018).
  22. Ge L, Zhou W, Du A, Zhu Z, J. Phys. Chem. C, 116, 13264 (2012)
  23. Cacho-Bailo F, Seoane B, Tellez C, Coronas J, J. Membr. Sci., 464, 119 (2014)
  24. Nagaraju D, Bhagat DG, Banerjee R, Kharul UK, J. Mater. Chem. A, 1, 8828 (2013)
  25. Khaletskaya K, Turner S, Tu M, Wannapaiboon S, Schneemann A, Meyer R, Ludwig A, Van Tendeloo G, Fischer RA, Adv. Funct. Mater., 24(30), 4804 (2014)
  26. Weber M, Julbe A, Ayral A, Miele P, Bechelany M, Chem. Mat., 30, 7368 (2018)
  27. Marichy C, Bechelany M, Pinna N, Adv. Mater., 24(8), 1017 (2012)
  28. Tynell T, Karppinen M, Semicond. Sci. Technol., 29, 043001 (2014)
  29. Miikkulainen V, Leskela M, Ritala M, Puurunen RL, J. Appl. Phys., 113, 021301 (2013)
  30. Zhao JJ, Losego MD, Lemaire PC, Williams PS, Gong B, Atanasov SE, et al., Adv. Mater. Interfaces, 1, 140004 (2014)
  31. Zhao JJ, Gong B, Nunn WT, Lemaire PC, Stevens EC, Sidi FI, Williams PS, et al., J. Mater. Chem. A, 3, 1458 (2015)
  32. Lee DT, Zhao JJ, Oldham CJ, Peterson GW, Parsons GN, ACS Appl. Mater. Interfaces, 9, 44847 (2017)
  33. Bechelany M, Drobek M, Vallicari C, Abou Chaaya A, Julbe A, Miele P, Nanoscale, 7, 5794 (2015)
  34. Drobek M, Bechelany M, Vallicari C, Abou Chaaya A, Charmette C, Salvador-Levehang C, Miele P, Julbe A, J. Membr. Sci., 475, 39 (2015)
  35. Zheng Q, Fu YC, Xu JQ, Elsevier Science Bv, Amsterdam, pp. 179-184 2010.
  36. Montoro C, Linares F, Procopio EQ, Senkovska I, Kaskel S, Galli S, Masciocchi N, Barea E, Navarro JAR, J. Am. Chem. Soc., 133(31), 11888 (2011)
  37. Moon SY, Liu YY, Hupp JT, Farha OK, Angew. Chem.-Int. Edit., 54, 6795 (2015)
  38. Liu YY, Howarth AJ, Vermeulen NA, Moon SY, Hupp JT, Farha OK, Coord. Chem. Rev., 346, 101 (2017)
  39. Troya D, J. Phys. Chem. C, 120, 29312 (2016)
  40. Ma XJ, Chai YT, Li P, Wang B, Accounts Chem. Res., 52, 1461 (2019)
  41. Viter R, Balevicius Z, Abou Chaaya A, Baleviciute I, Tumenas S, et al., J. Mater. Chem. C, 3, 6815 (2015)
  42. Almazan F, Pellejero I, Morales A, Urbiztondo MA, Sese J, Pina MP, Santamaria J, J. Micromech. Microeng., 26, 084010 (2016)
  43. REHAU. Acrylonitrile-butadiene-styrene (RAU-ABS) MATERIAL DATA SHEET AV0270 EN.
  44. Drobek M, Kim JH, Bechelany M, Vallicari C, Julbe A, Kim SS, ACS Appl. Mater. Interfaces, 8, 8323 (2016)
  45. Weber M, Kim JH, Lee JH, Kim JY, Iatsunskyi I, Coy E, Drobek M, Julbe A, Bechelany M, Kim SS, ACS Appl. Mater. Interfaces, 10, 34765 (2018)
  46. Iqbal J, Jilani A, Hassan PMZ, Rafique S, Jafer R, Alghamdi AA, J. King Saud Univ. Sci., 28, 347 (2016)
  47. Viter R, Iatsunskyi I, Fedorenko V, Tumenas S, Balevicius Z, Ramanavicius A, Balme S, Kempinski M, Nowaczyk G, Jurga S, Bechelany M, J. Phys. Chem. C, 120, 5124 (2016)
  48. Karagiaridi O, Lalonde MB, Bury W, Sarjeant AA, Farha OK, Hupp JT, J. Am. Chem. Soc., 134(45), 18790 (2012)
  49. Puype F, Samsonek J, Knoop J, Egelkraut-Holtus M, Ortlieb M, Food Addit. Contam. Part A-Chem., 32, 410 (2015)
  50. Truc NTT, Lee BK, J. Hazard. Mater., 329, 84 (2017)
  51. Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M, Chem. Mat., 21, 1410 (2009)
  52. Anzlovar A, Orel ZC, Kogej K, Zigon M, J. Nanomater., 760872 (2012).
  53. Dong DW, Tasaka S, Aikawa S, Kamiya S, Inagaki N, Inoue Y, Polym. Degrad. Stabil., 73, 319 (2001)
  54. Yang SY, Castilleja JR, Barrera EV, Lozano K, Polym. Degrad. Stabil., 83, 383 (2004)
  55. Wojtyla S, Klama P, Baran T, J. Occup. Environ. Hyg., 14, D80 (2017)
  56. Krokidas P, Castier M, Moncho S, Brothers E, Economou IG, J. Phys. Chem. C., 119, 27028 (2015)
  57. Kanan SM, Waghe A, Jensen BL, Tripp CP, Talanta, 72, 401 (2007)
  58. Panayotov DA, Morris JR, Langmuir, 25(6), 3652 (2009)
  59. Head AR, Tsyshevsky R, Trotochaud L, Yu Y, Karslioglu O, Eichhorn B, Kuklja MM, Bluhm H, J. Phys. Condens. Matter, 30, 134005 (2018)
  60. Liu GY, Li LY, Huang XD, Zheng SN, Xu XM, Liu ZX, Zhang YG, Wang J, Lin H, Xu DH, J. Mater. Sci., 53(15), 10772 (2018)
  61. Zhou Y, Zhou L, Zhang XH, Chen YL, Microporous Mesoporous Mater., 225, 488 (2016)
  62. Huynh K, Holdren S, Hu JK, Wang LN, Zachariah MR, Eichhorn BW, ACS Appl. Mater. Interfaces, 9, 40638 (2017)