화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.89, 239-249, September, 2020
DOI10.1016/j.jiec.2020.05.020  Export Citation
In-situ encapsulation of flaky aluminum pigment with poly (methylhydrosiloxane) anti-corrosion film for high-performance waterborne coatings
Chuanmin Zhang, Ran Huo, Xiaodong Wang1, †, Junying Zhang, Jue Cheng, and Ling Shi†
  • Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China
  • 1State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
E-mail:,
To improve the corrosion resistance and glossiness of flaky aluminum pigments in waterborne coatings, a flaky aluminum pigment was encapsulated with poly(methylhydrosiloxane) (PMHS) as an anti-corrosion film by in-situ polymerization, and its chemical composition was characterized by Fourier-transform infrared and X-ray photoelectron spectroscopy, and its morphology and microstructure was identified by scanning and transmission electron microcopy. Furthermore, its anticorrosive performance was confirmed by Zeta potential measurement and electrochemical impedance spectroscopy. The encapsulated flaky aluminum pigment not only exhibits excellent corrosion resistance but also shows an improved thermal stability due to the fabrication of a PMHS-based organosilicon film on the surface of aluminum flakes. Most of all, the original glossiness and brightness could be maintained for the waterborne coating film after the encapsulated flaky aluminum pigment was incorporated, indicating a great application potential in waterborne coatings, water-based paints, printing inks, spray-free materials and any more. This work provides a new strategy for design and fabrication of high corrosionresistant and high glossy aluminum pigments.
Keywords:Flaky aluminum pigment;Organosilicon film;In-situ polymerization;Corrosion resistance;Waterborne coatings
  1. Zhang WG, Jiang SN, Lv DD, Prog. Org. Coat., 143, 105622 (2020)
  2. Qi YQ, Shen LM, Zhang JL, Yao J, Lu R, Miyakoshi T, Environ. Pollut., 245, 810 (2019)
  3. Liu FG, Liu AM, Tao WJ, Yang YJ, Prog. Org. Coat., 145, 105684 (2020)
  4. Vostrikov AA, Shishkin AV, Fedyaeva ON, Int. J. Hydrog. Energy, 45(1), 1061 (2020)
  5. Liang JH, Azhar U, Men PC, Chen J, Li YN, He JX, Geng B, Appl. Surf. Sci., 487, 1000 (2019)
  6. Niu M, Pham-Huy C, He H, Microchim. Acta, 183, 2677 (2016)
  7. Feng LM, Yuan PY, Prog. Org. Coat., 140, 105508 (2020)
  8. Emad SGR, Morsch S, Hashimoto T, Liu Y, Gibbon SR, Lyon SB, Zhou X, Prog. Org. Coat., 137, 105340 (2019)
  9. Chaabane M, Bejaoui S, Trabelsi W, Telahigue K, Chetoui I, Chalghaf M, Zeghal N, Cafsi ME, Soudani N, Ecotox. Environ. Safe., 196, 10562 (2020)
  10. Zhao Y, Yan J, Li AP, Zhang ZL, Li ZR, Guo KJ, Zhao KC, Ruan Q, Guo L, Toxicol. Lett., 310, 31 (2019)
  11. Kera NH, Bhaumik M, Pillay K, Ray SS, Maity A, Mater. Today Commun., 15, 153 (2018)
  12. Niroumandrad S, Rostami M, Ramezanzadeh B, Appl. Surf. Sci., 357, 2121 (2015)
  13. Kwolek P, Kaminski A, Dychton K, Mrajewicz M, Sieniawski J, Corrosion Sci., 106, 208 (2016)
  14. Naderi R, Arman SY, Fouladvand S, Dyes Pigment., 105, 23 (2014)
  15. Tamilselvi M, Kamaraj P, Arthanareeswari M, Devikala S, Appl. Surf. Sci., 327, 218 (2015)
  16. Yohai L, Schreiner W, Vazquez M, Valcarce MB, Electrochim. Acta, 202, 231 (2016)
  17. Vega JM, Granizo N, de la Fuente D, Simancas J, Morcillo M, Prog. Org. Coat., 70, 213 (2011)
  18. Yang D, Xu Y, Xu W, J. Mater. Chem., 18, 5557 (2008)
  19. Bassyouni M, Abdel-Aziz MH, Zoromba MS, Abdel-Hamid SMS, Drioli E, J. Ind. Eng. Chem., 73, 19 (2019)
  20. Bao Y, Gao L, Feng C, Ma J, Zhang W, Liu C, Simion D, J. Ind. Eng. Chem., 82, 180 (2020)
  21. Pertays KM, Thompson GE, Alexander MR, Surf. Interface Anal., 36, 1361 (2004)
  22. Maayta AK, Al-Rawashdeh NAF, Corrosion Sci., 46, 1129 (2004)
  23. Kong L, Li Y, Qin F, Zhang T, Guo Q, Zhang X, Yang D, Xu J, Xue M, J. Ind. Eng. Chem., 58, 369 (2018)
  24. Yan R, Gao X, He W, Guo R, Wu R, Zhao Z, Ma H, RSC Adv., 7, 41152 (2017)
  25. Gao X, Jing X, Li Y, Zhu J, Zhang M, J. Macromol. Sci. A., 55, 24 (2018)
  26. Muller B, Langenbucher J, Corrosion Sci., 45, 395 (2003)
  27. Muller B, Corrosion Sci., 44, 1583 (2001)
  28. Muller B, Corrosion Sci., 46, 159 (2004)
  29. Kiehl A, Greiwe K, Prog. Org. Coat., 37, 179 (1999)
  30. Wang H, Huang S, Zuo Y, Corrosion Sci., 53, 161 (2011)
  31. Zhou L, Huang SL, Kong JR, Zhou T, Zuo YJ, Powder Technol., 237, 514 (2013)
  32. Liu H, Ye HQ, Tang XD, Appl. Surf. Sci., 254(2), 616 (2007)
  33. Amirshaqaqi N, Salami-Kalajahi M, Mahdavian M, Corrosion Sci., 87, 392 (2014)
  34. Amirshaqaqi N, Salami-Kalajahi M, Mahdavian M, Iran. Polym. J., 23, 699 (2014)
  35. Pi PH, Chen J, Chen K, Cai ZQ, Zheng DF, Wen XF, Cheng J, Yang ZR, Can. J. Chem. Eng., 90(5), 1224 (2012)
  36. Pi P, Liu C, Wen X, Zheng L, Xu S, Cheng J, Particuology, 19, 93 (2015)
  37. Pi PH, Liu C, Wen XF, Cheng J, Xu SP, Li Q, Can. J. Chem. Eng., 93(6), 1101 (2015)
  38. He Y, Li H, Ou L, Ding F, Zhan Z, Zhong Y, Corrosion Sci., 11, 802 (2016)
  39. Liu H, Ye H, Zhang Y, Colloids Surf. A: Physicochem. Eng. Asp., 315, 1 (2007)
  40. Li WQ, Shi L, Zhang JY, Cheng J, Wang XD, Powder Technol., 362, 462 (2020)
  41. Liu H, Ye H, Zhang Y, Dyes Pigment., 79, 236 (2008)
  42. Supplit R, Schubert U, Corrosion Sci., 49, 3325 (2007)
  43. Lin F, Song MZ, He ZZ, Zhang TY, J. Appl. Polym. Sci., 107(6), 3773 (2008)
  44. Greco PP, Stedile FC, dos Santos JHZ, J. Mol. Catal. A-Chem., 197(1-2), 233 (2003)
  45. Bauer F, Decker U, Dierdorf A, Ernst H, Heller R, Liebe H, Mehnert R, Prog. Org. Coat., 53, 183 (2005)
  46. Lin JB, Chen HL, Yuan YB, Ji Y, Appl. Surf. Sci., 257(21), 9024 (2011)
  47. Tanaka S, Chao Y, Araki S, Miyake Y, J. Membr. Sci., 348(1-2), 383 (2010)
  48. Wang K, Wang C, Yin Y, Chen K, J. Alloy. Compd., 690, 741 (2017)
  49. Mert BD, Corrosion Sci., 103, 88 (2016)
  50. Zhu GY, Cui XK, Zhang Y, Chen SG, Dong MY, Liu H, Shao Q, Ding T, Wu SD, Guo ZH, Polymer, 172, 415 (2019)