화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.90, 224-231, October, 2020
DOI10.1016/j.jiec.2020.07.015  Export Citation
Multifunctional aminoethylpiperazine-modified graphene oxide with high dispersion stability in polar solvents for mercury ion adsorption
Jeong-Un Jin1, 2, Hyeonuk Yeo3, Jae Ryang Hahn2, Jaesang Yu1, Bon-Cheol Ku1, and Nam-Ho You1, †
  • 1Carbon Composite Materials Research Center, Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Wanju, Jeonbuk 55324, Republic of Korea
  • 2Department of Chemistry, Jeonbuk National University, Jeonju, 54896, Republic of Korea
  • 3Department of Chemistry Education, Kyungpook National University, Daegu 41566, Republic of Korea
E-mail:
Graphene-derived materials including graphene oxide (GO) have infinite potential, but proper dispersibility must be ensured for the utilization of functionalities. To strengthen the compatibility of functionality and dispersibility, a new method by simply functionalizing GO with aminoethylpiperazine (AEP) is provided. Characterization of the synthesized AEP-GO was comprehensively carried out by several spectroscopic methods. Also, as intended, AEP-GO possessed good dispersibility in common organic solvents owing to the characteristics of the polytrophic amines in AEP. In particular, we investigated the possibility of its use as adsorbent for mercury ion as a representative of heavy metals. The solution with AEP-GO of 0.1 wt% achieved Hg2+ removal efficiency of 97.7% at low Hg2+ concentration of 50 ppm. Also, among the various adsorbent concentration, maximum adsorption capacity and removal efficiency were 107.2 mg/g and 98.4%, respectively. In this regard, our findings contribute to the discovery of new approaches to preparing graphene materials.
Keywords:Graphene oxide;Functionalization;Dispersibility;Mercury;Adsorption
  1. Duffus JH, Pure Appl. Chem., 74, 793 (2002)
  2. Robel I, Subramanian V, Kuno M, Kamat PV, J. Am. Chem. Soc., 128(7), 2385 (2006)
  3. Bolelli G, Berger LM, Borner T, Koivuluoto H, Lusvarghi L, Lyphout C, Markocsan N, Matikainen V, Nylen P, Sassatelli P, Surf. Coat. Technol., 265, 125 (2015)
  4. Harada M, Crit. Rev. Toxicol., 25, 1 (1995)
  5. Scoullos MJ, et al., 31, Springer Science & Business Media, 2012.
  6. Fu J, Zhang A, Wang T, Qu G, Shao J, Yuan B, Wang Y, Jiang G, Environ. Sci. Technol., 47, 7437 (2013)
  7. Alharbi OML, Basheer AA, Khattab RA, Ali I, J. Mol. Liq., 263, 442 (2018)
  8. RoHS 3 (EU 2015/863), https://rohsguide.com/, (2020).
  9. Scrosati B, Renew. Energy, 5, 285 (1994)
  10. Kadam AR, Nair GB, Dhoble SJ, J. Environ. Chem. Eng., 7, 103279 (2019)
  11. Lecler MT, Zimmermann F, Silvente E, Masson A, Morele Y, Remy A, Chollot A, Waste Manage., 76, 250 (2018)
  12. Barakat MA, Arabian J. Chem., 4, 361 (2011)
  13. Namasivayam C, Sangreetha D, J. Hazard. Mater., 135(1-3), 449 (2006)
  14. Dean JG, Bosqui FL, Lanouette KH, Environ. Sci. Technol., 6, 518 (1972)
  15. Burakov AE, Galunin EV, Burakova IV, Kucherova AE, Agarwal S, Tkachev AG, Gupta VK, Ecotoxicol. Environ. Saf., 148, 702 (2018)
  16. Li J, Wang X, Zhao G, Chen C, Chai Z, Alsaedi A, Hayat T, Wang X, Chem. Soc. Rev., 47(7), 2322 (2018)
  17. Chen ZS, Zhang S, Liu Y, Alharbi NS, Rabah SO, Wang SH, Wang XX, Sci. Total Environ., 731, 139054 (2020)
  18. Lu L, Yu W, Wang Y, Zhang K, Zhu X, Zhang Y, Wu Y, Ullah H, Xiao X, Chen B, Biochar, 2(1), 1 (2020)
  19. Corapcioglu M, Huang C, Water Res., 21, 1031 (1987)
  20. Kolodynska D, Krukowska J, Thomas P, Chem. Eng. J., 307, 353 (2017)
  21. Dias JM, Alvim-Ferraz MC, Almeida MF, Rivera-Utrilla J, Sanchez-Polo M, J. Environ. Econ. Manage., 85, 833 (2007)
  22. Huang JN, Li YH, Cao YH, Peng F, Cao YG, Shao Q, Liu H, Guo ZH, J. Mater. Chem. A, 6(27), 13062 (2018)
  23. Qian YX, Yuan YH, Wang HL, Liu H, Zhang JX, Shi S, Guo ZH, Wang N, J. Mater. Chem. A, 6(48), 24676 (2018)
  24. Perrich JR, Activated carbon adsorption for wastewater treatment, CRC press, 2018.
  25. Ruthven DM, Principles of adsorption and adsorption processes, John Wiley & Sons, 1984.
  26. Summers RS, Roberts PV, J. Colloid Interface Sci., 122, 382 (1988)
  27. Guo XY, Du B, Wei Q, Yang J, Hu LH, Yan LG, Xu WY, J. Hazard. Mater., 278, 211 (2014)
  28. Shen Y, Fang Q, Chen B, Environ. Sci. Technol., 49, 67 (2015)
  29. Vilela D, Parmar J, Zeng Y, Zhao Y, Sanchez S, Nano Lett., 16, 2860 (2016)
  30. Peng WJ, Li HQ, Liu YY, Song SX, J. Mol. Liq., 230, 496 (2017)
  31. Sitko R, Turek E, Zawisza B, Malicka E, Talik E, Heimann J, Gagor A, Feist B, Wrzalik R, Dalton Trans., 42, 5682 (2013)
  32. Zhao GX, Li JX, Ren XM, Chen CL, Wang XK, Environ. Sci. Technol., 45, 10454 (2011)
  33. Mukherjee R, Bhunia P, De S, Chem. Eng. J., 292, 284 (2016)
  34. Zhao DL, Zhang Q, Xuan H, Chen Y, Zhang KH, Feng SJ, Alsaedi A, Hayat T, Chen CL, J. Colloid Interface Sci., 506, 300 (2017)
  35. Xia T, Qi Y, Liu J, Qi Z, Chen W, Wiesner MR, Environ. Sci. Technol., 51(2), 828 (2017)
  36. Chen LL, Zhao DL, Chen SH, Wang XB, Chen CL, J. Colloid Interface Sci., 472, 99 (2016)
  37. Sherlala AIA, Raman AAA, Bello MM, Asghar A, Chemosphere, 193, 1004 (2018)
  38. Zhan WW, Gao L, Fu X, Siyar SH, Sui G, Yang XP, Appl. Surf. Sci., 467, 1122 (2019)
  39. Zhao DL, Gao X, Wu CN, Xie R, Feng SJ, Chen CL, Appl. Surf. Sci., 384, 1 (2016)
  40. Pirveysian M, Ghiaci M, Appl. Surf. Sci., 428, 98 (2018)
  41. Shin DG, Yeo H, Ku BC, Goh M, Carbon, 121, 17 (2017)
  42. Lim J, Yeo H, Kim SG, Park OK, Yu J, Hwang JY, Goh M, Ku BC, Lee HS, You NH, Compos. Part B, 114, 280 (2017)
  43. Lim J, Yeo H, Goh M, Ku BC, Kim SG, Lee HS, Park B, You NH, Chem. Mater., 27, 2040 (2015)
  44. Jin JU, Lee DH, Nam KH, Yu J, Kim YK, Goh M, Kim SG, Lee HS, Ku BC, You NH, Appl. Surf. Sci., 464, 509 (2019)
  45. Nam KH, Kim K, Kim SG, LEe HS, Jung H, Yu J, Jang SG, Ku BC, Moon B, You NH, Compos. Part B, 176, 107236 (2019)
  46. Chen J, Yao BW, Li C, Shi GQ, Carbon, 64, 225 (2013)
  47. Awad FS, AbouZeid KM, El-Maaty WMA, El-Wakil AM, El-Shal MS, ACS Appl. Mater. Interfaces, 9, 34230 (2017)
  48. Wang SF, Li X, Liu YG, Zhang C, Tan XF, Zeng GM, Song BA, Jiang LH, J. Hazard. Mater., 342, 177 (2018)
  49. Wang YY, Ni ZH, Yu T, Shen ZX, Wang HM, Wu YH, Chen W, Wee ATS, J. Phys. Chem. C, 112, 10637 (2008)
  50. Fang M, Zhang Z, Li JF, Zhang HD, Lu HB, Yang YL, J. Mater. Chem., 20, 9635 (2010)
  51. Lascovich JC, Scaglione S, Appl. Surf. Sci., 78, 17 (1994)
  52. Ravi S, Puthiaraj P, Row KH, Park DW, Ahn WS, Ind. Eng. Chem. Res., 56(36), 10174 (2017)
  53. Tadjarodi A, Ferdowsi SM, Zare-Dorabei R, Barzin A, Ultrason. Sonochem., 33, 118 (2016)
  54. Moulder JF, Handbook of X-ray Photoelectron Spectroscopy, 40, Perkin-Elmer Corp., pp.221 1992.
  55. Wagner CD, Naumkin AV, Kraut-Vass A, Allison JW, Powell CJ, Rumble JR, NIST XPS Datanase Version, 3, 251 (2003)
  56. Lesa B, Aneggi E, Rossi G, Comuzzi C, Goi D, J. Hazard. Mater., 171(1-3), 647 (2009)