화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.94, 448-456, February, 2021
DOI10.1016/j.jiec.2020.11.016  Export Citation
Natural marble powder-modified SBA-15 as an efficient catalyst for the selective production of 2-methyl-2-pentenal from n-propanal self-aldol condensation
Hari Prasad Reddy Kannapu1, 2, †, Jyothi Yadagiri2, Surendar Moogi1, Eilhann E. Kwon3, †, Su Shiung Lam4, and Young-Kwon Park1, †
  • 1School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea
  • 2Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India
  • 3Department of Environment and Energy, Sejong University, Seoul 05006, Republic of Korea
  • 4Pyrolysis Technology Research Group, Institute of Tropical Aquaculture and Fisheries (Akuatrop), Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia, Korea
E-mail:, ,
In this study, conversion of n-propanal to produce 2-methyl-2-pentenal (C6 compound, a fuel range precursor) was carried out using AMW-SBA-15 catalyst synthesized from activated marble waste (AMW) consisting mainly of Ca2+ and Mg2+ ions. AMW-SBA-15 catalysts with different weight ratios of AMW/Si (6, 12, and 18 wt. %) were prepared using single step sol-gel method. The catalytic activities were examined using a fixed bed continuous reactor over temperature ranging from 350-425 °C under atmospheric pressure. The 12AMW-SBA-15 catalysts showed superior catalytic performance with n-propanal conversion of 75 % and C-6 compound selectivity of 81 % at 375 °C without the need of deactivation for 12 h. To elucidate the structure-activity relationship, all catalysts were characterized using a variety of techniques. The superior performance of 12AMW-SBA-15 was ascribed to the high surface area and smaller particle size as well as the high hydrophobicity, which controlled the hydration of Ca2+/Mg2+ ions during the reaction.
Keywords:Bio-oil;n-propanal;2-methyl-2 pentenal;AMW-SBA-15;Hydrophobicity
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