화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.95, 292-304, March, 2021
DOI10.1016/j.jiec.2021.01.002  Export Citation
A highly-effective/durable metal-organic anti-corrosion film deposition on mild steel utilizing Malva sylvestris (M.S) phytoextract-divalent zinc cations
Mohammad Ebrahim Haji Naghi Tehrani1, 2, Mohammad Ramezanzadeh1, and Bahram Ramezanzadeh1, †
  • 1Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
  • 2School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran
E-mail:
For the first time, a metal-organic film with high anti-corrosion potency was constructed over the mild steel surface using Malva sylvestris (M.S) and zinc cations (Zn2+). The mild steel panels were immersed in the simulated seawater solution (3.5%wt. NaCl solution) containing different loadings of Zn:M.S inhibitors. The electrochemical impedance spectroscopy (EIS) and open circuit potential (OCP) measurements were performed at a different time step up to 240 h. The potentiodynamic polarization test was carried out to determine the inhibitor's inhibition mechanisms. The synergistic inhibition impact of the Zn:M.S before and after immersion was analyzed by Ultraviolet-Visible (UV-vis) spectroscopy. The protective film formed on the surface was studied by the Fourier transform infrared (FT-IR), Raman, grazing incidence X-ray diffraction (GIXRD), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), atomic force microscopy (AFM), and contact angle (CA) techniques. The EIS results evidenced that applying various ratios of Zn:M.S resulted in more than 98% corrosion inhibition efficiency (IE), which was stable up to 240 h. Meanwhile, the outstanding corrosion resistance of 170 kΩ.cm2 in 300:700 ppm Zn:M.S was recorded.
Keywords:Metal-organic;film;Corrosion;EIS;RAMAN;GIXRD
  1. Tang B, Su W, Wang J, Fu F, Yu G, Zhang J, J. Environ. Manage., 98, 147 (2012)
  2. Ramezanzadeh B, Mehdipour M, Arman SY, Prog. Color Colorants Coat, 8, 69 (2015)
  3. Leonzio G, J. Clean Prod., 133, 835 (2016)
  4. Coelho L, Taryba M, Alves M, Noirfalise X, Montemor M, Olivier MG, Corrosion Sci., 150, 207 (2019)
  5. Chaouiki A, Lgaz H, Zehra S, Salghi R, Chung IM, El Aoufir Y, Bhat KS, Ali IH, Gaonkar SL, Khan MI, Oudda H, J. Adhes. Sci. Technol., 33(9), 921 (2019)
  6. Edraki M, et al., Eurasian Chemical Communications 1(2, pp. 125-241.) (2019) 228-241, Eurasian Chem. Commun. 1 (2 (2019).
  7. Fayomi O, Akande I, J. Bio-Tribo-Corros., 5(1), 23 (2019)
  8. Choi DJ, You SJ, Kim JG, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 335(1-2), 228 (2002)
  9. Gomelya N, Shabliy T, Trohymenko A, Shuryberko M, J. Water Chem. Technol., 39, 92 (2017)
  10. Narenkumar J, Elumalai P, Subashchandrabose S, Megharaj M, Balagurunathan R, Murugan K, Rajasekar A, Chemosphere, 222, 611 (2019)
  11. Pareek S, Jain D, Hussain S, Biswas A, Shrivastava R, Parida SK, Kisan HK, Lgaz H, Chung IM, Behera D, Chem. Eng. J., 358, 725 (2019)
  12. Chauhan DS, Mouaden KE, Quraishi M, Bazzi L, Int. J. Biol. Macromol., 152, 234 (2020)
  13. Shabani-Nooshabadi M, Ghandchi MS, J. Ind. Eng. Chem., 31, 231 (2015)
  14. Ghanbari D, Salavati-Niasari M, J. Ind. Eng. Chem., 24, 284 (2015)
  15. Yousefi M, Gholamian F, Ghanbari D, Salavati-Niasari M, Polyhedron, 30(6), 1055 (2011)
  16. Masjedi-Arani M, Salavati-Niasari M, Ultrason. Sonochem., 29, 226 (2016)
  17. Refait P, Jeannin M, Sabot R, Antony H, Pineau S, Corrosion Sci., 90, 375 (2015)
  18. Fu A, Cheng Y, Prog. Org. Coat., 72(3), 423 (2011)
  19. Dong CF, Fu AQ, Li XG, Cheng YF, Electrochim. Acta, 54(2), 628 (2008)
  20. Ferchichi A, Calas-Etienne S, Smaihi M, Prevot G, Solignac P, Etienne P, J. Mater. Sci., 44(11), 2752 (2009)
  21. Mekeridis ED, Kartsonakis IA, Kordas GC, Prog. Org. Coat., 73(2-3), 142 (2012)
  22. Izadi M, Shahrabi T, Ramezanzadeh B, J. Ind. Eng. Chem., 57, 263 (2018)
  23. Izadi M, Shahrabi T, Ramezanzadeh B, Appl. Surf. Sci., 440, 491 (2018)
  24. Ramezanzadeh B, Mehdipour M, Arman S, Colorants Coat., 8(1), 69 (2014)
  25. Vastag G, Shaban A, Vranes M, Tot A, Belic S, Gadzuric S, J. Mol. Liq., 264, 526 (2018)
  26. Alaoui K, Ouakki M, Abousalem A, Serrar H, Galai M, Derbali S, Nouneh K, Boukhris S, Touhami ME, El Kacimi Y, J. Bio-Tribo-Corros., 5(1), 1 (2019)
  27. Majd MT, Shahrabi T, Ramezanzadeh B, Constr. Build. Mater., 221, 456 (2019)
  28. Asadikiya M, Zhong Y, Ghorbani M, Int. J. Corros., 2019 (2019)
  29. Kuruvilla K, Prasad AR, Shainy K, Joseph A, J. Bio-Tribo-Corros., 5(1), 9 (2019)
  30. Akbarzadeh S, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 297, 111862 (2020)
  31. Costa M, Klein CB, Crit. Rev. Toxicol., 36(2), 155 (2006)
  32. Lgaz H, Saha SK, Chaouiki A, Bhat KS, Salghi R, Banerjee P, Ali IH, Khan MI, Chung IM, Constr. Build. Mater., 233, 117320 (2020)
  33. Lgaz H, Salghi R, Jodeh S, Hammouti B, J. Mol. Liq., 225, 271 (2017)
  34. Izadi M, Shahrabi T, Ramezanzadeh B, J. Taiwan Inst. Chem. Eng., 81, 356 (2017)
  35. Pal S, Lgaz H, Tiwari P, Chung IM, Ji G, Prakash R, J. Mol. Liq., 276, 347 (2019)
  36. Haldhar R, Prasad D, Saxena A, J. Environ. Chem. Eng., 6(2), 2290 (2018)
  37. Saxena A, Prasad D, Haldhar R, Bioelectrochemistry, 124, 156 (2018)
  38. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A, J. Mol. Liq., 258, 89 (2018)
  39. Ye Y, Chen H, Zou Y, Ye Y, Zhao H, Corrosion Sci., 174, 108825 (2020)
  40. Ye Y, Yang D, Chen H, Guo S, Yang Q, Chen L, Zhao H, Wang L, J. Hazard. Mater., 381, 121019 (2020)
  41. Ye Y, Chen H, Zou Y, Zhao H, J. Mater. Sci. Technol., 67, 226 (2021)
  42. Ye Y, Zou Y, Jiang Z, Yang Q, Chen L, Guo S, Chen H, J. Alloy. Compd., 815, 152338 (2020)
  43. Ramezanzadeh M, Sanaei Z, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 256, 67 (2018)
  44. Bahlakeh G, Dehghani A, Ramezanzadeh B, Ramezanzadeh M, J. Mol. Liq., 294, 111550 (2019)
  45. Majd MT, Shahrabi T, Ramezanzadeh B, J. Alloy. Compd., 783, 952 (2019)
  46. Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 292, 111387 (2019)
  47. Bahlakeh G, Ramezanzadeh M, Ramezanzadeh B, J. Mol. Liq., 248, 854 (2017)
  48. Quave CL, Plano LR, Pantuso T, Bennett BC, J. Ethnopharmacol., 118(3), 418 (2008)
  49. Conforti F, Sosa S, Marrelli M, Menichini F, Statti GA, Uzunov D, Tubaro A, Menichini F, Loggia RD, J. Ethnopharmacol., 116, 144 (2008)
  50. Daniela A, Pichichero E, Canuti L, Cicconi R, Karou D, D’Arcangelo G, Canini A, Caryologia, 60(1-2), 90 (207)
  51. Barros L, Carvalho AM, Ferreira IC, Food Chem. Toxicol., 48(6), 1466 (2010)
  52. Guarrera PM, Fitoterapia, 74(6), 515 (2003)
  53. Ishtiaq M, Hanif W, Khan M, Ashraf M, Butt AM, Pak. J. Biol. Sci. PJBS, 10(13), 2241 (2007)
  54. Gasparetto JC, Martins CAF, Hayashi SS, Otuky MF, Pontarolo R, J. Pharm. Pharmacol., 64(2), 172 (2012)
  55. Billeter M, Meier B, Sticher O, Phytochemistry, 30(3), 987 (1991)
  56. Delfine S, Marrelli M, Conforti F, Formisano C, Rigano D, Menichini F, Senatore F, Ind. Crop. Prod., 98, 29 (2017)
  57. Sharifi-Rad J, Melgar-Lalanne G, Hernandez-Alvarez AJ, Taheri Y, Shaheen S, Kregiel D, Antolak H, Pawlikowska E, Brdar-Jokanovic M, Rajkovic J, Phytother. Res., 34(3), 546 (2020)
  58. Karm IFA, Int. J. Adv. Biol. Res., 7(2), 329 (2017)
  59. Tao ZH, Zhang ST, Li WH, Hou BR, Ind. Eng. Chem. Res., 49(6), 2593 (2010)
  60. Jeeva M, Prabhu GV, Boobalan MS, Rajesh CM, J. Phys. Chem. C, 119(38), 22025 (2015)
  61. Zhang Z, Wang F, Liu Y, Wu S, Li W, Sun W, Guo D, Jiang J, RSC Adv., 8(37), 20648 (2018)
  62. El Din AMS, Mohammed RA, Haggag HH, Desalination, 114(1), 85 (1997)
  63. Izadi M, Mohammadi I, Shahrabi T, Ramezanzadeh B, Fateh A, J. Taiwan Inst. Chem. Eng., 95, 555 (2019)
  64. Izadi M, Shahrabi T, Mohammadi I, Ramezanzadeh B, Prog. Org. Coat., 135, 135 (2019)
  65. Asadi N, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Taiwan Inst. Chem. Eng., 95, 252 (2019)
  66. Shahrabi T, Ramezanzadeh B, Bahlakeh G, J. Taiwan Inst. Chem. Eng., 96, 610 (2019)
  67. Amar H, Tounsi A, Makayssi A, Derja A, Benzakour J, Outzourhit A, Corrosion Sci., 49(7), 2936 (2007)
  68. Qiang Y, Guo L, Zhang S, Li W, Yu S, Tan J, Sci. Rep., 6, 33305 (2016)
  69. Qiang Y, Zhang S, Tan B, Chen S, Corrosion Sci., 133, 6 (2018)
  70. Qiang YJ, Zhang ST, Wang LP, Appl. Surf. Sci., 492, 228 (2019)
  71. Hassan HH, Abdelghani E, Amin MA, Electrochim. Acta, 52(22), 6359 (2007)
  72. Mobin M, Aslam R, Process Saf. Environ. Protect., 114, 279 (2018)
  73. Ahmadzadeh M, Shahrabi T, Izadi M, Mohammadi I, Hoseinieh S, Barnoush A, J. Alloy. Compd., 784, 744 (2019)
  74. Akbarzadeh S, Naderi R, Mahdavian M, Compos. Part B Eng., 175, 107109 (2019)
  75. Salehi E, Naderi R, Ramezanzadeh B, Appl. Surf. Sci., 396, 1499 (2017)
  76. Ghafari A, Yousefpour M, Shanaghi A, Appl. Surf. Sci., 465, 427 (2019)
  77. Obot I, Haruna K, Saleh T, Arabian J. Sci. Eng., 44(1), 1 (2019)
  78. Yeganeh M, Omidi M, Rabizadeh T, Prog. Org. Coat., 126, 18 (2019)
  79. Singh A, Soni N, Deyuan Y, Kumar A, Results Phys., 13, 102116 (2019)
  80. Sha JY, Ge HH, Wan C, Wang LT, Xie SY, Meng XJ, Zhao YZ, Corrosion Sci., 148, 123 (2019)
  81. Wen Y, Kong D, Shang W, Ma M, Zhan X, Li Y, Colloids Surf. A: Physicochem. Eng. Asp., 562, 247 (2019)
  82. Majdi MR, Danaee I, Afghahi SSS, Mater. Res., 20(2), 445 (2017)
  83. Akhavan H, Izadi M, Mohammadi I, Shahrabi T, Ramezanzadeh B, J. Electrochem. Soc., 165(10), C670 (2018)
  84. Abboud Y, Abourriche A, Saffaj T, Berrada M, Charrouf M, Bennamara A, Al Himidi N, Hannache H, Mater. Chem. Phys., 105(1), 1 (2007)
  85. Kumawat MK, Thakur M, Gurung RB, Srivastava R, ACS Sustainable Chem. Eng., 5(2), 1382 (2017)
  86. Chidiebere MA, Oguzie EE, Liu L, Li Y, Wang FH, Ind. Eng. Chem. Res., 53(18), 7670 (2014)
  87. Heakal FET, Deyab MA, Osman MM, Elkholy AE, Desalination, 425, 111 (2018)
  88. Zhang L, Zhang S, He Y, Yang R, Ma L, Xia Y, He Z, Int. J. Electrochem. Sci., 13, 2136 (2018)
  89. Kołodziejczak-Radzimska A, Markiewicz E, Jesionowski T, J. Nanomater., 2012 (2012)
  90. Majumder S, Dey S, Bagani K, Dey S, Banerjee S, Kumar S, Dalton Trans., 44(16), 7190 (2015)
  91. Javidparvar A, Ramezanzadeh B, Ghasemi E, Prog. Org. Coat., 90, 10 (2016)
  92. Siddique MN, Ali T, Ahmed A, Tripathi P, Nano-Struct. Nano-Objects, 16, 156 (2018)
  93. Thareja RK, Shukla S, Appl. Surf. Sci., 253(22), 8889 (2007)
  94. Wahab R, Kim YS, Shin HS, Mater. Trans., 50(8), 2092 (2009)
  95. Muster TH, Cole IS, Corrosion Sci., 46(9), 2319 (2004)
  96. Casaletto MP, Figa V, Privitera A, Bruno M, Napolitano A, Piacente S, Corrosion Sci., 136, 91 (2018)
  97. Tuinstra F, Koenig JL, J. Chem. Phys., 53(3), 1126 (1970)
  98. Pimenta M, Dresselhaus G, Dresselhaus MS, Cancado L, Jorio A, Saito R, Phys. Chem. Chem. Phys., 9(11), 1276 (2007)
  99. Amrollahi S, Ramezanzadeh B, Yari H, Ramezanzadeh M, Mahdavian M, Compos. Part B Eng., 173, 106804 (2019)
  100. Akbarzadeh S, Ramezanzadeh B, Bahlakeh G, Ramezanzadeh M, J. Mol. Liq., 296, 111809 (2019)
  101. Farahmand R, Sohrabi B, Ghaffarinejad A, Meymian MRZ, Corrosion Sci., 136, 393 (2018)
  102. Majd MT, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Constr. Build. Mater., 254, 119266 (2020)
  103. Narayan P, Hancock B, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 407(1-2), 226 (2005)
  104. Prochowicz D, Sokołowski K, Lewinski J, Coord. Chem. Rev., 270, 112 (2014)
  105. Hippolyte CN, Serge BY, Sagne A, Creus J, Albert T, J. Mater. Sci. Chem. Eng., 6(03), 100 (2018)
  106. Zhu C, Yang HX, Wang YZ, Chen Y, Gao LX, Ionics, 25(3), 1395 (2019)