Effects of catalyst preparation methods on the performance of La2MMnO6 (M=Co, Ni)double perovskites in catalytic combustion of propane

Hamidreza Roozbahani; Sarah Maghsoodi; Behrouz Raei; Amirhossein Shahbazi Kootenaei; Zoha Azizi

Korean Journal of Chemical Engineering, Vol.39, No.3, 586-595, March, 2022

DOI10.1007/s11814-021-0930-1 Export Citation

Effects of catalyst preparation methods on the performance of La2MMnO6 (M=Co, Ni)double perovskites in catalytic combustion of propane

Hamidreza Roozbahani, Sarah Maghsoodi^†, Behrouz Raei, Amirhossein Shahbazi Kootenaei, and Zoha Azizi

Department of Chemical Engineering, Islamic Azad University, Mahshahr, Iran

E-mail:

La2MMnO6 (M=Co, Ni) dual perovskite oxides were synthesized by sol-gel and gel-combustion methods and tested for the total oxidation of propane. The synthesized catalysts were characterized by TPR, XRD, ICP, SEM, TEM, H2-TPR and O2-TPD techniques. The preparation method had a significant effect on the physicochemical properties of samples. The XRD spectra resulting from the synthesized samples revealed the formation of single-phase perovskite structure. The largest BET specific surface area related to the La2NiMnO6 perovskite synthesized by the gelcombustion method was obtained as 35m2g-1 after calcination at 500℃. Based on the findings, the catalysts synthesized by the gel-combustion method showed an increase in specific surface area, oxygen capacity, reducibility and oxygen mobility compared to those synthesized by the sol-gel method. Accordingly, these catalysts revealed a better performance. The acquired results also showed that the presence of Ni improved the catalytic activity compared to Co. The La2NiMnO6 perovskite synthesized by the gel-combustion method with the T90 equal to 415℃ was found to be the most active catalyst, while the La2CoMnO6 double perovskite synthesized by the sol-gel method with the T90 equal to 474℃ demonstrated the lowest activity.

Keywords:Catalyst;Combustion;Double Perovskite;Sol-gel;Gel-combustion

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[2] Huang Y, Ho SSH, Lu Y, Niu R, Xu L, Cao J, Lee S, Molecules, 21, 56 (2016)

[3] Suib SL, New and future developments in catalysis: Catalysis for remediation and environmental concerns, Newnes (2013).

[4] Kamal MS, Razzak SA, Hossain MM, Atmos. Environ., 140, 117 (2016)

[5] Li WB, Chu WB, Zhuang M, Hua J, Catal. Today, 93-95, 205 (2004)

[6] Li WB, Wang JX, Gong H, Catal. Today, 148, 81 (2009)

[7] Ojala S, Koivikko N, Laitinen T, Mouammine A, Seelam PK, Laassiri S, Ainassaari K, Brahmi R, Keiski RL, Catalysts, 5, 1092 (2015)

[8] Sinquin G, Petit C, Hindermann JP, Kiennemann A, Catal. Today, 70, 183 (2001)

[9] Stege WP, Cad?s LE, Barbero BP, Catal. Today, 172, 53 (2011)

[10] Esmaeilnejad-Ahranjani P, Khodadadi A, Ziaei-Azad H, Mortazavi Y, Chem. Eng. J., 169, 282 (2011)

[11] Liang D, Huang H, Liu JL, Wang HL, Inorg. Chem. Commun., 127, 108533 (2021)

[12] Spinicci R, Delmastro A, Ronchetti S, Tofanari A, Mater. Chem. Phys., 78, 393 (2003)

[13] Zheng J, Lang X, Wang C, ACES, 4, 367 (2014)

[14] Wu Y, Chu B, Zhang M, Yi Y, Dong L, Fan M, Jin G, Zhang L, Li B, Appl. Surf. Sci., 481, 1277 (2019)

[15] Ferri D, Forni L, Appl. Catal. B: Environ., 16, 119 (1998)

[16] Tan X, Han N, Chen H, Su L, Zhang C, Li Y, Ceram. Int., 47, 8762 (2021)

[17] Labhsetwar NK, Watanabe A, Biniwale RB, Kumar R, Mitsuhashi T, Appl. Catal. B: Environ., 33, 165 (2001)

[18] Chen DL, Pan KL, Chang MB, J. Environ. Sci., 56, 131 (2017)

[19] Yoon S, Maegli AE, Karvonen L, Matam SK, Shkabko A, Riegg S, Gro��mann T, Ebbinghaus SG, Pokrant S, Weidenkaff A, J. Solid State Chem., 206, 226 (2013)

[20] de Santana Santos M, Frety R, Lisi L, Cimino S, Brand?o ST, Fuel, 292, 120187 (2021)

[21] Wu Y, Liu H, Li G, Jin L, Li X, Ou X, Dong L, Jin G, Li B, Appl. Surf. Sci., 508, 145158 (2020)

[22] Gallagher PK, Johnson DW, Vogel EM, Schrey F, Mater. Res. Bull., 10, 623 (1975)

[23] Tuza PV, Souza MMVM, Catal. Lett., 146, 47 (2016)

[24] Popescu I, Wu Y, Granger P, Marcu IC, Appl. Catal. A: Gen., 485, 20 (2014)

[25] Onrubia-Calvo JA, Pereda-Ayo B, De-La-Torre U, Gonz?lez-Velasco JR, Appl. Catal. B: Environ., 213, 198 (2017)

[26] Tasca JE, Lavat AE, Gonz?lez MG, J. Asian Ceram. Soc., 5, 235 (2017)

[27] Pan KL, Pan GT, Chong S, Chang MB, J. Environ. Sci., 69, 205 (2018)

[28] Wei Y, Ni L, Li M, Zhao J, Catal. Commun., 155, 106314 (2021)

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[30] Chen X, Carabineiro SAC, Tavares PB, ?rf?o JJM, Pereira MFR, Figueiredo JL, J. Environ. Chem. Eng., 2, 344 (2014)

[31] Li C, Liu B, He Y, Lv C, He H, Xu Y, J. Alloys Compd., 590, 541 (2014)

[32] Miniajluk N, Trawczy?ski J, Zawadzki M, Tylus W, AMPC, 8, 193 (2018)

[33] Wu Y, Li G, Chu B, Dong L, Tong Z, He H, Zhang L, Fan M, Li B, Dong L, Ind. Eng. Chem. Res., 57, 15670 (2018)

[34] Maghsoodi S, Towfighi J, Khodadadi A, Mortazavi Y, Chem. Eng. J., 215-216, 827 (2013)

[35] Liang H, Hong Y, Zhu C, Li S, Chen Y, Liu Z, Ye D, Catal. Today, 201, 98 (2013)

[36] Zhu CQ, Liang H, Li SH, Hong YX, Ye D, Chin. J. Inorg. Chem., 27, 1093 (2011)

[37] Parvizi N, Rahemi N, Allahyari S, Tasbihi M, J. Ind. Eng. Chem., 84, 167 (2020)

[38] Touahra F, Rabahi A, Chebout R, Boudjemaa A, Lerari D, Sehailia M, Halliche D, Bachari K, Int. J. Hydrogen Energy, 41, 2477 (2016)

[39] Pecchi G, Campos C, Pe?a O, Cadus LE, J. Mol. Catal. A: Chem., 282, 158 (2008)

[40] Lavat AE, Baran EJ, J. Alloys Compd., 460, 152 (2008)

[41] Lima SM, Assaf JM, Pe?a MA, Fierro JLG, Appl. Catal. A: Gen., 311, 94 (2006)

[42] Lavat AE, Baran EJ, Vib. Spectrosc., 32, 167 (2003)

[43] Kucharczyk B, Adamska K, Tylus W, Mi?ta W, Szczygie�� B, Winiarski J, Catal. Lett., 149, 1919 (2019)