화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.107, 259-267, March, 2022
Nepenthes pitcher-inspired lubricant-infused slippery surface with superior anti-corrosion durability, hot water repellency and scratch resistance
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Nepenthes pitcher-inspired slippery surface provides an alternative strategy to overcome the shortcomings of the current superhydrophobic surfaces such as thermal–mechanical stability and functional durability. Herein, we fabricate a lubricant-infused slippery surface (LISS) through micro-nano structure building, low surface energy molecular grafting and perfluoropolyethers (PFPE) lubricant oil infusion. The surface morphologies, chemical compositions, wettability, dynamic liquids movement, self-cleaning, anti-corrosion behavior, and thermal–mechanical stability were investigated and analyzed. The electrochemical impedance spectroscopy (EIS) results reveal that the fabricated LISS exhibits enhanced Rct and |Z|0.01Hz values with 2 orders of magnitude higher even after 30 days immersion, demonstrating outstanding long-lasting anti-corrosion properties. Besides, the LISS also exhibits superior capacities of hot water repellency (∼90 °C water droplets) and scratching resistance. We believe these results have significant implications for understanding the design and multi-functional applications of biomimetic liquid-infused slippery materials.
  1. Lin S, Nie Z, Huang H, Li B, Mater. Des., 31, 1607 (2010)
  2. Zhang B, Guan F, Zhao X, Zhang Y, Li Y, Duan J, Hou B, J. Taiwan Inst. Chem. Eng., 97, 433 (2019)
  3. Li Z, Yi D, Tan C, Wang B, J. Alloy. Compd., 817 (2020)
  4. Zhang T, Wang J, Zhang G, Liu H, Corrosion Sci., 176 (2020)
  5. Barthlott W, Neinhuis C, Planta, 202, 1 (1997)
  6. Neinhuis C, Barthlott W, Ann. Bot., 79, 667 (1997)
  7. Feng L, Li S, Li Y, Li H, Zhang L, Zhai J, Song Y, Liu B, Jiang L, Zhu D, Adv. Mater., 14, 1857 (2002)
  8. Wang N, Wang Q, Xu S, Lei L, J. Ind. Eng. Chem., 103, 314 (2021)
  9. Zhang B, Xu W, Xia DH, Fan X, Duan J, Lu Y, Langmuir, 37, 11061 (2021)
  10. Qing Y, Yang C, Yu N, Shang Y, Sun Y, Wang L, Liu C, Chem. Eng. J., 290, 37 (2016)
  11. Ye Y, Liu Z, Liu W, Zhang D, Zhao H, Wang L, Li X, Chem. Eng. J., 348, 940 (2018)
  12. Ye Y, Zhang D, Liu T, Liu Z, Liu W, Pu J, Chen H, Zhao H, Li X, J. Hazard. Mater., 364, 244 (2019)
  13. Zhang B, Xu W, New J. Chem., 45, 15170 (2021)
  14. Zhang B, Li J, Zhao X, Hu X, Yang L, Wang N, Li Y, Hou B, Chem. Eng. J., 306, 441 (2016)
  15. Qi Y, Yang Z, Chen T, Xi Y, Zhang J, Appl. Surf. Sci., 501 (2020)
  16. Li M, Xu X, Zhang L, J. Ind. Eng. Chem., 84, 340 (2020)
  17. Long C, Qing Y, Li S, Cui M, Han M, An K, Long X, Liu C, Liu C, Compos. Pt. B. Eng, 223 (2021)
  18. Qing Y, Shi S, Lv C, Zheng Q, Adv. Funct. Mater., 30, 1910665 (2020)
  19. Zhang L, Xue X, Zhang H, Huang Z, Zhang Z, Compos. Pt. A-Appl. Sci. Manuf., 146 (2021)
  20. Liu Y, Chen X, Xin JH, J. Mater. Chem., 19, 5602 (2009)
  21. Peng S, Yang X, Tian D, Deng W, ACS Appl. Mater. Interfaces, 6, 15188 (2014)
  22. Zhang B, Xu W, Zhu Q, Hou B, J. Mater. Sci. Technol., 66, 74 (2021)
  23. Zulkapli MM, Ghani NSA, Ting TY, Aizat WM, Goh HH, Front. Plant Sci., 11 (2021)
  24. Chen H, Zhang P, Zhang L, Liu H, Jiang Y, Zhang D, Han Z, Jiang L, Nature, 532, 85 (2016)
  25. Wong TS, Kang SH, Tang SKY, Smythe EJ, Hatton BD, Grinthal A, Aizenberg J, Nature, 477, 443 (2011)
  26. Zhang M, Yu J, Wang J, Surf. Coat. Technol., 407 (2021)
  27. Ma Q, Wang W, Dong G, Colloids Surf. A: Physicochem. Eng. Asp., 577, 17 (2019)
  28. Zhang D, Xia Y, Chen X, Shi S, Lei L, Langmuir, 35, 8276 (2019)
  29. Guo P, Sun Y, Zhang Y, Hou X, Song Y, Wang JJ, ChemPhysChem, 20, 946 (2019)
  30. Li P, Cao M, Bai H, Zhao T, Ning Y, Wang X, Liu K, Jiang L, Adv. Funct. Mater., 29, 1904446 (2019)
  31. Long C, Qing Y, An K, Long X, Liu C, Shang S, Yang C, Liu C, Chem. Eng. J., 415 (2021)
  32. Latthe SS, Sutar RS, Bhosale AK, Nagappan S, Ha CS, Sadasivuni KK, Liu S, Xing R, Prog. Org. Coat., 137 (2019)
  33. Liu C, Li Y, Lu C, Liu Y, Feng S, Liu Y, ACS Appl. Mater. Interfaces, 12, 25471 (2020)
  34. Kant K, Pitchumani R, Chem. Eng. Sci., 230 (2021)
  35. Hatte S, Pitchumani R, Soft Matter, 17, 1388 (2021)
  36. Maji K, Das A, Dhar M, Manna U, J. Mater. Chem. A, 8, 25040 (2020)
  37. Feng R, Xu C, Song F, Wang F, Wang XL, Wang YZ, ACS Appl. Mater. Interfaces, 12, 12373 (2020)
  38. He W, Liu P, Zhang J, Yao X, Chem.-Eur. J., 24, 14864 (2018)
  39. Howell C, Grinthal A, Sunny S, Aizenberg M, Aizenberg J, Adv. Mater., 30, 1802724 (2018)
  40. Xiang T, Zhang M, Sadig HR, Li Z, Zhang M, Dong C, Yang L, Chan W, Li C, Chem. Eng. J., 345, 147 (2018)
  41. Long Y, Yin X, Mu P, Wang Q, Hu J, Li J, Chem. Eng. J., 401 (2020)
  42. Cai G, Liu F, Wu T, Colloids Surf. B: Biointerfaces, 202 (2021)
  43. Li H, Feng X, Peng Y, Zeng R, Nanoscale, 12, 7700 (2020)
  44. Wang X, Bai H, Yang J, Li Z, Wu Y, Yu C, Jiang L, Cao M, Small, 17, 2007803 (2021)
  45. Liu G, Zhang C, Liu M, Guo Z, Wang X, Yu C, Cao M, Trans. Tianjin Univ., 26, 441 (2020)
  46. Xia DH, Qin Z, Song S, Macdonald D, Luo JL, Corros. Commun., 2, 1 (2021)
  47. Xia DH, Song S, Tao L, Qin Z, Wu Z, Gao Z, Wang J, Hu W, Behnamian Y, Luo JL, J. Mater. Sci. Technol., 53, 146 (2020)
  48. Xia DH, Pan C, Qin Z, Fan B, Song S, Jin W, Hu W, Prog. Org. Coat., 143 (2020)
  49. Ye Y, Zhang D, Li J, Liu T, Pu J, Zhao H, Wang L, Corrosion Sci., 147, 9 (2019)
  50. Zhang B, Xu W, Zhu Q, Sun Y, Li Y, Corrosion Sci., 158 (2019)
  51. Liu S, Wang X, Tao Y, Han X, Cui C, Appl. Surf. Sci., 484, 403 (2019)
  52. Huang Y, Li Y, Xiao Z, Liu Y, Huang Y, Ren X, J. Alloy. Compd., 673, 73 (2016)