화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.46, No.3, 327-341, May, 2022
DOI10.7317/pk.2022.46.3.327  Export Citation
높은 투명도와 강도를 갖는 자가치료용 Polyurethane: 복합 초분자 상호작용의 영향
A Novel Self-Healing Polyurethane with High Transparency and Strength: Effects of Multiple Supermolecular Forces
Yuan Liu, Yanmei Liao1, Yintao Long1, Yuxiang Qian2, Shengqiang Nie, Yi Wang, Jia Zeng, Chunmei Zhang, Linbo Tian, and Jun Luo†
  • Engineering Research Center for Materials Protection of Wear and Corrosion of Guizhou Province, Guiyang University, Guiyang 550005, China
  • 1State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Guizhou University, Guiyang 550025, China
  • 2Shanghai Space Propulsion Technology Research Institute, No. 3888, Yuanjiang Road, Minhang District, Shanghai 201100, China
E-mail:
It is a considerable challenge for expanding the applications of self-healing polyurethane because of the dilemma in balancing its mechanical and self-healing properties. Herein, a series of self-healing polyurethane systems (PUT-x) with short-range ordered rigid aromatic structures were synthesized by simply adjusting two kinds of diisocyanates, and by ingenious addition of aromatic chain extender. We hope to regulate the π-π interactions and further to manipulate the properties of obtained polyurethanes via adjusting the amount of the benzene rings in the molecular chains of the PUT-x systems. The PUT-5 with decent self-healing ability, optimal mechanical properties, acceptable thermal stability and favorable transparency was selected to incorporate liquid metal and fluorescent powder to fabricate conductive wire and anti-counterfeiting film. Significantly, the liquid metal could be recycled from the conductive wire conveniently without using strong acids or strong bases. Moreover, PUT-5 exemplarily withstood long-term soaking in normal saline, and no deformation could be identified.
Keywords:self-healing;polyurethane;π-π interaction;hydrogen bond;properties
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