Spin crossover bistability in three mutually perpendicular interpenetrated (4,4) nets

Moliner N; Munoz C; Letard S; Solans X; Menendez N; Goujon A; Varret F; Real JA

Inorganic Chemistry, Vol.39, No.23, 5390-5393, 2000

Moliner N, Munoz C, Letard S, Solans X, Menendez N, Goujon A, Varret F, Real JA

The synthesis, crystal structure, magnetic properties, and Mossbauer spectra of [Fe(bpb)(2)(NCS)(2)](.)0.5CH(3)OH (1) (bpb = 1,4-bis(4-pyridyl)-butadiyne) are reported. 1 is a singular example of the interpenetration of three mutually perpendicular nets with spin crossover properties. [GRAPHICS]