An organic/inorganic hybrid salt is obtained by combination of the photochromic nitroprusside complex with the organic donor TTF. The organic part shows an unprecedented 2D organization formed by an orthogonal arrangement of TTF hexamers and monomers. However, the donor layers are formed by pairs of moderately interacting dimeric (TTF)(2)(2+) units surrounded by neutral TTF molecules in such a way that the charge is localized and the compound is a semiconductor. Shea contacts between the organic layers and the nitroprusside anions are present that may affect the photophysical properties of the nitroprusside. [GRAPHICS]