화학공학소재연구정보센터
Journal of Materials Science, Vol.37, No.23, 4985-4992, 2002
Process intensification in particle technology: flow induced phase inversion in the intensive emulsification of epoxy polymer melts in water
The flow induced phase inversion phenomenon is applied to the phase inversion emulsification of high molecular weight epoxy polymer melt to obtain sub-micron particles. It is found that molecular surfactants could not be used to obtain the initial [water-in-polymer melt] emulsion. Polymeric surfactants, hydrophobically modified water soluble polymers have to be used for this purpose. The molecular structure of the polymeric surfactant is important in obtaining smaller emulsion droplets for a given polymer melt. Depending on the processing history, either a 'powdery dispersion' containing 10 wt% water or water continuous dispersion can be obtained. Sub-micron epoxy particles can be obtained, even at relatively low polymeric surfactant concentrations, by subjecting the [water-in-polymer melt] emulsion to very high deformation rates using a model static mixer called Multiple Expansion Contraction Static Mixer. This mixer is essentially a series of short capillaries separated by flow dividers. In order to provide constant flow rate at very high pressures, an injection moulding machine is used.