Journal of Industrial and Engineering Chemistry, Vol.9, No.5, 513-517, September, 2003
Synthesis of Photopolymers Bearing Pendant Cinnamic Ester and Cyclic Carbonate Groups
E-mail:
This study is related to the synthesis of photopolymer bearing pendant cinnamic ester and cyclic carbonate groups by the addition reaction of poly (glycidyl methacrylate-co-acrylonitrile)[poly(GMA-co-AN)] with carbon dioxide and then with cinnamoyl chloride. Quaternary ammonium salts showed good catalytic activity for the synthesis of poly [3-chloro-2-cinnamoyloxy propyl methacrylate-co-(2-oxo-1,3-dioxolane-4-yl) methyl methacrylate-co-acrylonitrile][poly(CNMA-co-DOMA-co-AN)]. The conversion of poly(GMA-co-AN) increased with the increase of alkyl chain length and the nucleophilicity of counter anion of the quaternary salt. Photochemical relation experiments revealed that the photopolymer had good photosensitivity even in the absence of sensitizer.
- Nagamatzu G, Inui H, Photosensitive Polymers, Kodansha, Tokyo (1977)
- Nishikubo T, Synthesis and Application of Photosenstive Polymers, CMC, Tokyo (1979)
- Ichimura K, Kameyama A, Hayashi K, J. Appl. Polym. Sci., 34, 2747 (1987)
- Kato M, Ichijo T, Ishii K, Hasegawa M, J. Polym. Sci. A: Polym. Chem., 9, 2109 (1971)
- Unruh CC, Smith AC, J. Appl. Polym. Sci., 3, 310 (1960)
- Nishikubo T, Ichijyo T, Takaoka T, J. Appl. Polym. Sci., 18, 2009 (1974)
- Subramanian K, Krichnasamy V, Nanjundan S, Reddy AVR, Polym. Int., 49, 579 (2000)
- Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
- Park SY, Lee HS, Ha CS, Park DW, J. Appl. Polym. Sci., 81(9), 2161 (2001)
- Sung CK, Kim KH, Moon JY, Chun SW, Na SE, Park DW, J. Korean Ind. Eng. Chem., 10(1), 129 (1999)
- Nishikubo T, Iizawa T, Saito Y, J. Polym. Sci. A: Polym. Chem., 21, 2291 (1983)
- Funahashi K, Makromol. Chem., 180, 501 (1979)
- Starks CM, Liotta CL, Halpern M, Phase Transfer Catalysis, Chapman & Hall, New York (1994)
- Yang JG, Moon JY, Jung SK, Park DW, Lee JK, J. Korean Ind. Eng. Chem., 7(6), 1156 (1996)
- Kihara N, Endo T, J. Polym. Sci. A: Polym. Chem., 31, 2765 (1993)
- Nishikubo T, Iizawa T, Yamada M, J. Polym. Sci. C: Polym. Lett., 19, 177 (1981)
- Ali AH, Srinivasan KSV, Polym. Int., 43, 310 (1997)
- Park SY, Lee HS, Ha CS, Park DW, J. Appl. Polym. Sci., 81(9), 2161 (2001)
- Park SY, Park HY, Lee HS, Park SW, Ha CS, Park DW, J. Polym. Sci. A: Polym. Chem., 39(9), 1472 (2001)
- Lee DW, M.S. Dissertation, Pusan National University, Busan, Korea (2003)