화학공학소재연구정보센터
Macromolecular Research, Vol.12, No.1, 11-21, February, 2004
Rubber Toughened Epoxy
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Toughening of epoxy resins for improvement of crack resistance has been the subject of intense research interest during the last two decades. Epoxy resins are successfully toughened by blending with a suitable liquid rubber, which initially remains miscible with epoxy and undergoes a phase separation in the course of curing that leads to the formation of a two-phase microstructure, or by directly blending preformed rubbery particle. Unlike the situation for thermoplastics, physical blending is not successful for toughening epoxy resins. Recent advances in the development of various functionalized liquid rubber-based toughening agents and core-shell particles are discussed critically in this review.
  1. Potter WG, Epoxide Resins, Springer, New York (1970)
  2. May CA, Tanka GY, Epoxy Resin Chemistry and Technology, Marcell Dekker, New York (1973)
  3. Bouer RS, Epoxy Resin Chemistry, Advances in Chemistry Series, 114, American Chemical Society, Washington, DC (1979)
  4. Hodd KA, Raptra Rev. Report, 38, 4 (1990)
  5. Bascom WD, Hunston DL, Rubber Toughened Plastics, Advances in Chemistry Series, 222, American Chemical Society, Washington, D.C., pp. 193 (1989)
  6. McGarry FJ, Willner AM, Toughening of an Epoxy Resin by an Elastomer Second Phase, R 68-8, MIT, March (1968)
  7. Sultan JN, McGarry FJ, Polym. Eng. Sci., 13, 29 (1973) 
  8. Sohn JE, Org. Coat. Plast. Chem., 44, 38 (1981)
  9. Daly J, Pethrick RA, Fuller P, Cunliffe AV, Dutta PK, Polymer, 22, 32 (1981) 
  10. Xuzong N, Lijuan W, Rulian X, Yiming L, Yunchao Y, Adhesive Chemistry: Developments and Trends, L.H. Lee, Ed., Plenum, New York, pp. 659 (1984)
  11. Dodiuk H, Kenig S, Liran I, J. Adhes., 22, 227 (1987)
  12. Siebert AR, Riew CK, Org. Coat. Plast. Chem., 31, 552 (1971)
  13. Bascom WD, Moulton RJ, Rowe EJ, Siebert AR, Org. Coat. Plast. Chem., 39, 1964 (1978)
  14. Romanchick WA, Sohn JE, Gaibel JF, Epoxy Resins Chemistry II, R.S. Bauer, Ed., Adv. Chem. Ser., 221, American Chemical Society, Washington, D.C., pp. 93 (1983)
  15. Paul NC, Richards HD, Thomson D, Polymer, 18, 945 (1977) 
  16. Bucknall CB, Partridge IK, Polym. Eng. Sci., 26, 45 (1986) 
  17. Olabisi O, Robeson LM, Shaw MT, Polymer-Polymer Miscibility, Academic Press, London, Chaps. 2&3 (1979)
  18. Flory PJ, Principles of Polymer Chemistry, cornell University Press, Ithaca, NY (1975)
  19. Visconti S, Marchessault RH, Macromolecules, 7, 913 (1974) 
  20. Bitner JL, Rushford JL, Rose WS, Hunston DL, Riew CK, J. Adhes., 13, 3 (1981)
  21. Nae HN, J. Appl. Polym. Sci., 31, 15 (1986) 
  22. Bartlet P, Pascault JP, Sautereau H, J. Appl. Polym. Sci., 30, 2955 (1985) 
  23. Gillham JK, Glandt CA, McPherson CA, Am. Chem. Soc. Div. Org. Coat. Plast. Chem., 37, 195 (1977)
  24. Verchere D, Pascault JP, Sautereau H, Moschair SM, Riccardi CC, Williams RJJ, J. Appl. Polym. Sci., 42, 701 (1991) 
  25. Bird RB, Stewart WE, Lightfoot EN, Transport Phenomena, Wiley, New York (1969)
  26. Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 889 (1981) 
  27. Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 906 (1981)
  28. Hwang JF, Manson JA, Hertzberg RW, Miller GA, Sperling HL, Polym. Eng. Sci., 29, 1466 (1989) 
  29. Manternal S, Pascault JP, Sautereau H, Rubber Toughened Plastics, C.K. Riew, ed., Adv. Chem. Ser., 222, American Chemical Society, Washington, D.C., pp. 193 (1989)
  30. Williams RJJ, Borrajo J, Adabbo HE, Rojas AJ, Rubber Modified Thermoset Resins, C.K. Riew and J.K. Gillham, Eds., Adv. Chem. Ser., 208, American Chemical Society, Washington, D.C., pp. 195 (1984)
  31. Williams RJJ, Adabbo HE, Rojas AJ, Borrajo J, New Polymeric Materials, E. Martuscelli and C. Marchetta, Eds., VNU Science Press, Utrecht (1987)
  32. Vazquez A, Rojas AJ, Adabbo HE, Borrajo J, Williams RJJ, Polymer, 28, 1156 (1987) 
  33. Villiani RV, Bianchi N, Braglia R, Polym. Int., 26, 69 (1991)
  34. Verchere D, Sautereau H, Pascault JP, Moschiar SM, Riccardi CC, Williams RJJ, J. Appl. Polym. Sci., 41, 467 (1990) 
  35. Butta E, Lavita G, Marchetti A, Lazzeri A, Polym. Eng. Sci., 26, 63 (1986) 
  36. Kinloch AJ, Hunston DL, J. Mater. Sci. Lett., 6, 131 (1987) 
  37. Verchere D, Sautereau H, Pascault JP, Moschair SM, Riccardi CC, Williams RJJ, Macromolecules, 23, 725 (1990) 
  38. Roginskya GF, Volkov VP, Vogdanova LM, Chalykh AY, Rosenberg BA, Polym. Sci. USSR, 25, 2305 (1983) 
  39. Hsich HSY, Polym. Eng. Sci., 30, 493 (1990) 
  40. Hsich HSY, J. Mater. Sci., 26, 3209 (1991) 
  41. Yamanka K, Takagi Y, Inoue T, Polymer, 30, 1839 (1989) 
  42. Kim DS, Kim SC, Polym. Eng. Sci., 34(21), 1598 (1994) 
  43. Riew CK, Rubber Chem. Technol., 58, 622 (1985)
  44. Frigione ME, Mascia L, Acierno D, Eur. Polym. J., 31, 1021 (1995) 
  45. Rezaiford AH, Hodd KA, Tod DA, Barton JM, Int. J. Adhes. Adhes., 14, 153 (1994) 
  46. Slysh R, Epoxy Resins, Advances in Chemistry Series, 92, American Chemical Society, Washington, D.C., pp. 108 (1970)
  47. Kemp TJ, Wilford A, Howarth OW, Lee TCP, Polymer, 33, 1860 (1992) 
  48. Mizutani K, J. Mater. Sci., 28, 2178 (1993) 
  49. Frischinger I, Dirlikov SK, Polym. Mater. Sci. Eng., 65, 178 (1991)
  50. Frischinger I, Dirlikov SK, Polym. Mater. Sci. Eng., 70, 1 (1993)
  51. Ratna D, Banthia AK, J. Adhes. Sci. Technol., 14(1), 15 (2000) 
  52. Kinloch AJ, Adhesion and Adhesive; Science and Technology, Chapman Hall, London (1987)
  53. Okamoto Y, Polym. Eng. Sci., 23, 222 (1983) 
  54. Duseck K, Lendnicky F, Lunak S, Mach M, Duskova D, Rubber Modified Thermoset Resins, C.K. Riew, Ed., Adv. Chem. Ser., 208, American Chemical Society, Washington, D.C., pp. 28 (1984)
  55. Jin SJ, Yee AF, Polym. Mater. Sci. Eng., 63, 107 (1990)
  56. Hedric JC, McGrath JE, Polym. Mater. Sci. Eng., 63, 107 (1990)
  57. Shen JS, Shao ZZ, Li SJ, Polymer, 36(18), 3479 (1995) 
  58. Konczol L, Doll W, Buchholz U, Mulhaupt R, J. Appl. Polym. Sci., 54(6), 815 (1994) 
  59. Buchholz U, Mulhaupt R, Polym. Prepr., 33, 205 (1992)
  60. Tong JD, Bai RK, Zou YF, Pan CY, Ichimura S, J. Appl. Polym. Sci., 52(10), 1373 (1994) 
  61. Tong JD, Bai RK, Pan CY, Goethals EJ, J. Appl. Polym. Sci., 57(8), 895 (1995) 
  62. Riffle J, Yilgor I, Banthia AK, Wilkes GL, McGrath JE, Org. Coat. Plast. Chem., 42, 122 (1982)
  63. Riffle J, Yilgor I, Trans C, Wilkes GL, McGrath JE, Banthia AK, Epoxy Resin Chemistry II, ACS Symp. Series, 221, 21 (1983)
  64. Ochi M, Yamana H, Kobunsi Ronbunghu, 49, 499 (1992)
  65. Laurienzo NP, Malinconico M, Martuscelli E, Rongosta G, Valpe MG, J. Mater. Sci., 27, 786 (1992) 
  66. Jackson MB, Edmond LN, Varley RJ, Warden PG, J. Appl. Polym. Sci., 48, 1259 (1993) 
  67. Sasidharan Achary P, Gouri C, Ramamurty R, J. Appl. Polym. Sci., 42, 743 (1991) 
  68. Sasidharan Achary P, Latha PB, Ramaswamy R, J. Appl. Polym. Sci., 41, 151 (1990) 
  69. Wang HB, Li SJ, Ye JY, J. Appl. Polym. Sci., 44, 789 (1989) 
  70. Laeuger J, Albert P, Kressler J, Grouski W, Muelhaupt R, Acta Polym., 46, 68 (1995) 
  71. Lee YD, Wang SK, Chin WK, J. Appl. Polym. Sci., 32, 6317 (1986) 
  72. Banthia AK, Chaturvedi PN, Pendyala VNS, Jha V, Rubber Toughened Plastics, C.K. Riew, ed., Advances in Chemistry Series, 222, American Chemical Society, Washington, D.C., pp. 343 (1989)
  73. Ratna D, Banthia AK, Polym. Int., 49, 281 (2000) 
  74. Ratna D, Banthia AK, Deb PC, J. Appl. Polym. Sci., 78(4), 716 (2000) 
  75. Ratna D, Banthia AK, Deb PC, J. Appl. Polym. Sci., 80(10), 1792 (2001) 
  76. Ratna D, Polymer, 42(9), 4209 (2001) 
  77. Iijima T, Tomoi M, Yamasaki J, Kakiuchi H, Eur. Polym. J., 26, 145 (1990) 
  78. Tomoi M, Yamazaki H, Akada H, Kakiuchi H, Angew. Makromol. Chem., 163, 63 (1988) 
  79. Boogh L, Pettersson B, Manson JAE, Polymer, 40(9), 2249 (1999) 
  80. Wu H, Xu J, Liu Y, Heiden P, J. Appl. Polym. Sci., 72(2), 151 (1999) 
  81. Ratna D, Simon GP, J. Polym. Mater., 19, 349 (2002)
  82. Ratna D, Simon GP, Polym. Eng. Sci., 41(10), 1815 (2001) 
  83. Ratna D, Simon GP, Polymer, 42(21), 8833 (2001) 
  84. Ratna D, Varley R, Raman RKS, Simon GP, J. Mater. Sci., 38(1), 147 (2003) 
  85. Mezzenga R, Boogh L, Manson JAE, J. Polym. Sci. B: Polym. Phys., 38(14), 1883 (2000) 
  86. Sue HJ, Polym. Eng. Sci., 31, 270 (1991) 
  87. Sue HJ, Young RJ, J. Mater. Sci., 31, 275 (1991)
  88. Maazouz A, Sautereau H, Gerard JF, Polym. Bull., 33(1), 67 (1994) 
  89. Nakamura Y, Tabata H, Sujuki H, Iko K, Ocubo M, Matsumoto T, J. Appl. Polym. Sci., 32, 4865 (1986) 
  90. Vanderhoff JW, El-Aasser MS, Micale FJ, Sudol ED, Tseng CM, Silwanowicz A, Shew HR, Kornfeld DM, Polym. Mater. Sci. Eng., 54, 587 (1986)
  91. Ugelstad J, Mork PC, Kaggurud KH, Ellingsen T, Berge A, Adv. Colloid Interface Sci., 13, 101 (1980) 
  92. Barret KEJ, Disperson Polymerization in Organic Media, Wiley, New York (1975)
  93. Shen S, Sudol ED, El-Aasser MS, J. Polym. Sci. A: Polym. Chem., 32, 1393 (1993)
  94. Markel MP, Dimonie VL, El-Aasser MS, Vanderhoff JW, J. Polym. Sci. A: Polym. Chem., 25, 1219 (1987) 
  95. Lee DL, ACS Symp. Ser., 165, 893 (1981)
  96. Jhonson JL, Hassander H, Jansson LH, Tornwell B, Macromolecules, 24, 126 (1991) 
  97. Lee S, Rudin A, ACS Symp. Ser., 492, 234 (1992)
  98. Lin KF, Shieh YD, Polym. Mater. Sci. Eng., 76, 358 (1997)
  99. Sue HJ, Garcia-Maitin EL, Orchard NA, J. Polym. Sci. B: Polym. Phys., 31, 595 (1993) 
  100. Qian JY, Pearson RA, Dimonie VL, El-Aasser MS, J. Appl. Polym. Sci., 58, 139 (1995)
  101. Lin KF, Shieh YD, J. Appl. Polym. Sci., 70(12), 2313 (1998) 
  102. Lin KF, Shieh YD, J. Appl. Polym. Sci., 69(10), 2069 (1998) 
  103. Dompas D, Groeninckx G, Polymer, 35(22), 4743 (1994) 
  104. Dompas D, Groeninckx G, Isogawa M, Hasegawa T, Kadokura M, Polymer, 35(22), 4750 (1994) 
  105. Riew CK, Kinloch AJ, Toughened Plastics I, ACS Advances in Chemistry Series, 233 (1993)
  106. Riew CK, Kinloch AJ, Toughened Plastic II, ACS Advances in Chemistry Series, 252 (1996)
  107. Yamamoto H, Int. J. Fracture, 14, 347 (1978) 
  108. Li D, Chen IW, Chang SC, Takahashi K, Yee AF, J. Mater. Sci., 29(8), 2205 (1994) 
  109. Clarke JA, Rubber Modified Thermoset Resins, C.K. Riew and J.K. Gillham, Eds. Advances in Chemistry Series, 208, American Chemical Society, Washington, D.C., pp. 51 (1984)
  110. Lee BL, Lizak CM, Riew CK, Moulton RJ, Natl. SAMPE Tech. Conference, 12B, 1116 (1980)
  111. Diamant J, Moulton RJ, SAMPA Q., 16, 13 (1984)
  112. Iijima T, Yoshioka N, Tomoi M, Eur. Polym. J., 28, 573 (1992) 
  113. Ratna D, Patri M, Chakraborty BC, Deb PC, J. Appl. Polym. Sci., 65(5), 901 (1997) 
  114. Ratna D, Chakrabarty BC, Deb PC, J. Polym. Mater., 14, 185 (1997)
  115. Lemay JD, Kelley FN, Adv. Polym. Sci., 78, 115 (1986)
  116. Cherry BW, Thomson KW, J. Mater. Sci., 16, 1913 (1981) 
  117. Pearson RA, Yee AF, Polym. Mater. Sci. Eng. Prepr., 186, 316 (1983)
  118. Finch CA, Hashemi S, Kinloch AJ, J. Polym. Commun., 28, 322 (1987)
  119. Levita G, Depetris S, Marchetti A, Lazzeri A, J. Mater. Sci., 26, 2348 (1991) 
  120. Levita G, Rubber Toughened Plastics, C.K. Riew, Ed., Advances in Chemistry Series, 222, American Chemical Society, Washington, D.C., pp. 93 (1989)
  121. Pearce PJ, Ennis BC, Morris CEM, Polym. Commun., 29, 93 (1988)
  122. Pearce PJ, Morris CE, Ennis BC, Polymer, 37(7), 1137 (1996) 
  123. Lin KF, Chung UL, J. Mater. Sci., 29(5), 1198 (1994) 
  124. Siebert AR, Rubber Modified Thermoset Resins, C.K. Riew and J.K. Gillham, Eds., Advances in Chemistry Series, 208, American Chemical Society, Washington, D.C., pp. 179 (1984)
  125. Lowe A, Kwon OH, Mai YW, Polymer, 37(4), 565 (1996) 
  126. Kunz-Douglass S, Beamont PWR, Ashby MF, J. Mater. Sci., 15, 1109 (1980) 
  127. Kunz-Douglass S, Beamont PWR, J. Mater. Sci., 16, 3141 (1981) 
  128. Chen LC, Gillham JK, Kinloch AJ, Shaw ST, Rubber Modified Thermoset Resins, C.K. Riew and J.K. Gillham, Eds., Adv. Chem. Ser., 208, American Chemical Society, Washington, D.C., pp. 235 (1984)
  129. Zeng YB, Zang LZ, Peng WZ, Yu Q, J. Appl. Polym. Sci., 42, 1905 (1991) 
  130. Pearson RA, Yee AF, J. Mater. Sci., 26, 3828 (1991) 
  131. Wu S, Mongolina A, Polymer, 31, 972 (1990) 
  132. Pearson RA, Ph.D. Thesis, The University of Michigan, Ann Arbor (1990)
  133. Kinloch AJ, Hunston DL, J. Mater. Sci. Lett., 6, 137 (1987) 
  134. Kunz SC, Sayre JA, Assink RA, Polymer, 23, 1897 (1982) 
  135. Pearson RA, Yee AF, J. Mater. Sci., 24, 2571 (1989) 
  136. Sue HJ, Garcia-Meitin EI, Pickelman DM, Yang PC, Toughened Plastics, C.K. Riew and A.J. Kinloch, Eds., Adv. Chem. Ser., 233, American Chem. Soc., Washington, pp. 259 (1993)
  137. Bagheri R, Pearson RA, J. Appl. Polym. Sci., 58(2), 427 (1995)