UV-Vis Spectra of N, N'-Bis(4 '-Aminophenyl)-1,4-quinonenediimine Doped with H4SiW12O40

Jian Gong; Xiu-Jun Cui; Ya-Guang Chen; Zhong-Wei Xie; Lun-Yu Qu

Macromolecular Research, Vol.12, No.1, 22-25, February, 2004

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UV-Vis Spectra of N, N'-Bis(4 '-Aminophenyl)-1,4-quinonenediimine Doped with H₄SiW₁₂O₄₀

Jian Gong, Xiu-Jun Cui, Ya-Guang Chen, Zhong-Wei Xie, and Lun-Yu Qu^†

Department of Chemistry, Northeast Normal University, Changchun 130024, China

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We have synthesized aniline oligomer composites by using heteropoly acid (H₄SiW₁₂O₄₀) as a dopant. The doping and dedoping processes of the aniline oligomer composites were investigated with the aid of UV-Vis spectra. The bands of the aniline oligomer at 572 nm weakened or disappeared, and the bands at 268, 412, and 771 nm appeared, after the aniline oligomer was doped. When the solution of the aniline oligomer doped with H₄SiW₁₂O₄₀ was kept at lower values of pH, the aniline oligomer could not be dedoped by dilution. The turning point of doping and dedoping occurred at pH 5.5. The band at 771 nm shifted towards longer wavelengths when the aniline oligomer composites were synthesized using acetone as the solvent. This observation indicates that the molecular chain became stretched. In addition, we also investigated the change of the electronic absorption spectra of the composites with respect to the time laid up.

Keywords:heteropoly acid;aniline oligomer with three units;UV-Vis spectra;doping;dedoping.

[References]

Genies EM, Boyle A, Lapkowshi M, Synth. Met., 36, 136 (1990)
Gong J, Cui XJ, Xie ZW, Wang SG, Qu LY, Synth. Met., 129, 187 (2002)
Chiang JC, MacDiarmid AG, Synth. Met., 13, 193 (1986)
Gong J, Cui XJ, Xie ZW, Qu LY, Chin. Chem. Lett., 13, 123 (2002)
MacDiarmid AG, Chiang JC, Ritcher AF, Epstein AJ, Synth. Met., 18, 285 (1987)
Carllin CM, Kapley LJ, Bard AJ, J. Electrochem. Soc., 132, 353 (1985)
Wang FS, Wang LX, Sci. China, 9 (1989)
Morita M, Komaguchi K, Tsutsumi H, Electrochim. Acta, 37, 1093 (1992)
Lira-Cantu M, Gomea-Romoro P, Chem. Mater., 10, 698 (1998)
Lee SH, Yoon JW, Suh MH, Macromol. Res., 10(5), 282 (2002)
Wei Y, Yang CC, Ding TZ, Tetrahedron Lett., 37, 731 (1996)
Wei Y, Yang CC, Wei C, Feng GZ, Synth. Met., 84, 289 (1997)
Gong J, Yang JH, Cui XJ, Su ZM, Qu LY, Chin. Chem. Lett., 13, 266 (2002)
Gong J, Yang JH, Cui XJ, Wang SG, Su ZM, Qu LY, Synth. Met., 129, 15 (2002)
Pope MT, Muller A, Polyxoxmetalates: from Platonic Solids to Anti-retroviral Activity, Kluwer Academic Publishers, Netherlands (1994)
Gong J, Su ZM, Dai ZM, Wang RS, Qu LY, Synth. Met., 101, 751 (1999)
Gong J, Hua RN, Xie ZW, Wang SG, Qu LY, Polym. J., 33, 377 (2001)
Wilbur JM, Sandreczki TC, Brown IM, Leopold DJ, Mohite S, Synth. Met., 82, 175 (1996)
Xiu ZJ, Qi ZN, Wang FS, Acta Polym. Sinica, 4, 445 (1997)

[1] Genies EM, Boyle A, Lapkowshi M, Synth. Met., 36, 136 (1990)

[2] Gong J, Cui XJ, Xie ZW, Wang SG, Qu LY, Synth. Met., 129, 187 (2002)

[3] Chiang JC, MacDiarmid AG, Synth. Met., 13, 193 (1986)

[4] Gong J, Cui XJ, Xie ZW, Qu LY, Chin. Chem. Lett., 13, 123 (2002)

[5] MacDiarmid AG, Chiang JC, Ritcher AF, Epstein AJ, Synth. Met., 18, 285 (1987)

[6] Carllin CM, Kapley LJ, Bard AJ, J. Electrochem. Soc., 132, 353 (1985)

[7] Wang FS, Wang LX, Sci. China, 9 (1989)

[8] Morita M, Komaguchi K, Tsutsumi H, Electrochim. Acta, 37, 1093 (1992)

[9] Lira-Cantu M, Gomea-Romoro P, Chem. Mater., 10, 698 (1998)

[10] Lee SH, Yoon JW, Suh MH, Macromol. Res., 10(5), 282 (2002)

[11] Wei Y, Yang CC, Ding TZ, Tetrahedron Lett., 37, 731 (1996)

[12] Wei Y, Yang CC, Wei C, Feng GZ, Synth. Met., 84, 289 (1997)

[13] Gong J, Yang JH, Cui XJ, Su ZM, Qu LY, Chin. Chem. Lett., 13, 266 (2002)

[14] Gong J, Yang JH, Cui XJ, Wang SG, Su ZM, Qu LY, Synth. Met., 129, 15 (2002)

[15] Pope MT, Muller A, Polyxoxmetalates: from Platonic Solids to Anti-retroviral Activity, Kluwer Academic Publishers, Netherlands (1994)

[16] Gong J, Su ZM, Dai ZM, Wang RS, Qu LY, Synth. Met., 101, 751 (1999)

[17] Gong J, Hua RN, Xie ZW, Wang SG, Qu LY, Polym. J., 33, 377 (2001)

[18] Wilbur JM, Sandreczki TC, Brown IM, Leopold DJ, Mohite S, Synth. Met., 82, 175 (1996)

[19] Xiu ZJ, Qi ZN, Wang FS, Acta Polym. Sinica, 4, 445 (1997)