Fluorescent Polyurethane Foams Containing Red Fluorescent Perylene Chromophore

Ohyoung Kim; Myoung-Seon Gong

Journal of Industrial and Engineering Chemistry, Vol.10, No.5, 801-805, September, 2004

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Fluorescent Polyurethane Foams Containing Red Fluorescent Perylene Chromophore

Ohyoung Kim , and Myoung-Seon Gong^{1, †}

Department of Polymer Science & Engineering, Dankook University, Seoul 140-714, Korea
¹Department of Chemistry, Dankook University, Cheonam, Chungnam 330-714, Korea

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Reactive red fluorescent dyes based on perylene tetracarboxylic diimide were prepared by reaction of 1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxy anhydride with various alkyl amines and their application to the coloration of polyurethane foams was performed. Fluorescent polyurethane foams were prepared by the reaction of dye0dispersed polyol resin with 4,4'-methylenebis(phenyl isocyanate) in the presence of a blowing agent. The degree of fluorescence of the resulting polyurethane foam is dependent upon the chemical structure of the dye molecule and also it is a function of the solubility of the dye within the monomeric polyol solution.

Keywords:fluorescent red dye;perylene tetracarboxylic diimide;polyurethane;foam

[References]

Wiesel M, Sommer R, Pape G, Kressner M, US Patent 4,026,931 (1977)
Desiderio FA, US Patent 3,954,397 (1977)
Jollinger H, Color Chemistry, VCH, New York (1991)
Feller L, Langhals H, Palborns K, Liebigs Ann., 1229 (1995)
Quante H, Geerts Y, Mullen K, Chem. Mater., 9, 495 (1997)
Quante H, Schlichting P, Rohr U, Geerts Y, Mullen K, Macromol. Chem. Phys., 197, 4029 (1996)
Fabian J, Zahrodnik K, Angew. Chem.-Int. Edit., 28, 677 (1989)
Lee SK, Zu YB, Herrmann A, Geerts Y, Mullen K, Bard AJ, J. Am. Chem. Soc., 121(14), 3513 (1999)
Schneider M, Mullen K, Chem. Mater., 12, 352 (2000)
Marechal E, Prog. Org. Coat., 10, 251 (1982)
Patrick LGF, Whiting A, Dyes Pigment., 52, 137 (2002)
Lee CW, Ko J, Joo SW, Lee SS, Kim JS, Gong MS, Synth. Met., 126, 97 (2002)
Lee CW, Kim O, Ko J, Joo SW, Gong MS, Dyes Pigment., 52, 37 (2002)
Kim DW, Lee CW, Joo SW, Gong MS, J. Lumines., 99, 215 (2002)

[Referenced By]

[Related Articles]

[1] Wiesel M, Sommer R, Pape G, Kressner M, US Patent 4,026,931 (1977)

[2] Desiderio FA, US Patent 3,954,397 (1977)

[3] Jollinger H, Color Chemistry, VCH, New York (1991)

[4] Feller L, Langhals H, Palborns K, Liebigs Ann., 1229 (1995)

[5] Quante H, Geerts Y, Mullen K, Chem. Mater., 9, 495 (1997)

[6] Quante H, Schlichting P, Rohr U, Geerts Y, Mullen K, Macromol. Chem. Phys., 197, 4029 (1996)

[7] Fabian J, Zahrodnik K, Angew. Chem.-Int. Edit., 28, 677 (1989)

[8] Lee SK, Zu YB, Herrmann A, Geerts Y, Mullen K, Bard AJ, J. Am. Chem. Soc., 121(14), 3513 (1999)

[9] Schneider M, Mullen K, Chem. Mater., 12, 352 (2000)

[10] Marechal E, Prog. Org. Coat., 10, 251 (1982)

[11] Patrick LGF, Whiting A, Dyes Pigment., 52, 137 (2002)

[12] Lee CW, Ko J, Joo SW, Lee SS, Kim JS, Gong MS, Synth. Met., 126, 97 (2002)

[13] Lee CW, Kim O, Ko J, Joo SW, Gong MS, Dyes Pigment., 52, 37 (2002)

[14] Kim DW, Lee CW, Joo SW, Gong MS, J. Lumines., 99, 215 (2002)