화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of the Korean Industrial and Engineering Chemistry, Vol.15, No.8, 901-906, December, 2004
Export Citation
고체산 촉매에 의한 바이오매스의 직접 접촉 열분해 반응
Direct Catalytic Pyrolysis of Biomass using Solid Acid Catalysts
전종기, 김지만1, 박영권2, †, 박현주2, 명소영2, 김주식2, 최진희2, 김승도3, 엄유진3
  • 동양대학교 생명화학공학부, 경북 750-711
  • 1아주대학교 분자과학기술학과, 수원 442-749
  • 2서울시립대학교 환경공학부, 서울 130-743
  • 3한림대학교 환경시스템공학과, 강원 200-702
Jong-Ki Jeon, Ji Man Kim1, Young-Kwon Park2, †, Hyun Ju Park2, Soyoung Myung2, Joo-Sik Kim2, Jinhee Choi2, Seungdo Kim3, and Yujin Eom3
  • Department of Chemical Engineering, Dong-Yang University, Young-Jou, Kyungbook 750-711, Korea
  • 1Department of Molecular Science & Technology, Ajou Universty, Suwon 442-749, Korea
  • 2Faculty of Environmental Engineering, University of Seoul, 90, Jeonnong-Dong, Dongdaemun-Gu, Seoul 130-743, Korea
  • 3Department of Environmental System Engineering, Hallym University, Chuncheon, Kangwon 200-702, Korea
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초록
바이오매스의 구성성분인 셀룰로오즈, 리그닌, 헤미셀룰로오즈에 대한 동역학과 촉매 접촉 열분해 반응을 수행하였다. 사용된 촉매는 실리카-알루미나, HZSM-5, HY, mordenite, beta, MCM-41 등이었으며, 촉매를 사용함으로써 바이오매스의 분해 온도를 낮추지는 못하였다. 그러나 촉매는 바이오 오일의 불안정성의 원인중 하나인 산소를 H2O, CO, CO2의 형태로 제거하여 보다 더 안정한 오일을 생성하였다.
Cellulose, hemicellulose and lignin, three main components of biomass, were pyrolyzed over catalysts such as silicaalumina, HZSM-5, HY, Mordenite, Beta and MCM-41, and the kinetic experiments for the catalytic pyrolysis reactions were conducted. The results indicated that by using the solid acid catalysts more stable oil was produced by transforming oxygen, which was the main cause for the instability of bio-oil, into H2O, CO and CO2, even though there was not significant difference in degradation temperature in the presence of catalysts.
Keywords:pyrolysis;biomass;catalyst;bio-oil
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