Journal of Industrial and Engineering Chemistry, Vol.12, No.2, 175-183, March, 2006
Polymer Electrolyte Membranes for Fuel Cells
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Current polymer electrolyte membranes (PEMs) for fuel cells are mostly based on perfluoro-sulfonated acids (PFSA), such as Nafion, Flemion, Aciplex, and Dow membranes. However, scientific and technical improvements are still needed to accommodate the increasing demands of fuel cell systems for specific applications. Higher performance, low cost, greater durability, better water management, and the ability to function at higher temperatures are some of the challenges that must be overcome bofore widespread commercial adoption of fuel cell technology occurs. Approaches and recent progress toward the development of polymer electrolyte membranes for fuel cells are reviewed. The newly developed/developing polymer membranes can be classified into four groups: modified PFSA membranes, alternative sulfonated polymers and their inorganic composite membranes, acid-base complex membranes, and ionic liquid-based gel-typeproton conductiong membranes. These polymer materials have a great variety of chemical structure and may be able to meet the targets for use in advanced fuel cell systems.
Keywords:fuel cell;polymer electrolyte membrane;conductivity;sulfonated polymer;gel-polymer;ionic liquid
- Atkinson S, Membr. Technol., May, 7 (2004)
- Millett S, Mahadevan K, J. Power Sources, 150, 187 (2005)
- Doyle M, Rajendran G, Handbook of Fuel Cells: Fundamentals, Technology, and Applications, W.Vielstich, A. Lamm, H. Gasteiger, Eds., p.351 John Wiley & Sons, Hoboken, N.J. (2003)
- Hilpert K, Handbook of Fuel Cells: Fundamentals, Technology, and Applications, p.1037 John Wiley & Sons, Hoboken, N.J. (2003)
- Lashway RW, MRS Bull., 30, 581 (2005)
- Hickner MA, Ghassemi H, Kim YS, Einsla BR, McGrath JE, Chem. Rev., 104(10), 4587 (2004)
- Li Q, He R, Jensen JO, Bjerrum NJ, Chem. Mater., 15, 4896 (2003)
- Costamagna P, Srinivasan S, J. Power Sources, 102(1-2), 242 (2001)
- Rajendran RG, MRS Bull., 30, 587 (2005)
- Yeo RS, Polymer, 21, 432 (1980)
- Florjanczyk Z, Wielgus-Barry E, Poltarzewski Z, Solid State Ion., 145(1-4), 119 (2001)
- Kimmerle FM, Breault R, Can. J. Chem., 58, 2225 (1980)
- Aldebert P, Guglielmi M, Pineri M, Polymer, 23, 399 (1991)
- Gebel G, Aldebert P, Pineri M, Polymer, 34, 333 (1993)
- Dhar H, U.S. Patent 5242,764 (1993)
- Bahar B, Hobson AR, Kolde JA, Zuckerbrod D, U.S. Patent 5,547,551 (1996)
- Higuchi Y, Terada N, Shimoda H, Hommura S, U.S. Patent application 0026883A1, EP1139472 (2001)
- Nouel KM, Fedkiw PS, Electrochim. Acta, 43(16-17), 2381 (1998)
- Liu W, Ruth K, Rusch G, J. New Mat. Electrochem. Syst., 4, 227 (2001)
- Watanabe M, Uchida H, Seki Y, Emori M, Stonehart P, J. Electrochem. Soc., 143(12), 3847 (1996)
- Mauritz KA, Mater. Sci. Eng., 6, 121 (1998)
- Staiti P, Arico AS, Baglio V, Lufrano F, Passalacqua E, Antonucci V, Solid State Ion., 145(1-4), 101 (2001)
- Yang C, Srinivasan S, Arico AS, Creti P, Baglio V, Antonucci V, Electrochem. Solid State Lett., 4, A31 (2001)
- Alberti G, Costantion U, Allulli S, Tomassini N, J. Inorg. Nucl. Chem., 40, 1113 (1978)
- Yamanaka S, Inorg. Chem., 15, 2811 (1976)
- Yamanaka S, Tanaka M, J. Inorg. Nucl. Chem., 41, 45 (1979)
- Alberti G, Casciola M, Costantion U, Vivani R, Adv. Mater., 8, 291 (1996)
- Alberti G, Boccali L, Casciola M, Massinelli L, Montoneri E, Solid State Ion., 84(1-2), 97 (1996)
- Savadogo O, J. New Mat. Electrochem. Syst., 1, 47 (1998)
- Kreuer KD, J. Membr. Sci., 185(1), 29 (2001)
- Flint SD, Slade RC, Solid State Ion., 97(1-4), 299 (1997)
- Wang F, Roovers J, Macromolecules, 26, 5295 (1993)
- Kobayashi H, Tomita H, Moriyama H, Kobayashi A, Watanabe T, J. Am. Chem. Soc., 116(7), 3153 (1994)
- Qi Z, Pickup PG, Chem. Commun., 15 (1998)
- Kobayashi T, Rikukawa M, Sanui K, Ogata N, Solid State Ion., 106(3-4), 219 (1998)
- Chalk AJ, Hay AS, J. Polym. Sci. A: Polym. Chem., 7, 691 (1968)
- Qi ZG, Lefebvre MC, Pickup PG, J. Electroanal. Chem., 459(1), 9 (1998)
- Johnson BC, Ylgor I, Iqbal M, Wrightman JP, Lliyd DR, McGrath JE, J. Polym. Sci. A: Polym. Chem., 22, 72 (1984)
- Wei XL, Wang YZ, Long SM, Bobeczko C, Epstein AJ, J. Am. Chem. Soc., 118(11), 2545 (1996)
- Miyatake K, Iyotani H, Yamamoto K, Tsuchida E, Macromolecules, 29(21), 6969 (1996)
- Miyatake K, Shouji E, Yamamoto K, Tsuchida E, Macromolecules, 30(10), 2941 (1997)
- Jin X, Bishop MT, Ellis TS, Karasz FE, Br. Polym. J., 17, 4 (1985)
- Lee J, Marvel CS, J. Polym. Sci. A: Polym. Chem., 22, 295 (1984)
- Noshay A, Robeson LM, J. Appl. Polym. Sci., 20, 1885 (1976)
- Litter MI, Marvel CS, J. Polym. Sci. A: Polym. Chem., 23, 2205 (1985)
- Makowsky H, Lundberg RD, Singahl GH, US Patent. US3870841 (1975)
- Bailly C, Williams DJ, Karasz FE, MacKnight WJ, Polymer, 28, 1009 (1987)
- Gieselman MB, Reynolds JR, Macromolecules, 23, 3188 (1990)
- Gieselman MB, Reynolds JR, Macromolecules, 25, 4832 (1992)
- Gieselman MB, Reynolds JR, Macromolecules, 26, 5633 (1993)
- Donoso P, Gorecki W, Berthier C, Dfendini F, Poinsignon C, Armand MB, Solid State Ion., 28, 969 (1988)
- Senadeera GK, Careem MA, Skaarup S, West K, Solid State Ion., 85(1-4), 37 (1996)
- Stevens JR, Wieczorek W, Raducha D, Jeffrey KR, Solid State Ion., 97(1-4), 347 (1997)
- Wieczorek W, Stevens JR, Polymer, 38(9), 2057 (1997)
- Jones DJ, Roziere J, J. Membr. Sci., 185(1), 41 (2001)
- Wainright JS, Wang JT, Weng D, Savinell RF, Litt M, J. Electrochem. Soc., 142(7), L121 (1995)
- Petty-Weeks S, Zupanic JJ, Swedo JR, Solid State Ion., 31, 117 (1988)
- Tanaka R, Yammoto H, Kawamura S, Iwase T, Electrochim. Acta, 40(13-14), 2421 (1995)
- Weng D, Wainright JS, Landau U, Savinell RF, J. Electrochem. Soc., 143(4), 1260 (1996)
- Tanaka R, Yamamoto H, Shono A, Kubo K, Sakurai M, Electrochim. Acta, 45(8-9), 1385 (2000)
- Zaidi SMJ, Chen SF, Mikhaikenko SD, Kaliaguine S, J. New Mat. Electrochem. Syst., 3, 27 (2000)
- Lassegues JC, Grondin J, Hernandez M, Maree B, Solid State Ion., 145(1-4), 37 (2001)
- Peled E, Duvdevani T, Melman A, Electrochem. Solid State Lett., 1, 210 (1998)
- Raducha D, Wieczorek W, Florjanczyk Z, Stevens JR, J. Phys. Chem., 100(51), 20126 (1996)
- Zukowska G, Rogowska M, Weczkowska E, Wieczorek W, Solid State Ion., 119(1-4), 289 (1999)
- Ericson H, Svanberg C, Brodin A, Grillone AM, Panero S, Scrosati B, Jacobsson P, Electrochim. Acta, 45(8-9), 1409 (2000)
- Nakamura O, Kodama T, Ogino I, Miyake Y, Chem. Lett., 17 (1979)
- Hatakeyama K, Sakaguchi H, Ogawa K, Inoue H, Iwakura C, Esaka T, J. Power Sources, 124(2), 559 (2003)
- Lee JS, Bae JY, Lee H, Quan ND, Kim HS, Kim H, J. Ind. Eng. Chem., 10(7), 1086 (2004)
- Welton T, Chem. Rev., 99(8), 2071 (1999)
- Ogihara W, Sun JZ, Forsyth M, MacFarlane DR, Yoshizawa M, Ohno H, Electrochim. Acta, 49(11), 1797 (2004)
- Nakagawa H, Izuchi S, Kuwana K, Nukuda T, Aihara Y, J. Electrochem. Soc., 150, 695 (2003)
- Doyle M, Choi SK, Proulx G, J. Electrochem. Soc., 147(1), 34 (2000)
- Susan MABH, Noda A, Mitsushima S, Watanabe M, Chem. Commun., 938 (2003)
- Lewandowski A, Swiderska A, Solid State Ion., 161(3-4), 243 (2003)
- Ue M, Takeda M, Toriumi A, Kominato A, Hagiwara R, Ito Y, J. Electrochem. Soc., 150, 499 (2003)
- Lewandowski A, Galinski M, J. Phys. Chem. Solids, 65, 281 (2004)
- Matsumoto H, Matsuda T, Tsuda T, Hagiwara R, Ito Y, Miyazaki Y, Chem. Lett., 26 (2001)
- Mikoshiba S, Murai S, Sumino H, Hayase S, Chem. Lett., 1156 (2002)
- Wang P, Zakeeruddin SM, Comte P, Exnar I, Gratzel M, J. Am. Chem. Soc., 125(5), 1166 (2003)
- Lu W, Fadeev AG, Qi BH, Smela E, Mattes BR, Ding J, Spinks GM, Mazurkiesics J, Zhou D, Wallace GG, MacFarlane DR, Forsyth SA, Forsyth M, Science, 297, 983 (2002)
- Noda A, Susan AB, Kudo K, Mitsushima S, Hayamizu K, Watanabe M, J. Phys. Chem. B, 107(17), 4024 (2003)
- de Souza RF, Padilha JC, Goncalves RS, Dupont J, Electrochem. Commun., 5, 728 (2003)
- Fuller J, Breda AC, Carlin RT, J. Electrochem. Soc., 144(4), L67 (1997)
- Ohno H, Ito K, Chem. Lett., 751 (1998)
- Kreuer KD, Fuchs A, Ise M, Spaeth M, Maier J, Electrochim. Acta, 43(10-11), 1281 (1998)
- Li ZY, Liu HT, Liu Y, He P, Li JH, J. Phys. Chem. B, 108(45), 17512 (2004)
- Navarra MA, Panero S, Scrosati B, Electrochem. Solid State Lett., 8, A324 (2005)
- Huang JF, Luo HM, Liang CD, Sun IW, Baker GA, Dai S, J. Am. Chem. Soc., 127(37), 12784 (2005)
- Yoshizawa H, Ohno H, Chem. Commun., 1828 (2004)
- Hagiwara R, Nohira T, Matsumoto K, Tamba Y, Electrochem. Solid State Lett., 8, A231 (2005)