Korea-Australia Rheology Journal, Vol.18, No.1, 9-14, March, 2006
On the congruence of some network and pom-pom models
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We show that some network and pom-pom constitutive models are essentially the same. Instead of the usual confrontation, we suggest that the two approaches can offer useful mutual support: vital information about network destruction rates found from detailed pom-pom calculations can be used to improve the network models, while deductions about network creation rates can pinpoint areas needing further attention in the tube modelling area. A new form of the PTT model, the PTT-X model, results in improved shear and elongational flow descriptions, plus an improved recoil behaviour. The remaining problems of strain-time separation, second normal stress difference description, and reduction of parameters are also discussed and some suggestions for progress are offered.
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