Reaction rate of carbon dioxide in glycidyl methacrylate solution using tricaprylylmethylammonium chloride as a catalyst

Sang-Wook Park; Dae-Won Park; Jae-Wook Lee

Korean Journal of Chemical Engineering, Vol.23, No.4, 645-649, July, 2006

Sang-Wook Park^†, Dae-Won Park , and Jae-Wook Lee¹

Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
¹Department of Chemical Engineering, Sogang University, Seoul 121-742, Korea

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Carbon dioxide was absorbed into organic solutions of glycidyl methacrylate (GMA) in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa to measure absorption rates of carbon dioxide, from which the reaction kinetics between carbon dioxide and GMA were studied by using tricaprylylmethylammonium chloride catalyst. The reaction rate constants of the reaction were estimated by using the mass transfer mechanism accompanied by the pseudo-first-order reaction. An empirical correlation formula between the reaction rate constants and the solubility parameters of solvents such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide was presented.

Keywords:Absorption;Carbon Dioxide;Glycidyl Methacrylate;Tricaprylylmethyl-ammonium Chloride

[References]

Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
Brandrup J, Immergut EH, Polymer Handbook, Second Ed., John Wiley & Sons, New York (1975)
Danckwerts PV, Gas-Liquid Reaction, McGraw-Hill Book Company, New York (1970)
Doraiswamy LK, Sharma MM, Heterogeneous Reaction: Analysis, Example and Reactor Design, John Wiley & Sons, New York, 17-26 (1984)
Herbrandson HF, Neufeld FR, J. Org. Chem., 31, 1140 (1966)
Inoue S, In organic and bioorganic chemistry of carbon dioxide, S. Inoue and N. Yamazaki, Eds. Kodansha Ltd., Tokyo (1982)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Morrison RT, Boyd RN, Organic Chemistry, Fourth Ed., Allyn and Bacon, Inc., Toronto, 244-246 (1983)
Nishikubo T, Kameyama A, Yamashita J, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939 (1993)
Park SW, Cho HB, Park DW, J. Ind. Eng. Chem., 9(4), 464 (2003)
Park SW, Choi BS, Kim SS, Lee JW, Korean J. Chem. Eng., 21(6), 1205 (2004)
Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)
Rokicki G, Makromol. Chem., 186, 331 (1985)
Rokicki G, Pawlicki J, Kurau W, Polym. J., 17, 509 (1985)

[Referenced By]

[Related Articles]

[1] Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)

[2] Brandrup J, Immergut EH, Polymer Handbook, Second Ed., John Wiley & Sons, New York (1975)

[3] Danckwerts PV, Gas-Liquid Reaction, McGraw-Hill Book Company, New York (1970)

[4] Doraiswamy LK, Sharma MM, Heterogeneous Reaction: Analysis, Example and Reactor Design, John Wiley & Sons, New York, 17-26 (1984)

[5] Herbrandson HF, Neufeld FR, J. Org. Chem., 31, 1140 (1966)

[6] Inoue S, In organic and bioorganic chemistry of carbon dioxide, S. Inoue and N. Yamazaki, Eds. Kodansha Ltd., Tokyo (1982)

[7] Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)

[8] Kihara N, Endo T, Macromolecules, 25, 4824 (1992)

[9] Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)

[10] Morrison RT, Boyd RN, Organic Chemistry, Fourth Ed., Allyn and Bacon, Inc., Toronto, 244-246 (1983)

[11] Nishikubo T, Kameyama A, Yamashita J, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939 (1993)

[12] Park SW, Cho HB, Park DW, J. Ind. Eng. Chem., 9(4), 464 (2003)

[13] Park SW, Choi BS, Kim SS, Lee JW, Korean J. Chem. Eng., 21(6), 1205 (2004)

[14] Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)

[15] Rokicki G, Makromol. Chem., 186, 331 (1985)

[16] Rokicki G, Pawlicki J, Kurau W, Polym. J., 17, 509 (1985)