In this paper, the authors investigated the adsorption phenomenon of compact chains confined between two parallel plane boundaries using a pruned-enriched Rosenbluth method. The authors considered three cases with different adsorption energies of epsilon = 0, -1, and -3 (in units of k(B)T) for the confined compact chains of different chain lengths N, respectively. Several parameters were employed to describe the size and shape of compact chain, and some special behaviors in the conformational structures were investigated for the first time. For example, the size and shape of confined compact chains undergo distinct changes in the adsorption cases of epsilon = - 1 and -3, and pass through the maximum values at the characteristic distances D,. The authors found that this characteristic distance D-c could be scaled as D-c similar to (N + 1)(v) (v = 0.56 +/- 0.01) in the case of epsilon = -3. In addition, the microstructures of chains were investigated, and several significant results were obtained by analyzing the segment density distribution and the mean fractions of segment in tails, trains, bridges, and loops structures. On the other hand, the thermodynamic properties were also investigated for the confined compact chains, such as average energy per bond, Helmholtz free energy per bond, and elastic force per bond. Results show that elastic forces f have different behaviors in three cases, indicating that it is not necessary to exert an external force on the boundaries in the nonadsorption case. At the same time, the average contact energy of compact chain obviously changes when the distance between the two parallel boundaries D increases, which is similar to those of the size and shape parameters. The authors also conclude that these thermodynamic properties of compact chains depend strongly on not only the adsorption energies but also the chain lengths and the confined condition. In addition, several results of the conformational and thermodynamic parameters, such as the segment density distribution and free energy, were compared with the results from the self-consistent field theory. These investigations may help us to deepen the knowledge about the adsorption phenomenon of confined compact chains. (c) 2006 Wiley Periodicals, Inc.