화학공학소재연구정보센터
Macromolecular Rapid Communications, Vol.25, No.10, 995-999, 2004
Copolymerization of propene and buta-1,3-diene in the presence of highly hindered C-2-symmetric zirconocene-based catalyst
Copolymerizations of propene and buta-1,3-diene performed in the presence of rac-[CH2(3-tert-butyl-1-indenyl)(2)]ZrCl2 and methylaluminoxane (MAO) have been investigated. Buta-1,3-diene gives prevailingly primary coordination to the metal, producing overall 1,2 units. Cyclopropane and cyclopentane rings, although in low amounts, are also obtained. The presence of butadiene would be responsible for some regioirregular 2,1-inserted propene units, which at high temperatures give rearrangement to 3,1 units.