Macromolecular Rapid Communications, Vol.25, No.10, 1000-1003, 2004
Synthesis and properties of a novel thiophene-based conducting copolymer with mesogenic groups attached parallel to the polymer backbone
A novel thiophene-based conducting copolymer has been synthesised with mesogenic groups attached parallel to the conducting polymer backbone; preliminary data are reported on its properties. These indicate that as the nonmesogenic intermediate polymer is converted into a liquid-crystalline polymer there is a significant increase in conductivity. Measurement of the temperature-dependent conductivity indicates a reduction of the activation energy in the liquid-crystalline phase.
Keywords:liquid-crystal line polymers (LCP);parallel attached;polythiophene;sideways attached;synthesis