모멘트 법을 이용한 그래파이트의 1,2-디클로로벤젠 흡착특성 연구

남경수; 권상숙; 유경선; Kyung Soo Nam; Sang Soog Kwon; Kyung Seun Yoo

Journal of the Korean Industrial and Engineering Chemistry, Vol.18, No.6, 603-606, December, 2007

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모멘트 법을 이용한 그래파이트의 1,2-디클로로벤젠 흡착특성 연구

Study of 1,2-Dichlorobenzene Adsorption Characteristics on Graphite using Moment Method

남경수, 권상숙, 유경선 ^†

광운대학교 환경공학과

Kyung Soo Nam, Sang Soog Kwon, and Kyung Seun Yoo^†

Department of Environmental Engineering, Kwangwoon University, Seoul 139-701, Korea

E-mail:

초록

ECD가 장착된 기체크로마토그래프를 이용하여 다이옥신과 구조적으로 유사한 1,2-디클로로벤젠의 그래파이트 흡착특성을 고찰하였다. 그래파이트에서 1,2-디클로로벤젠의 평형흡착상수는 흡착온도 220, 240, 260 ℃에서 각각 10.333, 6.167, 4.270m3/kg 값을 나타내었다. 표면 흡착열은 11.554 kcal/mol로 나타났으며 이는 그래파이트의 비표면적이 작고 표면기능기의 양이 적었기 때문이다.

Gas chromatograph equipped with ECD (Electron Ionization Detector) was used to investigate the adsorption characteristics of 1,2-dichlorobenzene, which has a similar structure with dioxin, on graphite. Equilibrium adsorption constants of 1,2-dichlorobenzene on graphite were measured as 10.333, 6.167 and 4.270 m3/kg at 220, 240, 260 ℃, respectively. The isosteric heat of adsorption of 1,2-dichlorobenzene on graphite was 11.554 kcal/mol. This was because specific surface area was low and the amount of surface functional groups was small.

Keywords:adsorption;moment method;graphite;1,2-dichlorobenzene

[References]

Ruthven DM, Principle of Adsorption and Adsorption Process, 1, 6, John Wiley and Sons, New York (1984)
Shin JW, Park SY, Song KS, Yoo KS, J. Ind. Eng. Chem., 12, 428 (2006)
Kwon S, Vidic R, Borguet E, Surf. Sci., 522, 17 (2003)
Rodriguez-reinoso F, Carbon, 36, 159 (1998)
Diaz E, Ordonez S, Vega A, J. Colloid Interface Sci., 305(1), 7 (2007)
Ousalem M, Zhu XX, Hradil J, J. Chromatogr. A, 903, 13 (2000)
Shin JW, Master Thesis, Kwangwoon Univ., Seoul, Korea (2003)
Grajek H, Witkiewicz Z, Jankowska H, J. Chromatogr. A, 782, 87 (1997)
Chihara K, Suzuki M, Kwazoe K, AIChE J., 24, 237 (1978)
Nam KS, Kwon SS, Yoo KS, J. Korean Ind. Eng. Chem., 18(3), 245 (2007)

[Related Articles]

[1] Ruthven DM, Principle of Adsorption and Adsorption Process, 1, 6, John Wiley and Sons, New York (1984)

[2] Shin JW, Park SY, Song KS, Yoo KS, J. Ind. Eng. Chem., 12, 428 (2006)

[3] Kwon S, Vidic R, Borguet E, Surf. Sci., 522, 17 (2003)

[4] Rodriguez-reinoso F, Carbon, 36, 159 (1998)

[5] Diaz E, Ordonez S, Vega A, J. Colloid Interface Sci., 305(1), 7 (2007)

[6] Ousalem M, Zhu XX, Hradil J, J. Chromatogr. A, 903, 13 (2000)

[7] Shin JW, Master Thesis, Kwangwoon Univ., Seoul, Korea (2003)

[8] Grajek H, Witkiewicz Z, Jankowska H, J. Chromatogr. A, 782, 87 (1997)

[9] Chihara K, Suzuki M, Kwazoe K, AIChE J., 24, 237 (1978)

[10] Nam KS, Kwon SS, Yoo KS, J. Korean Ind. Eng. Chem., 18(3), 245 (2007)