Solvent Effect on the Hydrosilylation Reactions for the Synthesis of Polydimethylsiloxane Grafted with Polyoxyethylene Catalyzed by Speier’s Catalyst

Dae-won Chung; Tae Gil Kim

Journal of Industrial and Engineering Chemistry, Vol.13, No.6, 979-984, November, 2007

Dae-won Chung^†, and Tae Gil Kim

Department of Polymer Engineering, University of Suwon, Gyeonggi-do 445-743, Korea

E-mail:

Polydimethylsiloxane grafted with polyoxyethylene was synthesized through hydrosilylation reactions in the presence of Speier’s catalyst and the solvent effect was investigated. Among the five solvents studied, acetonitrile (ACN) showed extremely low reactivity; the reactivities increased in the order ACN

Keywords:polydimethylsiloxane;polyoxyethylene;Speier’s catalyst;hydrosilylation

[References]

Hill RM, Specialist Surfactants, I. D. Robb Ed., Blackie, London (1997)
Riess G, Hurterz G, Bahadur P, Encyclopedia of Polymer Science and Engineering, 2nd Edn., p. 324, Wiley, New York (1985)
Fink HF, Tenside Surf. Det., 28, 5 (1991)
Speier JL, Adv. Organomet. Chem., 17, 407 (1979)
Sacarescu L, Ardeleanu R, Sacarescu G, Simionescu M, Eur. Polym. J., 40, 57 (2004)
Lamoreaux HF, Schenectady NY, U. S. Patent 3, 220, 972 (1965)
Lewis LN, Sumpter CA, J. Mol. Catal. A-Chem., 104, 293 (1996)
Cai GP, Weber WP, Polymer, 45(9), 2941 (2004)
Louis E, Jussofie I, Kuhn FE, Herrmann WA, J. Org. Chem., 691, 2031 (2006)
Chung DW, Kim TG, J. Ind. Eng. Chem., 13(4), 571 (2007)
Hou SS, Chung YP, Chan CK, Kuo PL, Polymer, 41(9), 3263 (2000)
Vadala ML, Rutnakornpituk M, Zalich MA, St Pierre TG, Riffle JS, Polymer, 45(22), 7449 (2004)
Chung DW, Kim JP, Kim D, Lim J, J. Ind. Eng. Chem., 12(5), 783 (2006)
Marciniec B, Gulinski J, Urbaniak W, Kornetka ZW, Comprehensive handbook on hydrosilylation, B. Marciniec Ed., pp. 42-43, Pergamon, Oxford (1992)
Nagatani N, Fukuda K, Suzuki T, J. Colloid Interface Sci., 234(2), 337 (2001)
Takeuchi K, Yoshino K, Suzuki Y, Kawamata A, J.P. Patent 4108795 (1992)
Ganicz T, Mizerska U, Moszner M, O'Brien M, Perry R, Stanczyk WA, Appl. Catal. A: Gen., 259(1), 49 (2004)
Feng S, Cui M, React. Funct. Polym., 45, 79 (2000)
Iojoiu C, Abadie MJ, Harabagiu V, Pinteala M, Eur. Polym. J., 36, 2115 (2000)
Meth S, Sukenik CN, Thin Solid Films, 425(1-2), 49 (2003)
Ho TH, Wang CS, Eur. Polym. J., 37, 267 (2001)
Choi KM, Mater. Chem. Phys., 103(1), 176 (2007)
Phan ST, Lim WC, Han JS, Jung IN, Yoo BR, J. Organomet. Chem., 691, 604 (2006)
Pesek JJ, Matyska MT, J. Chrom., 887, 31 (2000)
Bulgakova SA, Mazanova LM, Semenov VV, Semchikov YD, Eur. Polym. J., 43, 644 (2007)
Senthilkumar U, Reddy BSR, J. Membr. Sci., 232(1-2), 73 (2004)

[Referenced By]

[Related Articles]

[1] Hill RM, Specialist Surfactants, I. D. Robb Ed., Blackie, London (1997)

[2] Riess G, Hurterz G, Bahadur P, Encyclopedia of Polymer Science and Engineering, 2nd Edn., p. 324, Wiley, New York (1985)

[3] Fink HF, Tenside Surf. Det., 28, 5 (1991)

[4] Speier JL, Adv. Organomet. Chem., 17, 407 (1979)

[5] Sacarescu L, Ardeleanu R, Sacarescu G, Simionescu M, Eur. Polym. J., 40, 57 (2004)

[6] Lamoreaux HF, Schenectady NY, U. S. Patent 3, 220, 972 (1965)

[7] Lewis LN, Sumpter CA, J. Mol. Catal. A-Chem., 104, 293 (1996)

[8] Cai GP, Weber WP, Polymer, 45(9), 2941 (2004)

[9] Louis E, Jussofie I, Kuhn FE, Herrmann WA, J. Org. Chem., 691, 2031 (2006)

[10] Chung DW, Kim TG, J. Ind. Eng. Chem., 13(4), 571 (2007)

[11] Hou SS, Chung YP, Chan CK, Kuo PL, Polymer, 41(9), 3263 (2000)

[12] Vadala ML, Rutnakornpituk M, Zalich MA, St Pierre TG, Riffle JS, Polymer, 45(22), 7449 (2004)

[13] Chung DW, Kim JP, Kim D, Lim J, J. Ind. Eng. Chem., 12(5), 783 (2006)

[14] Marciniec B, Gulinski J, Urbaniak W, Kornetka ZW, Comprehensive handbook on hydrosilylation, B. Marciniec Ed., pp. 42-43, Pergamon, Oxford (1992)

[15] Nagatani N, Fukuda K, Suzuki T, J. Colloid Interface Sci., 234(2), 337 (2001)

[16] Takeuchi K, Yoshino K, Suzuki Y, Kawamata A, J.P. Patent 4108795 (1992)

[17] Ganicz T, Mizerska U, Moszner M, O'Brien M, Perry R, Stanczyk WA, Appl. Catal. A: Gen., 259(1), 49 (2004)

[18] Feng S, Cui M, React. Funct. Polym., 45, 79 (2000)

[19] Iojoiu C, Abadie MJ, Harabagiu V, Pinteala M, Eur. Polym. J., 36, 2115 (2000)

[20] Meth S, Sukenik CN, Thin Solid Films, 425(1-2), 49 (2003)

[21] Ho TH, Wang CS, Eur. Polym. J., 37, 267 (2001)

[22] Choi KM, Mater. Chem. Phys., 103(1), 176 (2007)

[23] Phan ST, Lim WC, Han JS, Jung IN, Yoo BR, J. Organomet. Chem., 691, 604 (2006)

[24] Pesek JJ, Matyska MT, J. Chrom., 887, 31 (2000)

[25] Bulgakova SA, Mazanova LM, Semenov VV, Semchikov YD, Eur. Polym. J., 43, 644 (2007)

[26] Senthilkumar U, Reddy BSR, J. Membr. Sci., 232(1-2), 73 (2004)