Measurement and correlation of high pressure phase behavior of carbon dioxide + water system

Ji Min Han; Hun Yong Shin; Byoung-Moo Min; Keun-Hee Han; Ara Cho

Journal of Industrial and Engineering Chemistry, Vol.15, No.2, 212-216, March, 2009

DOI10.1016/j.jiec.2008.09.012 Export Citation

Measurement and correlation of high pressure phase behavior of carbon dioxide + water system

Ji Min Han, Hun Yong Shin^†, Byoung-Moo Min¹, Keun-Hee Han¹, and Ara Cho¹

Department of Chemical Engineering, Seoul National University of Technology, Gongreung 2-dong, Nowon-gu, Seoul 139-743, Republic of Korea
¹Climate Change Technology Research Department, Korea Institute of Energy Research, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343, Republic of Korea

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A visual and variable volume view cell analyzer was installed and the phase behaviors of the carbon dioxide + water system were measured in the temperature and pressure ranges from 313.2 K to 343.2 K and from 4.33 MPa to 18.34 MPa, respectively. The measured data were correlated with the MF-NLF-HB equation of state to consider the effects of the hydrogen bonding of the saturated liquid and vapor mixture. The calculated data agree well with the measured data within an absolute average error deviation of 5%. The fraction of hydrogen bonding could be calculated by the MF-NLF-HB EOS for the carbon dioxide + water system with the obtained VLE data. The calculated hydrogen bonding fraction of the saturated liquid phase of the mixture decreased with increasing pressure in the isothermal calculations. The hydrogen bond strength was affected by the concentration of carbon dioxide and solubility of carbon dioxide was affected by pressure. The calculated hydrogen bonding fraction of the saturated vapor phase of the mixture had a minimum value near 10 MPa for the three isothermal calculations.

Keywords:Water;Carbon dioxide;Vapor liquid equilibrium;Hydrogen bonding

[References]

Gillespie PC, Wilson GM, Gas Processor Association Research Report RR-48, Tulsa OK (1982)
Nakayama T, Sagara H, Arai K, Saito S, Fluid Phase Equilibr, 38, 109 (1987)
Yoon YI, Baek IH, Park SD, J. Ind. Eng. Chem., 13(5), 842 (2007)
Nighswander JA, Kalogerakis N, Mehrotra AK, J. Chem. Eng. Data, 34, 335 (1989)
Zawisza A, Malesinska B, J. Chem. Eng. Data, 26, 388 (1981)
Lin CC, Chen BC, J. Ind. Eng. Chem., 13(7), 1083 (2007)
Takenouchi S, Kennedy GC, Am. J. Sci., 262, 1055 (1964)
Wiebe R, Gaddy VL, Am. J. Chem. Soc., 62, 815 (1940)
Zheng DQ, Guo TM, Knapp H, Fluid Phase Equilib., 129(1-2), 197 (1997)
DSouza R, Patrick JR, Teja AS, Can. J. Chem. Eng., 66, 319 (1988)
Day CY, Chang CJ, Chen CY, J. Chem. Eng. Data, 41(4), 839 (1996)
Shin HY, Haruki M, Yoo KP, Iwai Y, Arai Y, Fluid Phase Equilib., 189(1-2), 49 (2001)
Gupta RB, Panayiotou CG, Sanchez IC, Johnston KP, AIChE J., 38, 1243 (1992)
Kehiaian HV, Grolier JPE, Kechavarz MR, Benson GC, Fluid Phase Equilibr., 5, 159 (1981)
Briones JA, Mullins JC, Thies MC, Kim BU, Fluid Phase Equilibr., 36, 235 (1987)

[Referenced By]

[Related Articles]

[1] Gillespie PC, Wilson GM, Gas Processor Association Research Report RR-48, Tulsa OK (1982)

[2] Nakayama T, Sagara H, Arai K, Saito S, Fluid Phase Equilibr, 38, 109 (1987)

[3] Yoon YI, Baek IH, Park SD, J. Ind. Eng. Chem., 13(5), 842 (2007)

[4] Nighswander JA, Kalogerakis N, Mehrotra AK, J. Chem. Eng. Data, 34, 335 (1989)

[5] Zawisza A, Malesinska B, J. Chem. Eng. Data, 26, 388 (1981)

[6] Lin CC, Chen BC, J. Ind. Eng. Chem., 13(7), 1083 (2007)

[7] Takenouchi S, Kennedy GC, Am. J. Sci., 262, 1055 (1964)

[8] Wiebe R, Gaddy VL, Am. J. Chem. Soc., 62, 815 (1940)

[9] Zheng DQ, Guo TM, Knapp H, Fluid Phase Equilib., 129(1-2), 197 (1997)

[10] DSouza R, Patrick JR, Teja AS, Can. J. Chem. Eng., 66, 319 (1988)

[11] Day CY, Chang CJ, Chen CY, J. Chem. Eng. Data, 41(4), 839 (1996)

[12] Shin HY, Haruki M, Yoo KP, Iwai Y, Arai Y, Fluid Phase Equilib., 189(1-2), 49 (2001)

[13] Gupta RB, Panayiotou CG, Sanchez IC, Johnston KP, AIChE J., 38, 1243 (1992)

[14] Kehiaian HV, Grolier JPE, Kechavarz MR, Benson GC, Fluid Phase Equilibr., 5, 159 (1981)

[15] Briones JA, Mullins JC, Thies MC, Kim BU, Fluid Phase Equilibr., 36, 235 (1987)