A life-cycle inventory model for the office buildings is developed in this paper. The environmental effects of two different building structures, steel and concrete, are intercompared. The results show that the steel-framed building is superior to the concrete-framed building on the following two indexes, the life-cycle energy consumption and environmental emissions of building materials. It is found that the life-cycle energy consumption of building materials per area in the steel-framed building is 24.9% as that in the concrete-framed building, whereas, on use phase, the energy consumption and emissions of steel-framed building are both larger than those of concrete-framed building. As a result, lower energy consumption and environmental emissions are achieved by the concrete-framed building compared with the steel-framed building on the whole life cycle of building. The present study also provides a good method of assessing the performance of energy saving and environmental protection of different building structures based on a whole life cycle. (C) 2008 Elsevier B.V. All rights reserved.