화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Chemical Engineering Research, Vol.47, No.5, 519-530, October, 2009
Export Citation
촉매 전환을 이용한 이산화탄소의 고부가 가치제품 생산에 대한 최근 연구 동향
Recent Research Trends of Catalytic Conversion of CO2 to High-value Chemicals
송기훈, 류준형1, †, 정종식
  • 포항공과대학교 화학공학과, 794-784 경북 포항시 남구 효자동 산 31
  • 1동국대학교 에너지환경대학 에너지환경시스템학과, 780-714 경북 경주시 석장동 707
Ki-Hun Song, Jun-hyung Ryu1, †, and Jong-Sik Chung
  • Department of Chemical Engineering, POSTECH, San 31, Hyoja-dong, Pohang, Gyeongbuk 790-784, Korea
  • 1Department of Energy, Systems and Environment, Dongguk University, 707 Seokjang-dong, Geoyngjoo, Gyeongbuk 780-714, Korea
E-mail:
초록
온실 가스의 주원인인 이산화탄소 발생의 저감은 범세계적으로 중요한 문제가 되었다. 이산화탄소를 단순히 분리하고 외부와 격리시키는 것보다는 이를 이용하여 고부가가치의 화학제품으로 전환 가능하다는 점에서 이산화탄소의 자원화에 대해 많은 관심을 받고 있다. 본 논문에서는 이산화탄소의 촉매 전환을 통한 합성가스 생산의 방법으로서 이산화탄소 개질, 삼중 개질 그리고 내부 개질 고체 산화형 연료 전지(Solid Oxide Fuel Cell) 시스템과 연계하여 전기와 합성가스를 동시에 생산하는 기술로 정하고 이에 대한 최근 연구 동향을 정리하였다. 또한 합성가스로부터 Fischer-Tropsch 합성을 통한 장쇄 탄화수소 생성과 Dimethyl Ether(DME) 생성을 중심으로 한 유용한 화학제품을 생산에 관한 연구동향을 포함하였다.
Reducing the emission of carbon dioxide, which is the main contributor to the green house effect, is becoming a global hot issue. Great attention has been thus given to utilization of carbon dioxide rather than just capturing and isolating it because it could convert carbon dioxide to high-value chemicals. In this paper, recent research trends are investigated on the catalytic conversion of carbon dioxide to syngas in the context of CH4, dry-reforming, trireforming, and the electro-catalytic conversion of carbon dioxide through SOFC(Solid Oxide Fuel Cell) system. Research trends for utilizing syngas to high-value-added useful products, mainly fuel such as DME(Dimethyl Ether) are also discussed.
Keywords:Carbon Dioxide;CO2 Utilization;Solid Oxide Fuel Cell;Reforming;Dimethyl Ether(DME);Fischer-Tropsch Synthesis
  1. Bradford MCJ, Vannice MA, Catal. Rev.-Sci. Eng., 41(1), 1 (1999)
  2. Hu YH, Ruckenstein E, Catal. Rev.-Sci. Eng., 44(3), 423 (2002)
  3. Assabumrungrat S, Laosiripojana N, Piroonlerkgul P, J. Power Sources, 159(2), 1274 (2006)
  4. Li XC, Li SG, Yang YF, Min W, Fei H, Catal. Lett., 118(1-2), 59 (2007)
  5. Snoeck JW, Froment GF, Fowles M, J. Catal., 169(1), 240 (1997)
  6. Trimm DL, Elsevier Science Bv, pp. 3-10 (1999)
  7. Rostrupnielsen JR, Hansen JHB, J. Catal., 144, 38 (1993)
  8. Verykios XE, Appl. Catal. A: Gen., 255(1), 101 (2003)
  9. Wisniewski M, Boreve A, Gein P, Catal. Commun., 6, 596 (2005)
  10. Qin D, Lapszewicz J, Elsevier Science Bv, 51-560 (1994)
  11. Tomishige K, Yamazaki O, Chen YG, Yokoyama K, Li XH, Fujimoto K, Elsevier Science Bv, 35-39 (1998)
  12. Tsipouriari VA, Verykios XE, Catal. Today, 64(1-2), 83 (2001)
  13. Chen YG, Yamazaki O, Tomishige K, Fujimoto K, Catal. Lett., 39(1-2), 91 (1996)
  14. Tang S, Ji L, Lin J, Zeng HC, Tan KL, Li K, J. Catal., 194(2), 424 (2000)
  15. Zhang ZL, Verykios XE, Elsevier Science Bv, 589-595 (1994)
  16. De Lima SM, Pena MA, Fierro JLG, Assaf JM, Catal. Lett., 124, 195 (2008)
  17. Gallego GS, Mondragon F, Barrault J, Tatibouet JM, Batiot-Dupeyrat C, Appl. Catal. A: Gen., 311, 164 (2006)
  18. Goldwasser MR, Rivas ME, Pietri E, Perez-Zurita MJ, Cubeiro ML, Gingembre L, Leclercq L, Leclercq G, Appl. Catal. A: Gen., 255(1), 45 (2003)
  19. Guo J, Lou H, Zhu Y, Zheng X, Mater. Lett., 57, 4450 (2003)
  20. Lima SM, Assaf JM, Pena MA, Fierro JLG, Appl. Catal. A: Gen., 311, 94 (2006)
  21. Rivas ME, Fierro JLG, Goldwasser MR, Pietri E, Perez-Zurita MJ, Griboval-Constant A, Leclercq G, Appl. Catal. A-Gen., 344, 10 (2008)
  22. Rivas ME, Fierro JLG, Guil-Lopez R, Pena MA, La Parola V, Goldwasser MR, Elsevier Science Bv, 367-373 (2008)
  23. Valderrama G, Kiennemann A, Goldwasser MR, Catal. Today, 133, 142 (2008)
  24. Crisafulli C, Scire S, Maggiore R, Minico S, Galvagno S, Catal. Lett., 59(1), 21 (1999)
  25. Crisafulli C, Scire S, Minico S, Solarino L, Appl. Catal. A: Gen., 225(1-2), 1 (2002)
  26. Zhang HG, Wang H, Dalai AK, Appl. Catal. A: Gen., 339(2), 121 (2008)
  27. Laosiripojana N, Assabumrungrat S, Appl. Catal. B: Environ., 60(1-2), 107 (2005)
  28. Wang JB, Hsiao SZ, Huang TJ, Appl. Catal. A: Gen., 246(2), 197 (2003)
  29. Zhang S, Wang J, Wang X, Journal of Natural Gas Chemistry, 17, 179 (2008)
  30. Osaki T, Mori T, J. Catal., 204(1), 89 (2001)
  31. Arena F, Frusteri F, Parmaliana A, Appl. Catal. A: Gen., 187(1), 127 (1999)
  32. Horiuchi T, Sakuma K, Fukui T, Kubo Y, Osaki T, Mori T, Appl. Catal. A: Gen., 144(1-2), 111 (1996)
  33. Laosiripojana N, Sutthisripok W, Assabumrungrat S, Chem. Eng. J., 112(1-3), 13 (2005)
  34. Borowiecki T, Golebiowski A, Catal. Lett., 25(3-4), 309 (1994)
  35. Chen XJ, Khor KA, Chan SH, Electrochem. Solid State Lett., 8(2), A79 (2005)
  36. Choi JE, Kim HR, Choi JS, Cheong JS, Korea Patent (applying) 10-2008-0044767 (2008)
  37. Halmann M, Steinfeld A, Energy, 31(15), 3171 (2006)
  38. Kang JS, Kim DH, Lee SD, Hong SI, Moon DJ, Appl. Catal. A: Gen., 332(1), 153 (2007)
  39. Lee SH, Cho W, Ju WS, Cho BH, Lee YC, Baek YS, Catal. Today, 87(1-4), 133 (2003)
  40. Song CS, Wei P, Catal. Today, 98(4), 463 (2004)
  41. Li Y, Wang Y, Zhang X, Mi Z, International Journal of Hydrogen Energy, 33, 2507 (2008)
  42. Kendall SCSK, High Temperature Solid Oxide Fuel Cells - Fundamentals, Design and Application, Elsevier Ltd, 1-3 (2003)
  43. Kendall SCSK, High temperature Solid Oxide Fuel Cells - Fundamentals, Design and Application, Elsevier Ltd, 89-91 (2003)
  44. Kendall SCSK, High temperature Solid Oxide Fuel Cells - Fundamentals, Design and Application, Elsevier Ltd, 149-152 (2003)
  45. Dicks JLA, John Wiley & Sons Ltd, 164 (2002)
  46. Zhang X, Ohara S, Chen H, Fukui T, Fuel, 81, 989 (2002)
  47. Wang W, Jiang SP, Tok AIY, Luo L, J. Power Sources, 159(1), 68 (2006)
  48. Douvartzides S, Tsiakaras P, IoNics, 7, 232 (2001)
  49. Fischer K, Rzepka M, Stimming U, Biermann JW, Johannaber M, Wallentowitz H, Proc. Inst. Mech. Eng. Part D-J. Automob. Eng., 219, 889 (2005)
  50. Shiratori Y, Oshima T, Sasaki K, Int. J. Hydrog. Energy., 33, 6316 (2008)
  51. Laosiripojana N, Assabumrungrat S, J. Power Sources, 163(2), 943 (2007)
  52. Clarke SH, Dicks AL, Pointon K, Smith TA, Swann A, Catal. Today, 38(4), 411 (1997)
  53. Vollmar HE, Maier CU, Nolscher C, Merklein T, Poppinger M, J. Power Sources, 86(1-2), 90 (2000)
  54. Ryu JW, Kang DM, Park JM, Kim YS, Nam SW, Lee BG, Lee SD, Moon DJ, The Korea Society for Energy Engineering, 12, 67 (2003)
  55. Moono DJ, Park JM, Kang JS, Yoo KS, Hong SI, J. Ind. Eng. Chem., 12(1), 149 (2006)
  56. Moon DJ, Ryu JW, Kang DM, Park JM, Lee SD, Nam SW, Lee BG, Reduction and Treatment Technology of Carbon Dioxide Workshop(1st), Korea (2003)
  57. Ge QJ, Huang YM, Qiu FY, Li SB, Appl. Catal. A: Gen., 167(1), 23 (1998)
  58. Sault AG, Datye AK, J. Catal., 140, 136 (1993)
  59. Moon DJ, Ryu JW, Catal. Today, 87(1-4), 255 (2003)
  60. Park SD, Vohs JM, Gorte RJ, Nature, 404(6775), 265 (2000)
  61. Gorte RJ, Kim H, Vohs JM, J. Power Sources, 106(1-2), 10 (2002)
  62. Gross MD, Vohs JM, Gorte RJ, J. Electrochem. Soc., 154(7), B694 (2007)
  63. Rostrupnielsen JR, Christiansen LJ, Appl. Catal. A: Gen., 126(2), 381 (1995)
  64. Meusinger J, Riensche E, Stimming U, J. Power Sources, 71(1-2), 315 (1998)
  65. Staniforth J, Ormerod RM, Catal. Lett., 81(1-2), 19 (2002)
  66. Shiratori Y, Sasaki K, J. Power. Sources., 180, 738 (2008)
  67. Finnerty CM, Coe NJ, Cunningham RH, Ormerod RM, Catal. Today, 46(2-3), 137 (1998)
  68. Lercher JA, Bitter JH, Hally W, Niessen W, Seshan K, Studies in Surface Science and Catalysis, 463 (1996)
  69. Jung SW, Lu C, He HP, Ahn KY, Gorte RJ, Vohs JM, J. Power Sources, 154(1), 42 (2006)
  70. Gross MD, Vohs JM, Gorte RJ, J. Mater. Chem., 17, 3071 (2007)
  71. Shanwen Tao JTSI, The Chemical Record, 4, 83 (2004)
  72. Marina OA, Canfield NL, Stevenson JW, Solid State Ion., 149(1-2), 21 (2002)
  73. Huang YH, Dass RI, Xing ZL, Goodenough JB, Science, 312, 254 (2006)
  74. Moon DJ, Ryu JW, Kim TY, Park JM, Kang DM, Lee BG, Lee SD, Korea Patent 10-2005-0039465.
  75. Goula G, Kiousis V, Nalbandian L, Yentekakis IV, Solid State Ion., 177(19-25), 2119 (2006)
  76. Janardhanan VM, Heuveline V, Deutschmann O, J. Power Sources, 172(1), 296 (2007)
  77. Klein JM, Bultel Y, Georges S, Pons M, Chem. Eng. Sci., 62(6), 1636 (2007)
  78. Moon DJ, Kang JS, Kim MH, Nho WS, Kim DH, Lee BG, Korea Patent 10-2007-0043304.
  79. Van Herle J, Larrain D, Autissier N, Wuillemin Z, Molinelli M, Favrat D, Elsevier Sci Ltd, 2627 (2005)
  80. Koh JH, Yoo YS, Park JW, Lim HC, Solid State Ion., 149(3-4), 157 (2002)
  81. Trembly JP, Marquez AI, Ohrn TR, Bayless DJ, J. Power Sources, 158(1), 263 (2006)
  82. Zhi M, Chen X, Finklea H, Celik I, Wu NQ, J. Power. Sources., 183, 485 (2008)
  83. Newsome DS, Catal. Revi., 21, 275 (1980)
  84. Davis BH, Catal. Today, 84(1-2), 83 (2003)
  85. Liu Y, Zhang CH, Wang Y, Li Y, Hao X, Bai L, Xiang HW, Xu YY, Zhong B, Li YW, Fuel Process. Technol., 89(3), 234 (2008)
  86. Kim SM, Bae JW, Lee YJ, Jun KW, Catal. Commu., 9, 2269 (2008)
  87. Fiato RA, Iglesia E, Rice GW, Soled SL, T. Inui MAKISY, Yamaguchi T, Stud. Surf. Sci. Catal., Elsevier, 339 (1998)
  88. Jin YM, Datye AK, J. Catal., 196(1), 8 (2000)
  89. Sai Prasad P, Bae J, Jun KW, Lee KW, Catal. Surv. Asia., 12, 170 (2008)
  90. Hwang JS, Jun KW, Lee KW, Appl. Catal. A: Gen., 208(1-2), 217 (2001)
  91. Choi PH, Jun KW, Lee SJ, Choi MJ, Lee KW, Catal. Lett., 40(1-2), 115 (1996)
  92. van Steen E, Claeys M, Chem. Eng. Technol., 31(5), 655 (2008)
  93. Dictor RA, Bell AT, J. Catal.; Vol/Issue: 97:1, Pages: 121 (1986)
  94. Bukur DB, Mukesh D, Patel SA, Industrial & Engineering Chemistry Research, 29, 194 (1990)
  95. Luo MS, Davis BH, Appl. Catal. A: Gen., 246(1), 171 (2003)
  96. Hayakawa H, Tanaka H, Fujimoto K, Appl. Catal. A: Gen., 328(2), 117 (2007)
  97. Peez-Alonso FJ, Ojeda M, Herranz T, Rojas S, Gonzeez-Carballo JM, Terreros P, Fierro JLG, Catal. Commun., 9, 1945 (2008)
  98. ArcoumaNis C, Bae C, Crookes R, Kinoshita E, Fuel, 87, 1014 (2008)
  99. Semelsberger TA, Borup RL, Greene HL, J. Power Sources, 156(2), 497 (2006)
  100. Good DA, Francisco JS, Jain AK, Wuebbles DJ, J. Geophys. Res., 103
  101. http://www.gasnews.com/news/main.php.
  102. Kung HH, Catal. Rev., 22, 235 (1980)
  103. Spivey JJ, Chemical Engineering CommuNications, 110, 123 (1991)
  104. Yaripour F, Baghaei F, Schmidt I, Perregaard J, Catal. Commu., 6, 147 (2005)
  105. Guisnet M, Magnoux P, Catal. Today, 36(4), 477 (1997)
  106. Raoof F, Taghizadeh M, Eliassi A, Yaripour F, Fuel, 87, 2967 (2008)
  107. Vishwanathan V, Jun KW, Kim JW, Roh HS, Appl. Catal. A: Gen., 276(1-2), 251 (2004)
  108. Shikada T, Ohno Y, Ogawa T, Ono M, Mizuguchi M, Tomura K, Fujimoto K, Parmaliana, A.S.D.F.F.V.A.A.F., ed., Elsevier Science Publ B V, 515-520 (1998)
  109. Kim JH, Park MJ, Kim SJ, Joo OS, Jung KD, Appl. Catal. A: Gen., 264(1), 37 (2004)
  110. Qi GX, Fei JH, Zheng XM, Hou ZY, Catal. Lett., 72(1-2), 121 (2001)
  111. Luan Y, Xu H, Yu C, Li W, Hou S, Catal. Lett., 125, 271 (2008)
  112. Wang TF, Wang JF, Jin Y, Ind. Eng. Chem. Res., 46(18), 5824 (2007)
  113. Ogawa T, Inoue N, Shikada T, Inokoshi O, Ohno Y, Bao, X.X.Y., ed., Elsevier Science Bv, 379-384 (2004)
  114. Sun KP, Lu WW, Qiu FY, Liu SW, Xu XL, Appl. Catal. A: Gen., 252(2), 243 (2003)
  115. Barbosa F, Ruiz V, Monteiro J, de Avillez R, Borges L, Appel L, Catal. Lett., 126, 173 (2008)
  116. Luan YS, Xu HY, Yu CY, Li WZ, Hou SF, Catal. Lett., 115(1-2), 23 (2007)
  117. Wang LG, Qi Y, Wei YX, Fang DR, Meng SH, Liu ZM, Catal. Lett., 106(1-2), 61 (2006)
  118. Yoo KS, Kim JH, Park MJ, Kimb SJ, Joo OS, Jung KD, Appl. Catal. A: Gen., 330, 57 (2007)
  119. Moradi G, Ahmadpour J, Yaripour F, Energy & Fuels, 22, 3587 (2008)
  120. Xu A, Indala S, Hertwig TA, Pike RW, Knopf FC, Yaws CL, Hopper JR, Clean Technologies and Environmental Policy, 7, 97 (2005)