Poly(dimethylsiloxane-co-N-phenylsiloxazane) 변성 Acrylate Resin의 제조와 그 특성

강두환; 금민우; 윤재선; Doo Whan Kang; Min Woo Kum; Jae Seon Yoon

Polymer(Korea), Vol.34, No.2, 154-158, March, 2010

Export Citation

Poly(dimethylsiloxane-co-N-phenylsiloxazane) 변성 Acrylate Resin의 제조와 그 특성

Preparation and Properties of Poly(dimethylsiloxane-co-N-phenylsiloxazane) Modified Acrylate Resin

강두환 ^†, 금민우, 윤재선

단국대학교 공과대학 고분자시스템공학과

Doo Whan Kang^†, Min Woo Kum, and Jae Seon Yoon

Department of Polymer Science & Engineering, College of Engineering, Dankook University, Yongin City 448-701, Korea

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초록

α,ω-Dichlorohexamethyltrisiloxane의 aniline과 고리 반응으로부터 N-phenylcyclotrisiloxazane(D3 ^(NPh))을 합성하고 이를 hexamethylcyclotrisiloxane(D3)과 이온 공중합시켜 poly(dimethylsiloxane-co-N-phenylsiloxazane)공중합체(PDMS-NPSOX)를 제조하였다. 이를 chloroethyl methacryalte에 도입하여 PDMS-NPSOX unit가 도입된 아크릴 단량체를 제조하였으며, 이를 MMA 및 n-butyl acrylate와 공중합시켜 PDMS-NPSOX가 도입된 삼원 아크릴 공중합체를 제조하고, 그 특성을 조사하였다. 단량체 조성은 생성 공중합체의 Tg가 25 ℃가 되도록 선택하여 공중합시켰다. 공중합체에서 PDMS만 도입된 경우 Tg 가 20 ℃인데 비하여 PDMS-NPSOX unit이 도입됨에 따라 25 ℃로 증가되었으며 접착력도 1.76 N/cm에서 2.23 N/cm로 증가되었다.

We first synthesized N-phenylcyclotrisiloxazane (D3^(NPh)) through a cyclization of α,ω- dichlorohexamethyltrisiloxane with aniline and prepared poly(dimethylsiloxane-co-N-phenylsiloxazane) copolymer (PDMS-NPSOX) by a ring opening copolymerization of them with hexamethylcyclotrisiloxane (D3). An acrylate monomer modified with PDMS-NPSOX was synthesized by using chloroethyl methacrylate and copolymerized with methylmethacrylate (MMA) and n-butylacrylate. The composition of the copolymer was chosen to control their glass transition temperature (Tg) to 25 ℃. By changing the comonomer from PDMS to PDMS-NPSOX, Tg and adhesive strength of the copolymer were increased from 20 to 25 ℃ and from 1.76 to 2.23 N/cm, respectively.

Keywords:N-phenylcyclotrisiloxazane;poly(dimethylsiloxane-co-N-phenylsiloxazane);hexamethylcyclotrisiloxane;acrylic copolymer.

[References]

Asakawa A, Yamauchi M, Masuda S, Unoki M, “Composition for Fluororesin Powder Coating Materials with Low Gloss and Weather-Resistance”, PCT Int. Appl., WO 029369A1 (2003)
Yoshida T, Toso Gijutsu, 40, 141 (2001)
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Nakamoto I, Kogyo Toso, 201, 48 (2006)
Zheng G, Shanghai Tuliao, 43, 36 (2005)
Suzuki K, Shimizu T, Yamagoe M, Sugisaki T, U.S. Pat. 5,219,560 (1993)
Lin MT, Chu FX, Guyot A, Putaux JL, Bourgeat-Lami E, Polymer, 46(4), 1331 (2005)
Kanegafuchi Kagaku Kogyo Co., U.S. Pat. 4,975488 (1990)
Rao VL, Babu GM, Eur. Polym. J., 26, 227 (1990)
Witucki GL, J. Coat. Technol., 65, 57 (1993)
Aylete BJ, Organometallic Chem., 3, 151 (1988)
Bennet EW, U.S. Pat. 3,646,090 (1972)
Bread LW, Elliot RL, Inorg. Chem., 3, 1622 (1964)
Kang DW, J. Kor. Soc. Text. Eng. Chem., 21, 61 (1984)
Schwartz M, Baumstrark R, Waterbased Acrylates for Decorative Coating, Vincentz Verlag, Hannover, pp 17-21 (2001)

[Related Articles]

[1] Asakawa A, Yamauchi M, Masuda S, Unoki M, “Composition for Fluororesin Powder Coating Materials with Low Gloss and Weather-Resistance”, PCT Int. Appl., WO 029369A1 (2003)

[2] Yoshida T, Toso Gijutsu, 40, 141 (2001)

[3] Matsuzawa H, Kudo S, “Ultraviolet-Curable Resin Composition, Ultraviolet-Curable Coating Material, and Coated Article”, PCT Int. Appl., WO 095686A1 (2006)

[4] Nakamoto I, Kogyo Toso, 201, 48 (2006)

[5] Zheng G, Shanghai Tuliao, 43, 36 (2005)

[6] Suzuki K, Shimizu T, Yamagoe M, Sugisaki T, U.S. Pat. 5,219,560 (1993)

[7] Lin MT, Chu FX, Guyot A, Putaux JL, Bourgeat-Lami E, Polymer, 46(4), 1331 (2005)

[8] Kanegafuchi Kagaku Kogyo Co., U.S. Pat. 4,975488 (1990)

[9] Rao VL, Babu GM, Eur. Polym. J., 26, 227 (1990)

[10] Witucki GL, J. Coat. Technol., 65, 57 (1993)

[11] Aylete BJ, Organometallic Chem., 3, 151 (1988)

[12] Bennet EW, U.S. Pat. 3,646,090 (1972)

[13] Bread LW, Elliot RL, Inorg. Chem., 3, 1622 (1964)

[14] Kang DW, J. Kor. Soc. Text. Eng. Chem., 21, 61 (1984)

[15] Schwartz M, Baumstrark R, Waterbased Acrylates for Decorative Coating, Vincentz Verlag, Hannover, pp 17-21 (2001)