GREEN-OIL FORMATION AND SELECTIVITY CHANGE IN SELECTIVE HYDROGENATION ON TITANIA-SUPPORTED AND UNSUPPORTED PALLADIUM CATALYST FOR ACETYLENE REMOVAL FROM ETHYLENE-RICH STREAM

LEE DK

Korean Journal of Chemical Engineering, Vol.7, No.3, 233-235, July, 1990

LEE DK

Green-oil accumulation during the selective hydrogenation of acetylene was measured on titania-supported and unsupported catalyst, and changes in the selectivity for ethylene formation with green-oil accumulation were observed. Selectivity decrease was observed on the titania-supported catalyst where green-oil accumulated continuously after induction time, while the green-oil accumulation on the unsupported catalyst resulted in a slight increase in selectivity.

[References]

Anderson HC, Haley AT, Egbert W, Ind. Eng. Chem. Fundam., 52, 901 (1960)
Lam WK, Lloyd L, Oil Gas J., 27, 66 (1972)
Huang W, Hydrocarb. Process., 132 (1979)
Little LH, Sheppard N, Yates DJC, Proc. Roy. Soc. London, A259, 242 (1960)
Sheppard N, Ward JW, J. Catal., 15, 50 (1969)
Al-Ammar AS, Webb G, J. Chem. Soc.-Faraday Trans., 74, 657 (1978)
Al-Ammar AS, Webb G, J. Chem. Soc.-Faraday Trans., 75, 1900 (1979)
Moses JM, Weiss AH, Matusek K, Guczi L, J. Catal., 86, 417 (1984)
Lee DK, Ihm SK, U.S. Patent, 4,839,329 (1989)
Margitfalvi J, Guczi L, J. Catal., 72, 185 (1981)
Battiston GC, Dalloro L, Tauszik GR, Appl. Catal., 2, 1 (1982)
Weiss AH, Gamdhir BS, Lapierre RB, Bell WK, Ind. Eng. Chem. Process Des. Dev., 16, 352 (1977)
Sarkany A, Guczi L, Weiss AH, Appl. Catal., 10, 369 (1984)
Sarkany A, Weiss AH, Szilagyi T, Sandor P, Guczi L, Appl. Catal., 12, 373 (1984)
McGown WT, Kemball C, Whan DA, Scurrell MS, J. Chem. Soc.-Faraday Trans., 73, 632 (1977)

[Referenced By]

[1] Anderson HC, Haley AT, Egbert W, Ind. Eng. Chem. Fundam., 52, 901 (1960)

[2] Lam WK, Lloyd L, Oil Gas J., 27, 66 (1972)

[3] Huang W, Hydrocarb. Process., 132 (1979)

[4] Little LH, Sheppard N, Yates DJC, Proc. Roy. Soc. London, A259, 242 (1960)

[5] Sheppard N, Ward JW, J. Catal., 15, 50 (1969)

[6] Al-Ammar AS, Webb G, J. Chem. Soc.-Faraday Trans., 74, 657 (1978)

[7] Al-Ammar AS, Webb G, J. Chem. Soc.-Faraday Trans., 75, 1900 (1979)

[8] Moses JM, Weiss AH, Matusek K, Guczi L, J. Catal., 86, 417 (1984)

[9] Lee DK, Ihm SK, U.S. Patent, 4,839,329 (1989)

[10] Margitfalvi J, Guczi L, J. Catal., 72, 185 (1981)

[11] Battiston GC, Dalloro L, Tauszik GR, Appl. Catal., 2, 1 (1982)

[12] Weiss AH, Gamdhir BS, Lapierre RB, Bell WK, Ind. Eng. Chem. Process Des. Dev., 16, 352 (1977)

[13] Sarkany A, Guczi L, Weiss AH, Appl. Catal., 10, 369 (1984)

[14] Sarkany A, Weiss AH, Szilagyi T, Sandor P, Guczi L, Appl. Catal., 12, 373 (1984)

[15] McGown WT, Kemball C, Whan DA, Scurrell MS, J. Chem. Soc.-Faraday Trans., 73, 632 (1977)