Removal of perrhenate anions in aqueous solutions using anion-exchange organic/inorganic hybrid nanoporous beads

Yeon-Sung Chung; Byunghwan Lee; Kwang-Ho Choo; Sang-June Choi

Journal of Industrial and Engineering Chemistry, Vol.17, No.1, 114-119, January, 2011

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Removal of perrhenate anions in aqueous solutions using anion-exchange organic/inorganic hybrid nanoporous beads

Yeon-Sung Chung, Byunghwan Lee^†, Kwang-Ho Choo¹, and Sang-June Choi¹

Department of Chemical System Engineering, Keimyung University, 2800 Dalgubeoldaero, Dalseo-Gu, Daegu, 704-701, South Korea
¹Department of Environmental Engineering, Kyungpook National University, 1370 Sankyeok-Dong, Buk-Gu, Daegu, 702-701, South Korea

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Organic/inorganic hybrid nanoporous beads functionalized with quaternary ammonium groups were prepared for the removal of perrhenate anions from aqueous solutions. Organic/inorganic hybrid anionexchange resins of powder type were synthesized first, and then hybrid nanoporous beads were prepared using the prepared powder samples and Na-alginate solutions. The prepared hybrid nanoporous beads showed good adsorption affinity to the perrhenate anions. The physical and chemical properties of prepared samples were characterized using small angle X-ray scattering (SAXS), scanning electron microscope (SEM), and N2 adsorption.desorption measurement. We have also investigated equilibrium isotherms for the measurement of adsorption capacities, and kinetic performances through fixed-bed column experiments.

Keywords:Anion-exchange resin;Organic-inorganic hybrid nanoporous bead;Perrhenate;Quaternary ammonium

[References]

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Bull RJ, Chang AC, Cranor CF, Shank RC, Trussell R, Perchlorate in Drinking Water: A Science and Policy Review, Urban Water Research Center, University of California, Irvine, CA (2004)
Yoon IH, Meng XG, Wang C, Kim KW, Bang S, Choe E, Lippincott L, J. Hazard. Mater., 164(1), 87 (2009)
Yoon SH, van Heiningen A, J. Ind. Eng. Chem., 16(1), 74 (2010)
Logan BE, Environ. Sci. Technol., 35, 482A (2001)
Jandera P, Komers D, J. Chromatogr. A., 762, 1997 (3)
Wang DM, Huang CP, Chen JG, Lin HY, Shah SI, Sep. Purif. Technol., 58(1), 129 (2007)
Bonnesen PV, Brown GM, Alexandratos SD, Bavoux LB, Presley DJ, Patel V, Ober R, Moyer BA, Environ. Sci. Technol., 34, 3761 (2000)
Gu B, Ku YK, Brown GM, Environ. Sci. Technol., 39, 901 (2005)
Gu B, Brown GM, Chiang CC, Environ. Sci. Technol., 41, 6277 (2007)
Ju YH, Webb OF, Dai S, Lin JS, Barnes CE, Ind. Eng. Chem. Res., 39(2), 550 (2000)
Kim TH, Jang M, Park JK, Microporous Mesoporous Mater., 108, 22 (2008)
Xiong Z, Zhao D, Harper WF, Ind. Eng. Chem. Res., 46(26), 9213 (2007)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)
Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
Liu J, Feng XD, Fryxell GE, Wang LQ, Kim AY, Gong ML, Adv. Mater., 10(2), 161 (1998)
Khalil KMS, J. Colloid Interface Sci., 315(2), 562 (2007)
Lihitkar NB, Abyaneh MK, Samuel V, Pasricha R, Gosavi SW, Kulkarni SK, J. Colloid Interface Sci., 314(1), 310 (2007)
Fryxell GE, Liu J, Hauser TA, Nie Z, Ferris KF, Mattigod S, Gong M, Hallen RT, Chem. Mater., 11, 2148 (1999)
Lin Y, Fryxell GE, Wu H, Engelhard M, Environ. Sci. Technol., 35, 3962 (2001)
Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 14, 4603 (2002)
Kim Y, Kim C, Choi I, Rengaraj S, Yi J, Environ. Sci. Technol., 38, 924 (2004)
Lee B, Bao LL, Im HJ, Dai S, Hagaman EW, Lin JS, Langmuir, 19(10), 4246 (2003)
Lee B, Chung YS, Park C, Korean Chem. Eng. Res., 46(2), 436 (2008)
Park C, Lee B, Han EJ, Lee J, Kim S, Enzyme Microb. Technol., 39(3), 371 (2006)
Jeon C, Park JY, Yoo YJ, Biochem. Eng. J., 11, 159 (2002)
Jeon C, Kwon YD, Park KH, J. Ind. Eng. Chem., 11(5), 643 (2005)
Tanev PT, Pinnavaia TJ, Chem. Mater., 8, 2068 (1996)
Lee B, Kim Y, Lee H, Yi J, Microporous Mesoporous Mater., 50, 77 (2001)
Reddad Z, Gerente C, Andres Y, Cloirec PL, Environ. Sci. Technol., 36, 2067 (2002)

[Referenced By]

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[1] Brown GM, Gu B, in: Gu B, Coates JD (Eds.), Perchlorate: Environmental Occurrence, Interactions and Treatment, Springer, New York, p. 17. (2006)

[2] Bull RJ, Chang AC, Cranor CF, Shank RC, Trussell R, Perchlorate in Drinking Water: A Science and Policy Review, Urban Water Research Center, University of California, Irvine, CA (2004)

[3] Yoon IH, Meng XG, Wang C, Kim KW, Bang S, Choe E, Lippincott L, J. Hazard. Mater., 164(1), 87 (2009)

[4] Yoon SH, van Heiningen A, J. Ind. Eng. Chem., 16(1), 74 (2010)

[5] Logan BE, Environ. Sci. Technol., 35, 482A (2001)

[6] Jandera P, Komers D, J. Chromatogr. A., 762, 1997 (3)

[7] Wang DM, Huang CP, Chen JG, Lin HY, Shah SI, Sep. Purif. Technol., 58(1), 129 (2007)

[8] Bonnesen PV, Brown GM, Alexandratos SD, Bavoux LB, Presley DJ, Patel V, Ober R, Moyer BA, Environ. Sci. Technol., 34, 3761 (2000)

[9] Gu B, Ku YK, Brown GM, Environ. Sci. Technol., 39, 901 (2005)

[10] Gu B, Brown GM, Chiang CC, Environ. Sci. Technol., 41, 6277 (2007)

[11] Ju YH, Webb OF, Dai S, Lin JS, Barnes CE, Ind. Eng. Chem. Res., 39(2), 550 (2000)

[12] Kim TH, Jang M, Park JK, Microporous Mesoporous Mater., 108, 22 (2008)

[13] Xiong Z, Zhao D, Harper WF, Ind. Eng. Chem. Res., 46(26), 9213 (2007)

[14] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)

[15] Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)

[16] Liu J, Feng XD, Fryxell GE, Wang LQ, Kim AY, Gong ML, Adv. Mater., 10(2), 161 (1998)

[17] Khalil KMS, J. Colloid Interface Sci., 315(2), 562 (2007)

[18] Lihitkar NB, Abyaneh MK, Samuel V, Pasricha R, Gosavi SW, Kulkarni SK, J. Colloid Interface Sci., 314(1), 310 (2007)

[19] Fryxell GE, Liu J, Hauser TA, Nie Z, Ferris KF, Mattigod S, Gong M, Hallen RT, Chem. Mater., 11, 2148 (1999)

[20] Lin Y, Fryxell GE, Wu H, Engelhard M, Environ. Sci. Technol., 35, 3962 (2001)

[21] Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 14, 4603 (2002)

[22] Kim Y, Kim C, Choi I, Rengaraj S, Yi J, Environ. Sci. Technol., 38, 924 (2004)

[23] Lee B, Bao LL, Im HJ, Dai S, Hagaman EW, Lin JS, Langmuir, 19(10), 4246 (2003)

[24] Lee B, Chung YS, Park C, Korean Chem. Eng. Res., 46(2), 436 (2008)

[25] Park C, Lee B, Han EJ, Lee J, Kim S, Enzyme Microb. Technol., 39(3), 371 (2006)

[26] Jeon C, Park JY, Yoo YJ, Biochem. Eng. J., 11, 159 (2002)

[27] Jeon C, Kwon YD, Park KH, J. Ind. Eng. Chem., 11(5), 643 (2005)

[28] Tanev PT, Pinnavaia TJ, Chem. Mater., 8, 2068 (1996)

[29] Lee B, Kim Y, Lee H, Yi J, Microporous Mesoporous Mater., 50, 77 (2001)

[30] Reddad Z, Gerente C, Andres Y, Cloirec PL, Environ. Sci. Technol., 36, 2067 (2002)