Inorganic Chemistry, Vol.34, No.4, 995-997, 1995
Metal-Complexes in Inorganic Matrices .13. Nickel-Complexes with Lysinate-Substituted Titanium Alkoxides as Ligands - X-Ray Structure-Analysis of ((Eto)(3)Ti(Glycinate))(2)
Reaction of Ti(OEt)(4) with amino acids results in alkoxide carboxylate derivatives, in which the amino carboxylate group chelates the Ti(OEt)(3) moiety via one oxygen atom and the NH2 group. An X-ray structure analysis of the glycine derivative showed the compound to be dimeric, with the two Ti atoms bridged by two OEt group. When lysine is used, only the alpha-amino group coordinates to the metal while the terminal amino group is dangling and can be used to coordinate metal ions.