Inorganic Chemistry, Vol.35, No.21, 5964-5965, 1996
Anomalous Magnetic-Properties of (K(Mn(3-Meo-SALEN))(2)(Mn(CN)(6))) - a Metamagnet Exhibiting a Strong Negative Magnetization (3-Meosalen Equals N,N’-Ethylenebis(3-Methoxysalicylideneaminato)
An abnormally strong negative magnetization has been found in the metamagnetic extended structure derived from assembled [Mn(CN)(6)](3-) and [Mn(5-Clsalen)](+) in a two dimensional array of Mn(III) ions, which contains the repeating cyclic octameric unit.