화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Clean Technology, Vol.17, No.3, 201-208, September, 2011
Export Citation
이산화탄소기반 고리형 카보네이트 및 폴리카보네이트 제조 연구 동향
Recent Development to Generate Carbon Dioxide-based Cyclic Carbonate and Polycarbonate
권두연, 김재일, 강휘주, 김다연, 김재호, 이봉1, 김문석†
  • 아주대학교 분자과학기술학과, 443-749 경기도 수원시 원통구 원천동 산 5
  • 1부경대학교 고분자공학과, 608-739 부산광역시 남구 용당동 산 100
Doo Yeon Kwon, Jae Il Kim, Hwi Ju Kang, Da Yeon Kim, Jae Ho Kim, Bong Lee1, and Moon Suk Kim†
  • Department of Molecular Science and Technology, Ajou University, San 5, Woncheon-Dong, Yeongtong-gu, Suwon 443-749, Korea
  • 1Department of Polymer Engineering, Pukyong National University, San 100, Yongdang-Dong, Nam-Gu, Busan 608-739, Korea
E-mail:
초록
온실효과 유발 이산화탄소는 학문적, 산업적 관점에서 이산화탄소 기반 폴리카보네이트 제조에 대한 원료로서 적용 가능하다. 그러므로 이산화탄소 기반 폴리카보네이트는 탁월한 경제적 녹색고분자이다. 최근 이산화탄소 기반 폴리카보네이트의 빠른 개발이 산업적으로 새로운 기회를 제공하고 있다. 본 총설에서는 다양한 촉매 존재하에서 이산화탄소 및 에폭사이드 계열 화합물을 이용한 고리형 카보네이트 모노마 제조 및 제조된 모노마로부터 이산화탄소 기반 폴리카보네이트 제조에 대한 연구 동향을 설명하고자 한다.
The green house gas, carbon dioxide, can be utilized as raw materials to prepare carbon dioxide-based polycarbonates in research and industry. The carbon dioxide-based polycarbonates is one of the emerging low-cost green polymers. Recently, the fast development of carbon dioxide-based polycarbonates has created new chances for industry. In this review, we describe the preparation and characterization of cyclic carbonate monomer using carbon dioxide, oxiranes and oxetanes in the presence of various catalysts and preparation of polycarbonates from cyclic carbonate monomer, presenting an organized and detailed overview of the state of the art.
Keywords:Carbon dioxide;Epoxide;Cyclic carbonate;Polycarbonate
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