Synthesis, characterization of mesoporous silica materials from waste coal fly ash for the classical Mannich reaction

Aashish O. Dhokte; Santosh L. Khillare; Machhindra K. Lande; Balasaheb R. Arbad

Journal of Industrial and Engineering Chemistry, Vol.17, No.4, 742-746, July, 2011

DOI10.1016/j.jiec.2011.05.033 Export Citation

Synthesis, characterization of mesoporous silica materials from waste coal fly ash for the classical Mannich reaction

Aashish O. Dhokte, Santosh L. Khillare, Machhindra K. Lande, and Balasaheb R. Arbad^†

Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, MS 431004, India

E-mail:

The present study describes the synthesis of mesoporous silica material (MCM-41) from fly ash of thermal power plants so as to meet requirements of green chemistry approach. The synthesized material was characterized by XRD, FT-IR, SEM-EDS techniques. The prepared material, MCM-41, was utilized as catalyst for classical Mannich reaction for the synthesis of β-amino carbonyl compounds. The present methodology offers several advantages, like excellent yields, short reaction times, reusability of catalyst and simple work up procedure.

Keywords:Coal fly ash (CFA);Mesoporous silica materials (MCM-41);Green chemistry;Mannich reaction;Heterogeneous catalysis

[References]

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[Referenced By]

[1] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)

[2] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu DTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am.Chem. Soc., 114, 10834 (1992)

[3] Beck JS, Vartuli JC, Curr. Opin. Solid State Mater. Sci., 1, 76 (1996)

[4] Tanaka H, Sakai Y, Hino R, Mater. Res. Bull., 37, 1873 (2002)

[5] Ferraiolo G, Zilli M, Converti A, J. Chem. Technol. Biotechnol., 47, 281 (1990)

[6] Carlson CL, Adriano DC, J. Environ. Qual., 22, 227 (1993)

[7] Kikuchi R, Resour. Conserv. Rec., 27, 333 (1999)

[8] Kumar K, Kumar S, Mehrotra SP, Resour. Conserv. Recycl., 52, 157 (2007)

[9] Misran H, Singh R, Begum S, Yarmo MA, J. Mater. Process. Technol., 186, 8 (2007)

[10] Biz S, Occelli ML, Catal. Rev.-Sci. Eng., 40(3), 329 (1998)

[11] Kimura T, Micropor. Mesopor. Mater., 77, 97 (2005)

[12] Querol X, Moreno N, Umana JC, Alastuey A, Hernandez E, Lopez-Soler A, Plana F, Int. J. Coal Geol., 50, 413 (2002)

[13] Hollman GG, Steenbruggen G, Janssen-Jurkovicova M, Fuel, 78(10), 1225 (1999)

[14] Hui KS, Chao CYH, Kot SC, J. Hazard. Mater., 127(1-3), 89 (2005)

[15] Srinivasan A, Grutzeck MW, Environ. Sci. Technol., 33, 1464 (1999)

[16] Zhang AL, Deng FF, Zhou JT, Jin RF, Liang LL, Zhang GL, Huan Jing Ke Xue., 7, 1942 (2009)

[17] Ghaffar A, Tabata M, React. Kinet. Catal. Lett., 97(1), 35 (2009)

[18] ARKIVOC xiii., Gopalkrishan M, Sureshkumar P, Kanagarajan V, Thanusu J, Govindaraju R, 130 (2006)

[19] Arend M, Westermnn B, Risch N, Angew. Chem. Int. Ed. Engl., 37, 1044 (1998)

[20] Casimir JR, Turetta C, Ettouti L, J. Tetrahedron Lett. (Paris)., 36, 4797 (1995)

[21] Godfrey AG, Brooks DA, Hay LA, Peter M, McCarthy JR, Mitchell D, J. Org.Chem., 68, 2623 (2003)

[22] Da¨hn U, Hagenmaier H, Ho¨ hne H, Ko¨ nig WA, Wolf G, Za¨hner H, Arch. Microbiol., 107, 143 (1976)

[23] Kobinata K, Uramoto M, Nishii M, Kusakabe H, Nakamura G, Isono K, Agric.Biol. Chem., 44, 1709 (1980)

[24] Blatt AH, Gross N, J. Org. Chem., 29, 3306 (1964)

[25] Craig JC, Moyle M, Johnson LF, J. Org. Chem., 29, 410 (1964)

[26] Yi L, Lei HS, Zou JH, Xu XJ, Synthesis., 717 (1991)

[27] Manabe K, Kobayashi S, Org. Lett., 1, 1965 (1999)

[28] Iimura S, Nobutou D, Manabe K, Kobayashi S, Chem. Commun., 1644 (2003)

[29] Wang R, Li BG, Huang TK, Shi L, Lu XX, Tetrahedron Lett., 48, 2071 (2007)

[30] Wang LM, Han JW, Sheng J, Tian H, Fan ZY, Catal. Commun., 6, 201 (2005)

[31] Yi WB, Cai C, J. Fluorine Chem., 127, 1515 (2006)

[32] Dong F, Jun L, Zhou XL, Liu ZL, Catal. Lett., 116(1-2), 76 (2007)

[33] Azizi N, Torkiyan L, Saidi, MR, Org. Lett., 8, 2079 (2006)

[34] Chang CT, Liao BS, Liu ST, Tetrahedron Lett., 47, 9257 (2006)

[35] Li Z, Ma XL, Liu J, Feng X, Tian GQ, Zhu AG, J. Mol. Catal. A-Chem., 272(1-2), 132 (2007)

[36] Shen W, Wang LM, Tian H, J. Fluorine Chem., 129, 267 (2008)

[37] Kumar P, Mal N, Omani Y, Yamana K, Sano T, J. Mater. Chem., 11, 3285 (2001)

[38] Hui KS, Chao CYH, J. Hazard. Mater., 137(2), 1135 (2006)

[39] Kiseler AV, Lygin VI, 1st ed., Nauka, Moskow (1992)

[40] Romero AA, Alba MD, Zhou WZ, Klinowski J, J. Phys. Chem. B, 101(27), 5294 (1997)

[41] Takahashi R, Sato S, Sodesawa T, Kawakita M, Ogura K, J. Phys. Chem. B, 104(51), 12184 (2000)

[42] Kumar D, Schumacher K, Du Fresne von Hohenesche C, Gruen M, Unger KK, Physicochem. Eng. Aspects 187-188, 109 (2001)

[43] Wakihara T, Sugiyama A, Okubo T, Micropor. Mesopor. Mater., 70, 7 (2004)

[44] Dong F, Jun L, Zhou XL, Liu ZL, Catal. Lett., 116(1-2), 76 (2007)

[45] Wang M, Zhi-Guo, Song, Jiang H, Org. Prep. Proced. Int., 41, 315 (2009)

[46] Goswami P, Das B, Tetrahedron Lett., 50, 2384 (2009)