Applied Chemistry for Engineering, Vol.22, No.6, 627-630, December, 2011
Spouted Bed Reactor를 이용한 다양한 탄소수 원료유 촉매 열분해
Catalytic Pyrolysis of Various Carbon Number Feed Oil Using a Spouted Bed Reactor
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초록
본 연구에서는 원료의 직접 주입법과 다양한 탄소수를 갖는 화합물을 이용하여 휘발유와 등유 등의 고급 유분을 생성할 수 있는 상업용 촉매 공정의 반응특성을 평가하고자 하였다. 이를 통하여 순간주입 반응기(spouted bed reactor) 상에서 상용촉매를 사용하여 반응 특성을 평가하였다. 또한 decane과 pentadecane을 이용하여 고정층 반응기와 순간주입 반응기의 특성을 비교하였다. 본 연구 결과, 반응온도 550 ℃에서 가장 높은 휘발유 및 등유 수율을 기록하였다. 또한 순간 주입 반응기의 경우 주입량을 분할하여 주입하는 것보다 1회에 주입하는 것이 보다 효과적이었으며, 탄소수가 큰 물질을 사용할수록 반응활성이 증가하였다.
We focus on a catalytic process based on direct injection method that can produce high-quality oils of gasoline and kerosene with various carbon-number feed oils. The reaction characteristics of a commercial catalyst were analyzed using a spouted bed reactor. Decane and pentadecane were used to compare the characteristics of the fixed bed and the spouted bed reactor. The yield of gasoline plus kerosene was highest at the reaction temperature of 550 ℃. For the spouted bed reactor, the at-a-pulse injection was more effective for catalytic cracking of feed oils than multiple consecutive injections. The reaction activity became higher as the carbon number of feed oil is larger.
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