Inorganic Chemistry, Vol.37, No.21, 5681-5685, 1998
Larger cyclophanes : Synthesis and structural characterization of [2.2.2.2]Paracyclophane compounds with SbBr3 and BiBr3
The charge transfer (CT) compounds of [2.2.2.2]paracyclophane with SbBr3 and BiBr3 of formula SbBr3:[2.2.2.2]paracyclophane (1) and Bi2Br6:[2.2.2.2]paracyclophane:toluene (2) have been synthesized and characterized by crystallographic and spectroscopic analyses. Both compounds are characterized by long interactions between the metal and the aromatic rings of [2.2.2.2]paracyclophane.