Inorganic Chemistry, Vol.39, No.6, 1329-1332, 2000
Solid state structures of [Ag-5(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2)][PF6] and Ag-4(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2): Variable coordination modes of 1,1-dithiolate to silver(I)
A novel pentanuclear silver complex [Ag-5(dppm)(4)(S-2-CC(CN)P(O)(OEt)(2))(2)][PF6], containing bridging dppm and 2-(diethoxyphosphinyl)-2-cyanoethylene-1,1-dithiolato ligands of which the 1,1-dithiolates exhibit an unprecedented tetrametallic hexaconnective coordination pattern, is reported.
Keywords:CHEMICAL-VAPOR-DEPOSITION;COMPLEXES;LIGANDS;CRYSTAL;CLUSTERS;FILMS;DITHIOLATE;PRECURSORS;ZINC