Inorganic Chemistry, Vol.39, No.6, 1333-1335, 2000
Analogues of the Tp* ligand containing a 3-Me but non-methyl 5-R groups
Two new homoscorpionates, Tp(Me,mt3) and Tp(Me,mt4) were prepared, as the first examples of Tp(x) ligands containing a 3-Me but SR-substituents other than Me. Structures of Co[Tp(Me,mt3)][Tp(Nt)] and Rh[Tp(Me,mt4)](COD) were determined by X-ray crystallography.