Poly(1-oxotrimethylene) Fibers Prepared by Different Draw Ratios for the Tire Cord Application

Hae-Souk Cho; Jae-Seung Chung; Jaeyoon Shim; Jin-joo Kim; Won Jae Choi; Jong-Chan Lee

Macromolecular Research, Vol.20, No.7, 732-738, July, 2012

DOI10.1007/s13233-012-0101-7 Export Citation

Poly(1-oxotrimethylene) Fibers Prepared by Different Draw Ratios for the Tire Cord Application

Hae-Souk Cho^{1, 2}, Jae-Seung Chung^{1, 3}, Jaeyoon Shim², Jin-joo Kim^{1, 3}, Won Jae Choi^{1, 3}, and Jong-Chan Lee^{1, 3, †}

¹Department of Chemical and Biological Engineering and Institute of Chemical Process, Seoul National University, Seoul, 151-744, Korea
²Hyosung Corporation, Gyeonggi, 431-080, Korea
³, Korea

E-mail:

Poly(1-oxotrimethylene) (POTE) was prepared by polymerization of ethylene and carbon monoxide gases in an autoclave using a palladium catalyst system. POTE fibers having different draw ratios were prepared and characterized using differential scanning calorimetry (DSC), X-ray diffraction, and a universal testing machine (UTM). Tensile strength and modulus of POTE fibers having a draw ratio of 16 obtained by drying at 220 ℃ were found to be 13.4 and 369.8 g/denier, respectively. These values are much larger than those of poly(ethylene terephthalate)(PET) and Nylon 6 fibers that are currently used as tire cords.

Keywords:poly(1-oxotrimethylene);fiber;draw ratio;crystallinity.

[References]

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Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 17(2), 264 (2011)
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Kim SK, Kim TH, Jung JW, Lee JC, Polymer, 50(15), 3495 (2009)
Yoo Y, Spencer MW, Paul DR, Polymer, 52(1), 180 (2011)

[Referenced By]

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[1] Drent E, Budzelaar PH, Chem. Rev., 96(2), 663 (1996)

[2] Lommerts BJ, Klop EA, Aerts J, J. Polym. Sci. Part B: Polym. Phys., 31, 1319 (1993)

[3] Klop EA, Lommerts BJ, Veurink J, Aerts J, Vanpuijenbroek RR, J. Polym. Sci. B: Polym. Phys., 33(2), 315 (1995)

[4] Waddon AJ, Karttunen NR, Lesser AJ, Macromolecules, 32(2), 423 (1999)

[5] Lagaron JM, Vickers ME, Powell AK, Davidson NS, Polymer, 41(8), 3011 (2000)

[6] Drent E, Jager WW, Polym. Mater. Sci. Eng., 74, 100 (1997)

[7] Ash CE, Flood JE, Polym. Mater. Sci. Eng., 74, 110 (1997)

[8] Bonner JG, Powell AK, Polym. Mater. Sci. Eng., 74, 108 (1997)

[9] Brubaker MM, Coffman DD, Hoehn HH, J. Am.Chem. Soc., 74, 1509 (1952)

[10] Chatani Y, Takizawa T, Murahashi S, Sakata Y, Nishimura Y, J. Polym. Sci., 55, 811 (1961)

[11] Morita T, Taniguchi R, Matsuo T, Kato J, J. Appl. Polym. Sci., 92(2), 1183 (2004)

[12] Morita T, Taniguchi R, Kato J, J. Appl. Polym. Sci., 94(2), 446 (2004)

[13] Morita T, Adachi M, Kato J, J. Appl. Polym. Sci., 96(4), 1250 (2005)

[14] Morita T, Kato J, J. Appl. Polym. Sci., 100(4), 3358 (2006)

[15] Zuigyo Y, Tire Sci. Technol., 35, 317 (2007)

[16] Gupta P, Schulte JT, Flood JE, Spruiell JE, J. Appl. Polym. Sci., 82(7), 1794 (2001)

[17] Bonner JG, Powell AK, Polym. Mater. Sci. Eng., 74, 108 (1997)

[18] Liu Y, Li J, Pan ZJ, Adv. Mater. Res., 175, 90 (2011)

[19] Lund A, Hagstrom B, J. Appl. Polym. Sci., 116(5), 2685 (2010)

[20] Wu BZ, Gong Y, Yang GS, J. Mater. Sci., 46(15), 5184 (2011)

[21] Han N, Zhang XX, Yu WY, Gao XY, Macromol. Res., 18(11), 1060 (2010)

[22] Lee CH, Cha YJ, Choe S, J. Ind. Eng. Chem., 4(2), 161 (1998)

[23] Kang YA, Kim KH, Cho HH, Kikutani T, J. Appl. Polym. Sci., 95(2), 212 (2005)

[24] Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 17(2), 264 (2011)

[25] Kim WS, Lee DH, Kim IJ, Son MJ, Kim W, Cho SG, Macromol. Res., 17(10), 776 (2009)

[26] Kim SK, Kim TH, Jung JW, Lee JC, Polymer, 50(15), 3495 (2009)

[27] Yoo Y, Spencer MW, Paul DR, Polymer, 52(1), 180 (2011)