| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
n-Type Electrical Memory and Thin Film Morphology Controlled by Brush Polymer Bearing Perylene Diimide Moieties |
| 초록 |
We synthesize Poly(N-(1-hexylheptyl)-N′-(12-oxydodecyl)perylene-3,4,9,10-tetracarboxyldiimide acrylate) (PAcPDI), a perylene diimide (PDI) incorporating brush polymer. We examine the self-assembly and n-type memory characteristics of PAcPDI in nanoscale thin films. As-cast films of PAcPDI are fully amorphous, but the PDI units perform the formation of π–π stacks. During thermal annealing, the PAcPDI can self-assemble and form a horizontal lamellar structure. Monomorphic or polymorphic monoclinic crystals is formed by diverse π–π stack styles of the PDI units and film thickness. The differences of the thin film morphologies cause the electrical memory behavior. The thermally annealed thin films are confirmed that these tend to be high performance n-type unipolar volatile memory. The as-cast thin films are confirmed these tend to be n-type unipolar nonvolatile or volatile memory. The memory type of PAcPDI films can be changed by controlling the morphology and the film thickness. |
| 저자 |
김영용1, 브라이언 지원 리1, Makoto Kido2, 고용기1, Ryohei Ishige2, Tomoyasu Hirai2, 위동우1, 김제한1, 정유진1, 김원종1, Atsushi Takahara2, 이문호1
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| 소속 |
1포항공과대, 2Kyushu Univ. |
| 키워드 |
brush polymer; n-type electrical memory; morphology
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| E-Mail |
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