화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1715
발표분야 에너지
제목 Performance of spinel ferrite catalysts supported on mesoporous Al2O3 for high temperature water-gas shift reaction
초록 The present study focuses on the use of spinel ferrite (MFe2O4) catalysts supported on mesoporous alumina for the high temperature water-gas shift (WGS) reaction. High temperature WGS reaction has been carried out at a gas hourly space velocity of 41,821 h-1 over MFe2O4 catalysts prepared by the sol-gel method using a non-ionic template. Ni, Co, Fe, or Cu were employed as active metal for the target reaction in this study. Among these catalysts, copper ferrite supported on mesoporous alumina (CuFe2O4−MA) exhibited outstanding performance. The reason for the higher activity of CuFe2O4−MA might be a promotional effect of Cu on the reduction of hematite to magnetite, shifting it to a lower temperature, and better dispersion of CuO over the mesoporous alumina support.
저자 정대운, 나현석, JHA AJAY, 한원비, 심재오, 장원준, 김학민, 이열림, 전경원, 노현석
소속 연세대
키워드 Spinel ferrite; Mesoporous alumina; High temperature water-gas shift reaction; Sol-gel method
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