화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.37, No.1, 86-93, January, 2013
Export Citation
폴리프로필렌 부직포 섬유의 열, 항균 및 원적외선 방사 특성에 미치는 불소화 일라이트 첨가의 영향
Influence of Fluorinated Illite on Thermal, Antibiotic and Far-infrared Emission Properties of Polypropylene Non-woven Fibers
김진훈, 임지선, 서경원1, 이영석†
  • 충남대학교 공과대학 정밀응용화학과
  • 1(주)효창산업
Jinhoon Kim, Ji Sun Im, Kyeong-won Seo1, and Young-Seak Lee†
  • Department of Fine Chemical Engineering and Applied Chemistry, BK21-E2M, Chungnam National University, Daejeon 305-764, Korea
  • 1Hyochang Corporation, Seosan-city, Chungnam 356-821, Korea
E-mail:
초록
본 연구는 폴리프로필렌 수지에 불소화된 일라이트를 함량별로 첨가하여 제조한 일라이트/폴리프로필렌(PP) 부직포의 열적 특성, 항균성, 원적외선 방사율을 고찰하고자 하였다. 불소화 일라이트 첨가 폴리프로필렌 섬유의 열적 특성은 열중량 분석을 사용하여 조사하였다. 그 항균 특성은 황색포도상구균과 폐렴간균의 균주 실험으로, 원적외선 방사율은 퓨리에 변환 적외분광법을 사용하여 알아보았다. 그 실험결과, 일라이트/PP 부직포 섬유의 열적 특성 및 항균성, 원적외선 방사율은 불소화 일라이트의 함량이 증가할수록 증가하였고, 특히 불소화 일라이트 5 wt% 함유 PP 부직포 섬유의 경우가 일라이트를 함유하지 않은 PP 부직포에 비해 각각 10.3, 41.2 및 9.8%로 크게 증가하였다. 이는 일라이트의 불소화로 인하여 고분자 사슬 분자 사이의 계면결합력의 향상 때문이라 판단된다.
In this work, the thermal, antibiotic properties and far-infrared emissivity of fluorinated illite embedded polypropylene non-woven fibers (f-illite/PP fibers) were investigated in the presence of 0, 1, 3, 5 and 7 wt% illite powders. The thermal properties of f-illite/PP fibers were studied by thermogravimetric analysis (TGA). Their antibiotic properties were examined by Staphylococcus aureus and Klebsiella pneumoniae test. Their far-infrared emissivity was also investigated by Fourier transform infrared spectroscopy. From the experimental results, thermal, antibiotic properties and far-infrared emissivity of f-illite/PP fibers were improved by increasing fluorinated illite contents and the property values of 5 wt% f-illite/PP fibers were increased remarkably by about 10.3, 41.2 and 9.8% respectively in comparison with PP non-woven fibers having no fluorinated illite additive. This result was interpreted as the development of interfacial adhesion force between the polymer chains due to the fluorination of illite power.
Keywords:illite;polypropylene;fluorination;far-infrared emissivity;antibiotic property.
  1. Kim S, Palomino AM, Appl. Clay Sci., 51, 491 (2011)
  2. Reddy CR, Sardashti AP, Simon LC, Compos. Sci.Technol., 70, 1674 (2010)
  3. Alexandre M, Dubois P, Mater. Sci. Eng. R: Reports., 28, 1 (2000)
  4. Besra L, Sengupta DK, Roy SK, Ay P, Sep. Purif. Technol., 37(3), 231 (2004)
  5. Li M, Wu Z, Renew. Sust. Energ. Rev., 16, 2094 (2012)
  6. Perret B, Schartel B, Stoß K, Ciesielski M, Diederichs J, Doring M, Kramer J, Altstadt V, Eur. Polym. J., 47, 1081 (2010)
  7. Orhan T, Isitman NA, Hacaloglu J, Kaynak C, Polym.Degrad. Stabil., 97, 273 (2012)
  8. Jincheng W, Xiaoyu Z, Wenli H, Nan X, Xingchen P, Powder Technology., 221, 80 (2012)
  9. Mishra AK, Allauddin S, Narayan R, Aminabhavi TM, Raju KVSN, Ceram. Int., 38, 929 (2012)
  10. Birkenstock J, Kleemeier M, Vogt C, Wendschuh M, Hartwig A, Fischer RX, Appl. Clay Sci., 54, 144 (2011)
  11. Cao T, Fasulo PD, Rodgers WR, Appl. Clay Sci., 49, 21 (2010)
  12. Kang IM, Moon HS, Kim YJ, Song YG, Lee WP, Proceedings of the Annual Joint Conference, Petrological Society of Korea and Mineralogical Society of Korea, Cheongju, Korea (2004)
  13. Im JS, Park IJ, In SJ, Kim TJ, Lee YS, J. Fluorine Chem., 130, 1111 (2009)
  14. Jeong E, Lim JW, Seo K, Lee YS, J. Ind. Eng. Chem., 17(1), 77 (2011)
  15. Park Y, Ayoko GA, Frost RL, J. Colloid Interface Sci., 354(1), 292 (2011)
  16. Carja G, Kameshima Y, Nakajima A, Dranca C, Okada K, Int. J. Antimicrob. Agents., 34, 534 (2009)
  17. Sothornvit R, Rhim JW, Hong SI, J. Food Eng., 91, 468 (2009)
  18. Sastri VR, Plastics in Medical Devices., 5, 55 (2010)
  19. Meng N, Zhou NL, Zhang SQ, Shen J, Appl. Clay Sci., 42, 667 (2009)
  20. Bai BC, Kim JG, Im JS, Jung SC, Lee YS, Carbon Lett., 12, 236 (2011)
  21. Yu HR, Kim JG, Im JS, Bae TS, Lee YS, J. Ind. Eng. Chem., 18(2), 674 (2012)
  22. Yu HR, Jeong E, Kim J, Lee YS, Polym.(Korea), 35(1), 47 (2011)
  23. Cwil M, Kalisz M, Konarski P, Appl. Surf. Sci., 255(4), 1334 (2008)
  24. Jeong E, Lee YS, J. Ind. Eng. Chem., 22, 467 (2011)
  25. Marcincin A, Prog. Polym. Sci., 27, 853 (2002)
  26. Xie S, Jones EH, Shen Y, Hornsby P, McAfee M, McNally T, Patel R, Benkreira H, Coates P, Mater. Lett., 64, 185 (2010)
  27. Santos KS, Liberman SA, Oviedo MAS, Mauler RA, Composites Part A., 40, 1199 (2009)
  28. Han M, Yun J, Kim HI, Lee YS, J. Ind. Eng. Chem., 18(2), 752 (2012)
  29. Kim HC, Jeon S, Kim HI, Lee YS, Hong MH, Choi KS, Polym.(Korea), 36(3), 251 (2012)
  30. Doyle CD, J. Appl Polym Sci., 5, 285 (1961)
  31. Park SJ, Kim HC, J. Polym. Sci. B: Polym. Phys., 39(1), 121 (2001)
  32. Kim W, Bae JW, Choi ID, Kim YS, Polym. Eng. Sci., 39(4), 756 (1999)
  33. Hou A, Zhou M, Wang X, Carbohydr. Polym., 75, 328 (2009)
  34. Takeuchi O, Hoshino K, Kawai T, Sanjo H, Takada H, Ogawa T, Takeda K, Akira S, Immunity., 11, 443 (1999)
  35. Hong S, Lee C, Kim J, Textile Coloration and Finishing., 22, 119 (2010)
  36. Park JH, Shim MH, Shim HS, Key Eng. Mater., 321, 849 (2006)